Application of 3D printing hydrogel and bionic adhesion device
A 3D printing and hydrogel technology, applied in applications, household appliances, processing and manufacturing, etc., can solve the problems of restricting the practical application of bionic high-precision mechanical adhesion devices, difficulty in obtaining mechanical properties of adhesion devices, and poor formation of matrix materials , to achieve excellent driving performance, excellent adhesion performance, and high manufacturing freedom
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[0058] In the present invention, when the biomimetic adhesion device is a manual biomimetic hydrogel adhesion device or a pneumatic biomimetic hydrogel adhesion device, the preparation method of the hydrogel adhesion structure preferably includes the following steps:
[0059] Provide 3D printing hydrogel ink;
[0060] According to the structure of the hydrogel adhesion structure, the 3D printing hydrogel ink is subjected to photo-curing 3D printing to obtain the hydrogel adhesion structure.
[0061] In the present invention, unless otherwise specified, all preparation raw materials are commercially available products well known to those skilled in the art.
[0062] The present invention provides 3D printing hydrogel ink.
[0063] The present invention does not have any special limitation on the 3D printing hydrogel ink, which can ensure that the mechanical properties of the prepared hydrogel material meet the requirements of tensile strength of 1-20 MPa and elongation at brea...
Embodiment 1
[0087] Acrylamide (15.975 g) and acrylic acid (1.459 g) were dissolved in a mixed solution of dimethyl sulfoxide (15 mL) and deionized water (35 mL) by magnetic stirring, followed by the addition of N,N-methylenebisacrylamide (0.038 g), LAP (0.0872g), tartrazine (0.015g), stir to dissolve, and obtain 3D printing hydrogel ink;
[0088] Put the 3D printed hydrogel ink into a smooth 3D printer material box, and use a light-curing 3D printer to print according to the model program (the light source intensity of the 3D printer is 250mW, the slice layer thickness is 0.1mm, the bottom layer exposure time is 25s, The exposure time of the remaining layers is 10s), and a chemically cross-linked hydrogel material can be obtained.
[0089] After soaking the chemically cross-linked hydrogel material in an aqueous solution of zirconium oxychloride (0.1 mol / L) for 48 hours, it was then soaked in deionized water for 48 hours to obtain a hydrogel material (physicochemical cross-linking).
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Embodiment 2
[0092]Acrylamide (15.975 g) and N-acryloyl glycinamide (10 g) were dissolved in a mixed solution of dimethyl sulfoxide (25 mL) and deionized water (25 mL) by magnetic stirring, followed by the addition of polyethylene glycol diacrylate (PEGDA750, 0.076g), LAP (0.0872g) and tartrazine (0.03g), stir to dissolve, and obtain 3D printing hydrogel ink;
[0093] Put the 3D printing hydrogel ink into the material box of the light-curing 3D printer, and use the light-curing 3D printer to print according to the model program (the light source intensity of the 3D printer is 280mW, the slice layer thickness is 0.1mm, the bottom layer exposure time is 20s, The exposure time of the remaining layers is 8s) to obtain a hydrogel material.
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Abstract
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