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Special super-tough nylon capable of being subjected to blow molding

A nylon and super-tough technology, applied in the field of blow-moldable super-tough nylon, can solve the problems of complicated preparation process of blow-mold nylon, limited use of nylon materials, poor oxidation resistance, etc., to increase recoupling ability and increase dispersion. effect, high dispersibility

Pending Publication Date: 2022-07-29
台州俪盛塑料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nylon material has a series of advantages such as high strength, good wear resistance, and good impact performance, but nylon material has shortcomings such as poor low-temperature toughness, acid and alkali corrosion resistance, high water absorption rate, and poor oxidation resistance. These shortcomings are serious. Limits the use of nylon materials
[0003] In the prior art, there are many methods for modifying nylon to improve its performance. CN108329686A discloses a preparation method of a high-performance nylon nanocomposite material, which uses polyamino acid modified nanoparticles to modify nylon to improve the mechanical properties of nylon. performance, dimensional stability, but its modification process is complicated, and it is difficult to carry out large-scale production; CN102382452A discloses a preparation method of nano-modified nylon composite material, and the nano-modifier described in it is polyhedral oligomeric siloxane (POSS), its made nano material has higher toughness and strength; CN109836813B discloses nylon 6 composite material and preparation method thereof, and it passes through the nano SiO of adipic acid graft modification 2 As one of the formulations, nylon has good compatibility after processing, and the obtained nylon 6 composite material has excellent mechanical properties and flame retardancy, but the above-mentioned nano-modification process cannot really solve the problem of nano-particle dispersion , and the preparation process of blow-molded nylon is complicated in actual production, and various additives need to be added to meet different needs

Method used

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  • Special super-tough nylon capable of being subjected to blow molding
  • Special super-tough nylon capable of being subjected to blow molding

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Embodiment 1

[0028] A special super-tough nylon for blow molding, each component is calculated according to the mass fraction, including: 70% of PA6 resin, 29% of compatibilizer, 0.5% of amide functionalization assistant, and 0.5% of other assistants.

[0029] Among them, the amide functionalization assistant is loaded with SiO 2 Zn-BTC-MOF material; the compatibilizer is a commercially available POE graft material; other additives are silicone powder; PA6 is PA6 with a viscosity of 2.6;

[0030] The specific preparation method of the Zn-BTC-MOF material loaded with SiO2 is as follows:

[0031] Step (1) preparation of Zn-BTC-MOF: 8 mol of trimesic acid (H 3 BTC) was completely dissolved in 100L of absolute ethanol, and 100L of water and 12mol of Zn(NO) were added under stirring at room temperature. 3 ) 2 , after the solution is clear, add 30% NaOH solution under stirring, the amount of NaOH in the NaOH solution is 24 mol, stir for 1 h, stop stirring after the reaction is completed, and ...

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Abstract

The invention belongs to a composite material modification method of nylon PA6, and particularly relates to special super-tough nylon capable of blow molding, which is based on common nylon PA6 and comprises 70-90 parts of PA6 resin, 10-29 parts of a compatilizer, 0.5-1 part of an amide functionalized auxiliary agent and 0.5-1 part of other auxiliary agents, and the amide functionalized auxiliary agent is a Zn-BTC-MOF material loaded with SiO2. The material is simple in manufacturing process, replaces imported products and can be applied to the fields of automobiles, flow line production equipment and the like.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a special super-tough nylon for blow molding. Background technique [0002] Nylon (PA), the scientific name is polyamide, has many types, such as PA6, PA66, PA9, PA1010 and so on. Nylon has become the most widely used type of engineering plastics due to its high strength, good wear resistance, and good processing fluidity. Among them, nylon 6 is a common engineering plastic with good performance and can be widely used in the fields of automobiles, machinery, construction, electronic appliances and weapons and equipment. Nylon materials have a series of advantages such as high strength, good wear resistance, and good impact performance, but nylon materials have shortcomings such as poor low temperature toughness, poor acid and alkali corrosion resistance, high water absorption, and poor oxidation resistance. These shortcomings are serious. Limits the use of...

Claims

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Application Information

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IPC IPC(8): C08L77/02C08L51/06C08L87/00C08K9/12C08K3/36
CPCC08L77/02C08G83/008C08L51/06C08L87/00C08K9/12C08K3/36
Inventor 杨家山陈林卢小龙应光奇杨伟楼优萍冯勇沈金飞
Owner 台州俪盛塑料有限公司
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