Hydrogenation tackifying nickel ionic liquid catalyst, and preparation method, application and application method thereof
The technology of an ionic liquid and an application method is applied in the field of hydrogenation and thickening nickel-based ionic liquid catalyst and preparation thereof, and achieves the effects of wide application prospect, mild reaction conditions and simple preparation method
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
preparation example Construction
[0032] The present invention also provides a method for preparing the catalyst, which comprises the following steps: after mixing the raw materials, heating, stirring and ultrasonication are performed in sequence to obtain the hydrogenated and thickened nickel-based ionic liquid catalyst.
[0033] In the present invention, the temperature of the heating and stirring is preferably 60 to 70°C, more preferably 62 to 68°C, and more preferably 64 to 66°C.
[0034] In the present invention, the rotational speed of the heating and stirring is preferably 50-100 rpm, more preferably 60-90 rpm, more preferably 70-80 rpm, and the heating and stirring time is preferably 2-5 min, more preferably 3-4 min, More preferably, it is 3.4 to 3.6 minutes.
[0035] In the present invention, after the heating and stirring is completed, the mixed solution exhibits yellow-green color.
[0036] In the present invention, the frequency of the ultrasonic is preferably 28-40KHz, more preferably 30-38KHz, m...
Embodiment 1
[0049] Take 2 parts of chloride, 50 parts of aromatic hydrocarbon solvent oil, and 20 parts of tetralin; the molar ratio of nickel chloride hexahydrate and 1-butyl-3-methylimidazole chloride in the chloride is 0.4.
[0050] The weighed raw materials were mixed, stirred at 50 rpm for 2 min at 60° C., and then ultrasonicated at a frequency of 28 KHz for 1 min to obtain a hydrogenated and thickened nickel-based ionic liquid catalyst.
[0051] The catalyst prepared in this example was mixed with high-sulfur and low-viscosity coal at a liquid-solid ratio of 0.70, then the pressure was lowered to 1MPa in a hydrogen atmosphere, and the temperature was raised from room temperature to 350°C at a heating rate of 5°C / min, and then reacted for 70min. , after the reaction is completed, it is naturally cooled to room temperature in a closed state, and then filtered to obtain a solid substance, and the solid substance is dried at 100 ° C for 10 hours to obtain a solid product.
[0052] The r...
Embodiment 2
[0054] Take 2.5 parts of chloride, 52 parts of aromatic hydrocarbon solvent oil and 22 parts of tetralin; the molar ratio of nickel chloride hexahydrate and 1-butyl-3-methylimidazole chloride in the chloride is 0.43.
[0055] The weighed raw materials were mixed, stirred at 63° C. at 80 rpm for 2.5 min, and then sonicated at a frequency of 28 KHz for 1.5 min to obtain a hydrogenated and thickened nickel-based ionic liquid catalyst.
[0056] The catalyst prepared in this example was mixed with high-sulfur and low-viscosity coal at a liquid-solid ratio of 0.80, then the pressure was lowered to 1.3 MPa in a hydrogen atmosphere, and the temperature was raised from room temperature to 365 °C at a heating rate of 5 °C / min, and then reacted. 65min, after the reaction was completed, it was naturally cooled to room temperature in a closed state, and then filtered to obtain a solid substance, and the solid substance was dried at 103° C. for 9.5h to obtain a solid product.
[0057] The r...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More