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Flaky silver glossy ceramic rock plate and preparation method thereof

A silver glossy, ceramic technology used in the field of ceramic tile production and manufacturing

Pending Publication Date: 2022-02-08
MONALISA GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But zirconium silicate crystals have some radioactivity

Method used

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  • Flaky silver glossy ceramic rock plate and preparation method thereof
  • Flaky silver glossy ceramic rock plate and preparation method thereof
  • Flaky silver glossy ceramic rock plate and preparation method thereof

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preparation example Construction

[0053] The preparation method of the flaky silver luster ceramic rock slab of the present invention is different from obtaining glaze crystals to achieve flash, but uses non-radioactive zirconium slices and controls the composition and parameters of the zirconium slices to regulate reflection, thereby reducing the glaze surface. On the basis of defects, the difference in refractive index between the zirconium sheet and the glass phase formed after firing the transparent glaze promotes the glaze surface on the zirconium sheet decoration to have a reflective effect, thereby forming a flake silver metallic luster decoration.

[0054] In addition, the Mohs hardness scale of the zirconium sheet in the present invention is between 6.5 and 7.5. Compared with the traditional polished glaze surface (Mohs hardness level is 3.5-4.0), the preparation method of the present invention spreads the zirconium flakes on the lower layer of the transparent glaze polish layer, and at least part of t...

Embodiment 1

[0057] The preparation method of the flaky silver luster ceramic rock plate comprises the following steps:

[0058] Step 1. Press common ceramic base material into adobe;

[0059] Step 2. Drying the adobe in a drying kiln for 1 to 1.2 hours, and controlling the moisture content of the adobe within 0.5wt%;

[0060] Step 3. Spray the surface glaze on the surface of the brick; the chemical composition of the surface glaze includes: in terms of mass percentage: loss on ignition: 3.00~4.00%, SiO 2 : 49.98~50.78%, Al 2 o 3 : 29.87~31.45%, Fe 2 o 3 : 0.22~0.42%, TiO 2 : 0.05~0.07%, CaO: 0.65~0.97%, MgO: 0.13~0.24%, K 2 O: 4.78~5.52%, Na 2 O: 2.58~3.34%, P 2 o 5 : 0.26~0.45%, ZrO 2 : 5.03~6.45%; the specific gravity of the surface glaze is 1.40~1.43g / cm 3 , the glaze amount is 500~600g / m 2 ;

[0061] Step 4. Inkjet printing patterns on the surface of the adobe after applying the glaze;

[0062] Step 5. Sprinkle zirconium flakes whose main phase composition is tetragonal ...

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Abstract

The invention discloses a flaky silver glossy ceramic rock plate and a preparation method thereof. The preparation method comprises the following steps: applying cover glaze on the surface of a green brick; carrying out ink-jet printing on the surface of the green brick subjected to overglaze application to form a pattern; scattering zirconium sheets of which the main phase composition is tetragonal system zirconium oxide on the surface of the green brick subjected to ink-jet printing of the pattern; applying transparent glaze on the surface of the green brick after the zirconium sheets are scattered; and sintering and polishing the green brick with the transparent glaze until at least part of zirconium sheets are exposed out of the surface of the transparent glaze layer to obtain the flaky silver glossy ceramic rock plate. According to the method, high-refractive-index zirconium oxide composed of specific phases is made into a zirconium sheet form and is scattered on the surface of the green brick, and by means of the refractive index difference value between the zirconium sheet and a glass phase formed after firing of transparent glaze, the glaze surface of the decoration part of the zirconium sheet has a light reflecting effect, and irradiation of a strong light condition is not needed; and the glaze surface can be seen to have silver reflective luster under the condition of natural light.

Description

technical field [0001] The invention relates to a flaky silver luster ceramic rock plate and a preparation method thereof, which belong to the technical field of ceramic brick production and manufacture. Background technique [0002] Most of the glazed tiles in the market are antique tiles. Some manufacturers also prepare glazed flash glazed glazed tiles by forming crystals mainly composed of zirconium silicate crystals in the glaze layer. But zirconium silicate crystals have certain radioactivity. [0003] Chinese patent CN110357668A discloses a fully glazed ceramic tile with granular glitter decoration and a preparation method thereof, in which a layer of golden sand glaze is spread under the transparent glaze layer to achieve the glitter effect. Chinese patent CN109761649A discloses a rock slab ceramic tile with a diamond luster effect and a preparation method thereof, in which a layer of diamond dry particles is sprinkled to achieve the glaze sparkle effect. The above...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/89C03C8/00C03C8/04
CPCC04B41/89C04B41/52C03C8/00C03C8/04C04B41/4505C04B41/5042C04B41/5022
Inventor 刘一军覃增成杨元东胡志敏黄秋立张克林
Owner MONALISA GRP CO LTD