Positive current collector, preparation method thereof, positive plate, battery cell and battery
A technology for positive current collectors and batteries, which is applied in the field of battery pole pieces and can solve the problems of low electrical conductivity and current conductivity of positive current collectors
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[0062] The present application also provides a method for preparing a positive electrode current collector, comprising: forming an adhesive layer on the first surface of the base film, forming a diversion layer with inconsistent thickness on the adhesive layer, and forming a reinforcement layer on the diversion layer . The preparation method of the positive electrode current collector will be described in detail below.
[0063] Preparation of the adhesive layer.
[0064] Before preparing the adhesive layer, the base film may be pretreated, including: performing corona treatment on the first surface and the second surface of the base film. Then, an adhesive layer is formed on the surface of the base film by vapor deposition. The bonding layer is non-metal, optional, non-metal is SiC, Si 3 N 4 , SiO x (1.5≤x≤2) and AlO x At least one of (1≤x≤1.5).
[0065] In some embodiments of the present application, the method for forming the adhesive layer includes:
[0066] Put the...
Embodiment 1
[0091] This embodiment provides a positive electrode current collector and a preparation method thereof, comprising the following steps:
[0092] S1. First, corona treatment is carried out on the surface of the base film to be coated. The thickness of the base film is 12 μm, and then the roll base film is placed in the vacuum chamber of the vacuum coating machine, the vacuum chamber is sealed, and the vacuum is gradually evacuated until the vacuum degree reaches 5 ×10 -2 Pa, use the oxygen ventilation structure near the evaporation source to introduce compressed oxygen, and the ventilation volume is 4000sccm and 3500sccm. Evaporation source The raw material for evaporation is metal aluminum wire or aluminum ingot with purity ≥99.9%. A layer of Al 2 o 3 The oxide layer, ie the bonding layer, is about 10nm thick.
[0093] S2. Put the film with adhesive layer on the surface obtained in S1 into the vacuum chamber of a single-sided or double-sided reciprocating evaporation coat...
Embodiment 2
[0101] This embodiment provides a positive electrode current collector and a preparation method thereof, the only difference from Embodiment 1 is:
[0102] When coating perfluoropolyether oil in S2, the thickness of the coating is gradually reduced from the surface corresponding to the first coating section of the adhesive layer to the surface corresponding to the second functional section. After vapor deposition, an aluminum-coated layer with inconsistent thickness is formed on the surface of the bonding layer, and the thickness of the aluminum-coated layer changes gradually.
[0103] The unequal thickness positive electrode current collector obtained in this embodiment, the structure of the positive electrode current collector is as follows Image 6 .
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Abstract
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