The invention discloses a method for detecting and analyzing halogenated organic matters in landfill
leachate and polluted water thereof, which comprises the following steps: acidifying a sample by using
formic acid through a combined
solid-phase extraction method of HLB
solid-phase extraction and PPL
solid-phase extraction, respectively performing solid-phase extraction and enrichment on the
water sample by using an HLB solid-phase extraction column and a PPL solid-phase extraction column, and eluting by using
methanol, the method comprises the following steps of: performing solid-phase extraction and enrichment on a
water sample, respectively performing FT-ICR MS detection on the solid-phase extraction and enrichment samples, respectively performing molecular formula matching,
molecular screening, molecular information summarization and sample data
statistical analysis on two types of FT-ICR MS detection data, taking a union set of the two types of FT-ICR MS detection data to obtain all soluble halogenated organic matters (HOCs) in the
water sample, and then visualizing the types of the halogenated organic matters through a mulberry-based diagram. According to the method, the molecular information of HOCs in the sample, especially the soluble halogenated
organic matter containing Cl and Br molecules, can be more sufficiently obtained, and the occurrence characteristics, molecular characteristics and distribution characteristics of halogenated soluble
organic matter molecules in the sample in a
water body can be more clearly and comprehensively displayed.