Fuel additive containing porphyrin metal complex as well as preparation method and application of fuel additive
A metal complex and additive technology, applied in the field of fuel additives, can solve the problems of insoluble, time-consuming, insoluble nanoparticles, etc., to extend the regeneration time and regeneration distance, reduce maintenance times and costs, and save fuel maintenance times. and cost effects
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Embodiment 1
[0047] Preparation of porphyrin metal complex (iron porphyrin): Dissolve tetraphenylporphyrin (50mmol) and ferric chloride (150mmol) in N'N-dimethylformamide (50mL), stir The temperature of the reaction system was raised to 150° C. to react for 8 hours, and the reaction mixture was poured into ice water to precipitate iron porphyrin, filtered with suction, washed with deionized water, and dried in vacuum to obtain iron porphyrin.
[0048] Preparation of the fuel additive containing porphyrin metal complex (iron porphyrin): 2.5 parts by weight of iron porphyrin, 6 parts by weight of polyisobutylene succinimide, 100 parts by weight of 6# solvent oil, 0.6 parts by weight of p-tert-butylphenol parts by weight, mixed uniformly at 50°C to prepare a fuel additive containing iron porphyrin.
[0049] Solubility of fuel additives containing porphyrin metal complexes (iron porphyrin): After mixing fuel additives containing porphyrin metal complexes (iron porphyrin) and fuel oil at a volu...
Embodiment 2
[0054] Preparation of porphyrin metal complex (octaethylporphyrin-platinum): dissolve octaethylporphyrin (50mmol) and platinum chloride (100mmol) in N'N-dimethylformamide (50mL), Under magnetic stirring, the reaction system was heated to 120°C for 2 hours, and the reaction mixture was poured into ice water to precipitate octaethylporphyrin-platinum, filtered with suction, washed with deionized water, and dried in vacuum to obtain octaethylporphyrin Phenyl-platinum complexes.
[0055] Preparation of fuel additive containing porphyrin metal complex (octaethylporphyrin-platinum): 7.5 parts by weight of octaethylporphyrin-platinum complex, 14 parts by weight of polyisobutylamine, 100 parts by weight of 120# solvent oil , 0.6 parts by weight of BHT, mixed uniformly at 30°C to prepare a fuel additive containing octaethylporphyrin-platinum complex.
[0056] Solubility of fuel additives containing porphyrin metal complexes (octaethylporphyrin-platinum): the ratio of fuel additives co...
Embodiment 3
[0061] Preparation of porphyrin metal complex (cerium porphyrin): tetraphenylporphyrin (50mmol) and cerium nitrate (150mmol) were dissolved in N'N-dimethylformamide (50mL), and the The temperature of the reaction system was raised to 150° C. for 8 hours, and the reaction mixture was poured into ice water to precipitate cerium porphyrin, filtered with suction, washed with deionized water, and dried in vacuum to obtain cerium porphyrin.
[0062] Preparation of fuel additive containing porphyrin metal complex (cerium porphyrin): 5.5 parts by weight of cerium porphyrin, 10 parts by weight of polyisobutylene succinimide, 100 parts by weight of 6# solvent oil, 0.5 parts by weight of p-tert-butylphenol parts by weight, uniformly mixed at 50°C to prepare a fuel additive containing cerium porphyrin.
[0063] Solubility of fuel additives containing porphyrin metal complexes (cerium porphyrin): After mixing fuel additives containing porphyrin metal complexes (cerium porphyrin) and fuel o...
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