Fuel additive containing porphyrin metal complex as well as preparation method and application of fuel additive

A metal complex and additive technology, applied in the field of fuel additives, can solve the problems of insoluble, time-consuming, insoluble nanoparticles, etc., to extend the regeneration time and regeneration distance, reduce maintenance times and costs, and save fuel maintenance times. and cost effects

Pending Publication Date: 2022-04-12
天津悦泰石化科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This technique for cleaning the DPF requires vehicle maintenance, which is time-consuming and laborious, and it is easy to break through the wall-flow micropores in the DPF, resulting in a decrease in the filtration efficiency of the DPF.
Chinese patent CN104845682A discloses a fuel catalyst for an automobile internal combustion engine. The catalyst is composed of tourmaline, alumina, iron oxide and cerium oxide. The role of removing carbon deposits, but aluminum oxide, iron oxide, cerium oxide, etc. are all particles of about 250 μm, which cannot be dissolved in fuel and are not mentioned in the application of DPF particle filter regeneration
Although the particle size of the catalyst is below 5nm, it is still insoluble in fuel and the nanoparticles are easy to agglomerate, which affects its use

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Preparation of porphyrin metal complex (iron porphyrin): Dissolve tetraphenylporphyrin (50mmol) and ferric chloride (150mmol) in N'N-dimethylformamide (50mL), stir The temperature of the reaction system was raised to 150° C. to react for 8 hours, and the reaction mixture was poured into ice water to precipitate iron porphyrin, filtered with suction, washed with deionized water, and dried in vacuum to obtain iron porphyrin.

[0048] Preparation of the fuel additive containing porphyrin metal complex (iron porphyrin): 2.5 parts by weight of iron porphyrin, 6 parts by weight of polyisobutylene succinimide, 100 parts by weight of 6# solvent oil, 0.6 parts by weight of p-tert-butylphenol parts by weight, mixed uniformly at 50°C to prepare a fuel additive containing iron porphyrin.

[0049] Solubility of fuel additives containing porphyrin metal complexes (iron porphyrin): After mixing fuel additives containing porphyrin metal complexes (iron porphyrin) and fuel oil at a volu...

Embodiment 2

[0054] Preparation of porphyrin metal complex (octaethylporphyrin-platinum): dissolve octaethylporphyrin (50mmol) and platinum chloride (100mmol) in N'N-dimethylformamide (50mL), Under magnetic stirring, the reaction system was heated to 120°C for 2 hours, and the reaction mixture was poured into ice water to precipitate octaethylporphyrin-platinum, filtered with suction, washed with deionized water, and dried in vacuum to obtain octaethylporphyrin Phenyl-platinum complexes.

[0055] Preparation of fuel additive containing porphyrin metal complex (octaethylporphyrin-platinum): 7.5 parts by weight of octaethylporphyrin-platinum complex, 14 parts by weight of polyisobutylamine, 100 parts by weight of 120# solvent oil , 0.6 parts by weight of BHT, mixed uniformly at 30°C to prepare a fuel additive containing octaethylporphyrin-platinum complex.

[0056] Solubility of fuel additives containing porphyrin metal complexes (octaethylporphyrin-platinum): the ratio of fuel additives co...

Embodiment 3

[0061] Preparation of porphyrin metal complex (cerium porphyrin): tetraphenylporphyrin (50mmol) and cerium nitrate (150mmol) were dissolved in N'N-dimethylformamide (50mL), and the The temperature of the reaction system was raised to 150° C. for 8 hours, and the reaction mixture was poured into ice water to precipitate cerium porphyrin, filtered with suction, washed with deionized water, and dried in vacuum to obtain cerium porphyrin.

[0062] Preparation of fuel additive containing porphyrin metal complex (cerium porphyrin): 5.5 parts by weight of cerium porphyrin, 10 parts by weight of polyisobutylene succinimide, 100 parts by weight of 6# solvent oil, 0.5 parts by weight of p-tert-butylphenol parts by weight, uniformly mixed at 50°C to prepare a fuel additive containing cerium porphyrin.

[0063] Solubility of fuel additives containing porphyrin metal complexes (cerium porphyrin): After mixing fuel additives containing porphyrin metal complexes (cerium porphyrin) and fuel o...

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Abstract

The invention discloses a fuel additive containing a porphyrin metal complex as well as a preparation method and application of the fuel additive. The fuel additive is prepared from components including solvent oil, an amine detergent and a porphyrin metal complex, and can effectively solve the problem of passive regeneration failure of a diesel engine particulate filter (DPF) and reduce the number of times of active regeneration, so that the effects of maintaining the DPF, saving oil and reducing the number of times and cost of maintenance are achieved.

Description

technical field [0001] The invention belongs to the technical field of fuel additives, and in particular relates to a fuel additive containing a porphyrin metal complex and a preparation method and application thereof. Background technique [0002] With the implementation of increasingly stringent exhaust emission regulations in Europe, the United States, Japan, and China, the demand for diesel vehicle particulate filter DPF as an effective device to reduce particulate matter emissions will grow rapidly. On July 1, 2021, my country will implement the National VI emission standard nationwide, and the emission of particulate matter will be greatly tightened. In the past, the technical route of increasing the combustion temperature in the cylinder and the SCR system used in the National V emission stage can no longer meet the requirements of the particulate matter emission standard, and the particulate filter DPF must be installed to meet the emission requirements. [0003] DP...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10L1/236C10L1/2387C10L1/30C07D487/22
Inventor 张园赵扬朱宗敏庞雅枫阎敏陆慧琴
Owner 天津悦泰石化科技有限公司
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