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Solvent-free release silicone oil suitable for PET film and preparation method of solvent-free release silicone oil

A solvent-free, release technology, applied in the direction of film/sheet adhesives, adhesives, film/sheet release liners, etc., can solve the problems of non-release, release silicone oil coating, release difficulties, etc. , to achieve the effect of increasing adhesion, reducing peeling force and good curing

Active Publication Date: 2021-08-20
惠州市永卓科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the substrates suitable for solvent-free release silicone oil include paper substrates such as glassine paper and coated paper PEK. If solvent-free release silicone oil is applied to polyester film PET film coated with silicon, serious problems will occur. The phenomenon that the release silicone oil coating falls off, resulting in difficult or even non-release consequences

Method used

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  • Solvent-free release silicone oil suitable for PET film and preparation method of solvent-free release silicone oil
  • Solvent-free release silicone oil suitable for PET film and preparation method of solvent-free release silicone oil
  • Solvent-free release silicone oil suitable for PET film and preparation method of solvent-free release silicone oil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] 97.6 parts of polyorganosiloxane containing acryloyloxypropyl group, 2 parts of vinyl-terminated phenyl silicone oil, 0.4 part of acetylenic alcohol, 1.4 parts of crosslinking agent, and 1.5 parts of Castel catalyst.

[0036] Among them, polyorganosiloxane containing acryloxypropyl group, vinyl-terminated phenyl silicone oil, and acetylenic alcohol are used as the main agent of the release silicone oil.

[0037] Among them, in the polyorganosiloxane containing acryloyloxypropyl group, the synthetic formula has the following components in terms of parts by weight: 30 parts of allyl acrylate, 500 parts of hydrogen-terminated polydimethylsiloxane, chlorine 5 parts of isopropanol solution of platinum acid, 450 parts of toluene.

[0038] Among them, the polyorganosiloxane containing acryloyloxypropyl has a viscosity of 480mPa·s, and its structural formula is:

[0039]

[0040] Wherein, m=50-500, n=0-10.

[0041] In this embodiment, the polyorganosiloxane containing acry...

Embodiment 2

[0059] The difference between this embodiment and embodiment 1 is:

[0060] 95.8 parts of polyorganosiloxane containing acryloyloxypropyl group, 4 parts of vinyl-terminated phenyl silicone oil, 0.2 part of acetylenic alcohol, 1 part of crosslinking agent, and 1 part of Castel catalyst.

[0061] Among them, in the polyorganosiloxane containing acryloyloxypropyl group, the synthetic material has the following components in terms of parts by weight: 25 parts of allyl acrylate, 480 parts of hydrogen-terminated polydimethylsiloxane, chlorine 2 parts of isopropanol solution of platinum acid, 430 parts of toluene.

[0062] Wherein, the viscosity of polyorganosiloxane containing acryloxypropyl group is 300mPa·s, further, the structural formula of polyorganosiloxane containing acryloxypropyl group is:

[0063]

[0064] Among them, the viscosity of hydrogen-terminated polydimethylsiloxane is 20mPa·s,

[0065] Wherein, the concentration of elemental platinum in the isopropanol solut...

Embodiment 3

[0071] The difference between this embodiment and embodiment 1 is:

[0072] 98.8 parts of polyorganosiloxane containing acryloyloxypropyl group, 1 part of vinyl-terminated phenyl silicone oil, 0.2 part of acetylenic alcohol, 1.6 parts of crosslinking agent, and 3 parts of Castel catalyst.

[0073] Among them, in the polyorganosiloxane containing acryloyloxypropyl group, the synthetic material contains the following components in parts by weight: 35 parts of allyl acrylate, 520 parts of hydrogen-terminated polydimethylsiloxane, chlorine 8 parts of isopropanol solution of platinum acid, 470 parts of toluene.

[0074] Wherein, the polyorganosiloxane containing acryloxypropyl group has a viscosity of 600mPa·s, and further, the structural formula of the polyorganosiloxane containing acryloxypropyl group is:

[0075]

[0076] Among them, the viscosity of hydrogen-terminated polydimethylsiloxane is 150mPa·s,

[0077] Wherein, the concentration of elemental platinum in the isopro...

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Abstract

The invention relates to release silicone oil, in particular to solvent-free release silicone oil suitable for a PET (polyethylene terephthalate) film and a preparation method of the solvent-free release silicone oil, and the solvent-free release silicone oil comprises the following components: polyorganosiloxane containing acryloyloxypropyl, vinyl-terminated phenyl silicone oil, alkynol, a cross-linking agent and a Karstedt catalyst. Polyorganosiloxane containing acryloyloxypropyl is used as a main agent of the release silicone oil, so that the adhesive force of the release silicone oil to a PET film can be greatly increased, the prepared release silicone oil has no desilicication phenomenon after being applied and has very light stripping force, and an adhesive layer still has very high adhesive force after being stripped from a release silicone oil coating.

Description

technical field [0001] The invention relates to release-type silicone oil, in particular to a solvent-free release-type silicone oil suitable for coating silicon on PET films and a preparation method thereof. Background technique [0002] The release silicone oil is mainly divided into solvent-type release silicone oil and solvent-free release silicone oil. Since the solvent-type release silicone oil itself contains solvent, a large amount of solvent needs to be added during use, which is harmful to the environment and personnel. was gradually eliminated. The solvent-free release silicone oil product itself is non-toxic and non-polluting, and does not require the use of solvents during use, and has no pollution to the environment and no toxic effects on personnel. [0003] At present, the substrates suitable for solvent-free release silicone oil include paper substrates such as glassine paper and coated paper PEK. If solvent-free release silicone oil is applied to polyester...

Claims

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Application Information

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IPC IPC(8): C09D183/07C08J7/04C09J7/40C08L67/02
CPCC09D183/06C08J7/0427C09J7/401C08J2367/02C08J2483/07C09J2483/005C08L2205/02C08L83/04
Inventor 王细平
Owner 惠州市永卓科技有限公司
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