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Smelting method for accurately controlling nitrogen content in steel

A technology of precise control and smelting method, applied in the field of metallurgy, can solve the problems of high price, secondary pollution of molten steel, severe tumbling of molten steel, etc., and achieve the effect of improving quality stability

Pending Publication Date: 2022-02-11
SHIJIAZHUANG IRON & STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The vast majority of iron and steel enterprises use nitrogen-containing alloys in appropriate processes or feed nitrogen-containing alloy wires and bottom-blown nitrogen gas stirring in the refining process to achieve nitrogen increase. These methods of nitrogen increase are more effective methods, but there are also disadvantages : 1) Nitrogen-increasing of nitrogen-containing alloy is stable, but the price is relatively expensive. 2) Nitrogen-increasing of nitrogen-containing alloy wire is also relatively stable, but the molten steel is violently tumbling during the wire feeding process, which easily causes secondary pollution of molten steel. 3) Refining Too long nitrogen blowing time will affect the refining effect and the nitrogen increase will be unstable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Production of gear steel 20CrMoH, the production process includes converter smelting, LF furnace refining, VD furnace refining processes,

[0024] (1) Converter smelting process: 3.5kg / t ferromanganese nitride alloy is added during tapping and alloying, argon gas is used to stir during tapping, and manganese nitride alloy is added to steel during tapping to increase nitrogen by 70ppm.

[0025] (2) LF furnace refining process: the LF furnace refining process uses silicon carbide for diffusion deoxidation, the binary basicity of the slag at the end of refining is 3.4, and the FeO content in the slag is 0.5wt%. During the refining process, when the temperature of the molten steel reaches T, the ladle is stirred with nitrogen, the nitrogen flow rate is controlled at 200NL / min, and the nitrogen blowing time is controlled at 24min, and the T=T 液相线 +△T, where T 液相线 is the liquidus temperature of molten steel, and △T is 50°C. Nitrogen is blown at the bottom of the LF furnace ...

Embodiment 2

[0029] Production of gear steel 20CrMoH, the production process includes converter smelting, LF furnace refining, VD furnace refining processes,

[0030] (1) Converter smelting process: 3.7kg / t ferromanganese nitride alloy is added during tapping and alloying, argon gas is used to stir during tapping, and manganese nitride alloy is added to steel during tapping to increase nitrogen by 72ppm.

[0031] (2) LF furnace refining process: the LF furnace refining process uses silicon carbide for diffusion deoxidation, the binary basicity of the slag at the end of refining is 4.1, and the FeO content in the slag is 0.3wt%. During the refining process, when the temperature of the molten steel reaches T, the ladle is stirred with nitrogen, the nitrogen flow rate is controlled at 219NL / min, and the nitrogen blowing time is controlled at 23min, and the T=T 液相线 +△T, where T 液相线 is the liquidus temperature of molten steel, and △T is 50°C. Nitrogen is blown at the bottom of the LF furnace ...

Embodiment 3

[0035] Production of gear steel 20CrMoH, the production process includes converter smelting, LF furnace refining, VD furnace refining processes,

[0036] (1) Converter smelting process: 3.9kg / t ferromanganese nitride alloy is added during tapping and alloying, argon gas is used to stir during tapping, and manganese nitride alloy is added to steel during tapping to increase nitrogen by 74ppm.

[0037] (2) LF furnace refining process: LF furnace refining process uses silicon carbide for diffusion deoxidation, the binary basicity of slag at the end of refining is 5.4, and the FeO content in slag is 0.4wt%. During the refining process, when the temperature of the molten steel reaches T, the ladle is stirred with nitrogen, the nitrogen flow rate is controlled at 241NL / min, and the nitrogen blowing time is controlled at 25min, and the T=T 液相线 +△T, where T 液相线 is the liquidus temperature of molten steel, and △T is 51°C. Nitrogen is blown at the bottom of the LF furnace to increase ...

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PUM

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Abstract

The invention discloses a smelting method for accurately controlling the nitrogen content in steel, which comprises the procedures of converter smelting, LF furnace refining and VD furnace refining, wherein the vacuumizing process time of the VD furnace refining procedure is less than or equal to 10 min, bottom blowing stirring is forbidden in the vacuumizing process, bottom blowing nitrogen stirring is started when the vacuum degree is less than or equal to 67 Pa, the nitrogen flow is controlled to be 30-80 NL / min, and the vacuum time is controlled to be 6-7 min. The technology that a small amount of manganese nitride alloy is added in the stokehole tapping process to increase nitrogen, nitrogen blowing is carried out in the refining process and nitrogen blowing is carried out in the VD high-vacuum process is adopted, the requirement that the nitrogen content hits the target range at a time after VD vacuum treatment is achieved, the quality stability of nitrogen-containing steel is improved, the denitrification rate in the VD furnace refining process is less than or equal to 45%, and the loss rate is 5-6 ppm / min.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and in particular relates to a smelting method for precisely controlling the nitrogen content in steel. Background technique [0002] Nitrogen is a harmful element for most steel types, but it is a beneficial alloying element in some stainless steels, non-quenched and tempered steels, and some high-toughness structural steels. The nature of nitrogen is similar to that of carbon, and it is the main element as an interstitial atom, which is determined by its small atomic size and electronic layer structure. His role in steel is mainly to precipitate fine alloy nitrides in the cooling process after rolling or heading to achieve the purpose of dispersion strengthening. [0003] Nitrogen increase is a difficult problem for the steelmaking process, especially for steel types that have a narrow range of nitrogen content requirements. Different smelting equipment and conditions require matching nitro...

Claims

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Application Information

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IPC IPC(8): C21C7/072C21C7/10C21C7/06
CPCC21C7/072C21C7/10C21C7/06Y02P10/20
Inventor 黄永建刘国平陈良勇丁志军高鹏秦影祖衡陈国王成杰黄鑫
Owner SHIJIAZHUANG IRON & STEEL
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