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Powder activated carbon low-temperature heat-liquid phase in-situ regeneration method based on continuous frequency conversion ultrasonic wave/ozone solution coupling effect

The technology of powder activated carbon and frequency conversion ultrasonic wave is applied in the field of water treatment, which can solve the problems of high energy consumption and secondary pollution of exhaust gas, and achieve the effects of high contact efficiency, improved utilization efficiency, and good scope of application.

Pending Publication Date: 2021-11-23
BEIJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The invention provides a low-temperature heat-liquid phase in-situ regeneration method of powdered activated carbon based on the coupling effect of continuous frequency conversion ultrasonic wave / ozone solution. The low-temperature heat-liquid phase in-situ regeneration method of powdered activated carbon with frequency conversion ultrasonic / ozone solution coupling is used to solve the problems of regeneration by professional manufacturers, high energy consumption, and secondary pollution of exhaust gas in the regeneration process of saturated powdered activated carbon.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1: Add a regeneration solution of 0.05mM sodium hydroxide to the saturated powdered activated carbon concentrate that absorbs p-chlorophenol at a concentration of 5000mg / L, stir at 120rpm, and heat the regeneration solution to 70°C to form a low-temperature hot mixed solution . Add ozone solution to the low-temperature thermal mixture, the concentration of ozone in the low-temperature thermal ozone mixture is 1 mg / L, and continue stirring at 100 rpm for 5 minutes to form a low-temperature thermal ozone mixture of powdered activated carbon. Turn on the frequency conversion ultrasound, the total time of ultrasonic action is 45min, of which, the continuous frequency conversion cycle interval of the ultrasonic wave in the 0-5min time period is 20-40kHz, and the cycle period is 5min; the continuous frequency conversion cycle interval of the ultrasonic wave in the 5-30min time period is 35-100kHz , the cycle period is 5min; the ultrasonic continuous frequency conversi...

Embodiment 2

[0021] Example 2: Add a regeneration solution of 0.05mM hydrochloric acid to the saturated powdered activated carbon concentrate that absorbs active blue 81 at a concentration of 2000mg / L, and stir at 120rpm, and heat the regeneration solution to 50°C to form a low-temperature hot mixed solution. Add ozone solution to the low-temperature thermal mixture, the concentration of ozone in the low-temperature thermal ozone mixture is 0.5 mg / L, and continue stirring at 100 rpm for 5 minutes to form a low-temperature thermal ozone mixture of powdered activated carbon. Turn on the frequency conversion ultrasound, and the ultrasonic action time lasts for 30 minutes. Among them, the ultrasonic continuous frequency conversion cycle interval is 20-40kHz at 0-5min, and the ultrasonic continuous frequency conversion cycle is 2.5min; the ultrasonic continuous frequency conversion cycle interval is 35 when the action is 5-30min. -100kHz, the cycle period of ultrasonic continuous frequency conve...

Embodiment 3

[0022]Example 3: A regeneration solution of 0.1 mM sodium hydroxide is added to the saturated powdered activated carbon concentrate that absorbs acetone at a concentration of 5000 mg / L, stirred at 150 rpm, and the regeneration solution is heated to 80° C. to form a low-temperature hot mixed solution. Add ozone solution to the low-temperature thermal mixture, the concentration of ozone in the low-temperature thermal ozone mixture is 0.5 mg / L, and continue stirring at 100 rpm for 5 minutes to form a low-temperature thermal ozone mixture of powdered activated carbon. Turn on the frequency conversion ultrasound, the ultrasonic action time lasts for 5 minutes, the continuous frequency conversion cycle interval of the ultrasonic wave in the 0-5min period is 20-40kHz, and the cycle period of the continuous frequency conversion of the ultrasonic wave is 5min. The treated powdered activated carbon is separated and reused directly. The powdered activated carbon material used is wood, th...

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Abstract

The invention discloses a powder activated carbon low-temperature heat-liquid phase in-situ regeneration method based on continuous frequency conversion ultrasonic wave / ozone solution coupling effect, and belongs to the technical field of water treatment. According to the method, continuous frequency conversion ultrasound, ozone solution and low-temperature hydrothermal phase regeneration are synergistic, and the powdered activated carbon can be regenerated and recycled in situ, so that the regeneration cost is reduced, and many defects existing in the process of a traditional thermal regeneration method are overcome. The continuous variable-frequency ultrasonic waves can further strengthen migration and mass transfer effects of ozone molecules in the ozone solution in pores and pore channels of the activated carbon, effectively avoid damage to the pore structure of the activated carbon in the regeneration process, and remarkably strengthen the regeneration effect. According to the invention, the defects of conventional regeneration modes such as fixed-frequency ultrasonic waves, ozone bubbles and solvents are overcome, and the regeneration effect of the powdered activated carbon is obviously improved and optimized. Ultrasonic action parameters can be optimized according to the characteristics of pollutants adsorbed in the powdered carbon and the composition and temperature of the regeneration liquid required by regeneration, and the method has a relatively good application range.

Description

technical field [0001] The invention belongs to the technical field of water treatment, in particular to a method for regenerating waste powder activated carbon for water treatment. Background technique [0002] Powdered activated carbon has a well-developed pore structure and stable physical and chemical properties, and can adsorb various pollutants in water. It has been widely used in water source water purification, water quality emergency treatment, advanced treatment of urban sewage and industrial wastewater, etc. Due to the high price of activated carbon, regeneration and reuse are mostly considered in the field of water treatment. The use of efficient regeneration technology can realize the recycling of powdered activated carbon, reduce the amount of waste powdered activated carbon, improve the use efficiency of powdered activated carbon, and reduce the cost of process operation. The thermal regeneration method is to desorb, carbonize, oxidize and decompose the adsor...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/34C02F1/28
CPCB01J20/3475B01J20/3441B01J20/3416C02F1/283C02F2303/16
Inventor 杨艳玲于瑞李星周志伟
Owner BEIJING UNIV OF TECH