Improvements in copper/tin/lead production
A black copper, copper-rich technology, applied in the field of copper production, improved co-production of copper and solder flow from primary and secondary raw materials, can solve the problem of reducing the acceptability of nickel-containing raw materials
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[0300] In an embodiment, the method according to the present invention further comprises the step of cooling the first rough solder metal composition and / or the second rough solder metal composition and / or the pre-refined solder metal composition to a temperature of at most 825°C, to produce a bath containing a first upper layer of dross that floats under the force of gravity above the first liquid melt-conditioned solder phase. Applicants have discovered that this further downstream processing step can remove significant amounts of copper and other unwanted metals from the rough solder. Further details of this step can be found in WO 2018 / 060202 A1 or similar documents. Applicants have further discovered that this cooling step, in combination with some other downstream processing steps on the lead / tin stream, can at least partially replace the pretreatment with silicon metal mentioned elsewhere herein. This is advantageous because metallic silicon is a relatively rare proces...
Embodiment
[0323] The following examples illustrate preferred embodiments of the present invention. This example is in figure 1 is further shown, where figure 1 A flow chart showing the core part of the method according to the invention is shown. In the process, starting with black copper composition 1, a refined anode grade copper product 9, a high copper metal composition by-product 22, two rough solder metal composition products 18 and 26 and three are recovered from various feedstocks Kinds of waste residues 12, 20 and 28 and other parts.
[0324] exist figure 1 , the numerals indicate the following claimed features:
[0325] 1. Black copper composition feed to step b) (100)
[0326] 2. Fresh feed to step b) (100)
[0327] 3. The first copper refining slag
[0328] 4. The first copper-rich metal phase
[0329] 5. Fresh feed to step h) (200)
[0330] 6. Second copper refining slag
[0331] 7. The second copper-rich metal phase
[0332] 8. The third copper refining slag
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