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Tailing filling all-solid-waste cementing material and preparation method thereof

A technology for tailings filling and cementitious materials, applied in cement production and other directions, can solve the problems of high sedimentation rate and low compressive strength, and achieve the effects of preventing agglomeration, reducing shrinkage rate and reducing shrinkage.

Active Publication Date: 2021-08-10
HUBEI POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The invention proposes a tailings filling all-solid waste cementitious material and its preparation method, which solves the problems of high settlement rate and low compressive strength in the prior art

Method used

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  • Tailing filling all-solid-waste cementing material and preparation method thereof
  • Tailing filling all-solid-waste cementing material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] S1. Material preparation: 22 parts of tailings slag, 45 parts of steel slag, 3 parts of calcium fluoride slag, 18 parts of anhydrite, 7 parts of calcined clay, 0.2 parts of polycarboxylate superplasticizer, 4 parts of activator, of which the average particle size of activator is The diameter is 2-3 μm, and it is a composition of tetrasodium pyrophosphate, sodium silicate, and sodium fluorosilicate in a mass ratio of 1:2:0.3, and the particle size of anhydrite is ≤500 μm. The calcined clay is prepared by the following steps: The clay is calcined at 2000°C for 4 hours at a high temperature, and after cooling, it is ground to a particle size of ≤100 μm;

[0029] S2. Crushing steel slag, tailings slag, and calcium fluoride slag to a particle size of 20-30mm;

[0030] S3, dry grinding to a particle size of 5-10mm;

[0031] S4. Add water and half of the polycarboxylate high-efficiency water reducer, the mass ratio of water to the mixture is 15%, and wet mill until the partic...

Embodiment 2

[0035] S1. Material preparation: 31 parts of tailings slag, 50 parts of steel slag, 5 parts of calcium fluoride slag, 22 parts of fluorogypsum, 9 parts of calcined clay, 0.5 parts of polycarboxylate superplasticizer, 6 parts of activator, of which the average particle size of activator is The diameter is 2-3 μm, and it is a composition of tetrasodium pyrophosphate, sodium silicate, and sodium fluorosilicate in a mass ratio of 1:2:0.3, and the particle size of anhydrite is ≤500 μm. The calcined clay is prepared by the following steps: The clay is calcined at 1800°C for 5 hours at a high temperature, and after cooling, it is ground to a particle size of ≤100 μm;

[0036] S2. Crushing steel slag, tailings slag, and calcium fluoride slag to a particle size of 20-30mm;

[0037] S3, dry grinding to a particle size of 5-10mm;

[0038] S4. Add water and half of the polycarboxylate high-efficiency water reducer, the mass ratio of water to the mixture is 20%, and wet mill until the par...

Embodiment 3

[0042] S1. Material preparation: 28 parts of tailings slag, 48 parts of steel slag, 4 parts of calcium fluoride slag, 20 parts of fluorogypsum, 8 parts of calcined clay, 0.4 part of polycarboxylate superplasticizer, 5 parts of activator, of which the average particle size of activator is The diameter is 2-3 μm, and it is a composition of tetrasodium pyrophosphate, sodium silicate, and sodium fluorosilicate in a mass ratio of 1:2:0.3, and the particle size of anhydrite is ≤500 μm. The calcined clay is prepared by the following steps: The clay is calcined at 1900°C for 4.5 hours at high temperature, and after cooling, it is ground to a particle size of ≤100 μm;

[0043] S2. Crushing steel slag, tailings slag, and calcium fluoride slag to a particle size of 20-30mm;

[0044] S3, dry grinding to a particle size of 5-10mm;

[0045] S4. Add water and half of the polycarboxylate high-efficiency water reducer, the mass ratio of water to the mixture is 20%, and wet mill until the part...

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Abstract

The invention relates to the technical field of filling materials, and provides a tailing filling all-solid-waste cementing material which comprises the following components in parts by weight: 22-31 parts of tailing slag, 45-50 parts of steel slag, 3-5 parts of calcium fluoride slag, 18-22 parts of gypsum, 7-9 parts of calcined clay, 0.2-0.5 part of a polycarboxylate superplasticizer and 4-6 parts of an activator, and the invention also provides a preparation method of the tailing filling all-solid-waste cementing material. By means of the technical scheme, the problems that in the prior art, the sinking shrinkage rate is high, and the compressive strength is low are solved.

Description

technical field [0001] The invention relates to the technical field of filling materials, in particular to a tailings filling solid waste cementitious material and a preparation method thereof. Background technique [0002] With the development of the economy, the human demand for energy is increasing day by day. There are a lot of energy substances in mines. While mining brings a lot of resources, it will also cause environmental pollution and even lead to geological disasters, the most prominent of which is surface subsidence. [0003] The part of the product of the sorting operation in mineral processing that has a low content of useful target components and cannot be used for production is called tailings. Under the current technical and economic conditions, further sorting is no longer suitable. Realizing the recycling of waste is the need of fully utilizing mineral resources and protecting the ecological environment. At present, the accumulation of tailings in my co...

Claims

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Application Information

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IPC IPC(8): C04B7/153
CPCC04B7/1535Y02P40/10
Inventor 李幸泽屈媛陈跃冯伟
Owner HUBEI POLYTECHNIC UNIV