Complete solid state nanocrystalline solar battery and its preparing method

A solar cell and nanocrystalline technology, applied in circuits, photovoltaic power generation, electrical components, etc., to achieve the effect of good stability and low production cost

Inactive Publication Date: 2006-01-18
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

There are no patent applications for the preparation of all-solid-state dye-sensitized solar cells using conductive polymers or inorganic / conductive polymer synergistic systems as p-type semiconductor materials

Method used

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  • Complete solid state nanocrystalline solar battery and its preparing method
  • Complete solid state nanocrystalline solar battery and its preparing method
  • Complete solid state nanocrystalline solar battery and its preparing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Clean the conductive glass and prepare TiO by spin-coating method 2 dense layer. Then TiO 2 The sol is uniformly coated on the electrode and sintered at 450°C to form TiO 2 The nanocrystalline electrode has a film thickness of 1-10 μm. Immerse the electrode in the ethanol solution of the ruthenium complex, let it stand for 2 days, take it out, rinse it repeatedly with ethanol, and dry it. Polyaniline with a conductivity of 300 S / cm was coated on the dye-sensitized electrode as a solid electrolyte in the form of a drop film. Finally, the platinum-plated conductive glass is used as the counter electrode to form a solar cell. Its open-circuit photovoltage is 173mV, and the short-circuit photocurrent is 0.37mA / cm 2 , The photoelectric conversion efficiency is 0.02%.

Embodiment 2

[0035] Clean the conductive glass and prepare TiO by spin-coating method 2 dense layer. Then TiO 2 The sol is uniformly coated on the electrode and sintered at 450°C to form TiO 2 The nanocrystalline electrode has a film thickness of 1-10 μm. Immerse the electrode in the ethanol solution of the ruthenium complex, let it stand for 2 days, take it out, rinse it repeatedly with ethanol, and dry it. Polyaniline with a conductivity of 100 S / cm was coated on the dye-sensitized electrode as a solid electrolyte in the form of a drop film. Finally, the platinum-plated conductive glass is used as the counter electrode to form a solar cell. Its open-circuit photovoltage is 319mV, and the short-circuit photocurrent is 0.51mA / cm 2 , The photoelectric conversion efficiency is 0.08%.

Embodiment 3

[0037] Clean the conductive glass and prepare TiO by spin-coating method 2 dense layer. Then TiO 2 The sol is uniformly coated on the electrode and sintered at 450°C to form TiO 2 The nanocrystalline electrode has a film thickness of 1-10 μm. Immerse the electrode in the ethanol solution of the ruthenium complex, let it stand for 2 days, take it out, rinse it repeatedly with ethanol, and dry it. Polyaniline with a conductivity of 10 S / cm was coated onto the dye-sensitized electrode as a solid electrolyte in the form of a drop film. Finally, the platinum-plated conductive glass is used as the counter electrode to form a solar cell. Its open-circuit photovoltage is 332mV, and the short-circuit photocurrent is 0.72mA / cm 2 , the photoelectric conversion efficiency is 0.1%.

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Abstract

The invention is an all-solid nano crystal solar battery and making method. It smears the plasm of semiconductor nano material on the transparent base piece of the electric thin film, then making high-temperature sintering to prepare wide-band semiconductor nano crystal thin film, and then immerge in the solution to obtain sensitized dye nano crystal semiconductor electrode as anode; uses electric polymer or inorganic / electric polymer cooperative system as P-type material to smear the anode, and uses the electric base piece plated with Pt or Au as pair electrodes to compose the solar battery.

Description

technical field [0001] The invention belongs to the field of nanocrystalline solar cells, and in particular relates to an all-solid-state nanocrystalline solar cell prepared by using a conductive polymer or an inorganic / conductive polymer synergistic system as a p-type material and a preparation method thereof. Background technique [0002] Since the Swiss scientist Gratzel reported the research work of the dye-sensitized nanocrystalline solar cell in 1991, it has become the most potential new type of solar cell due to its high efficiency and cheap characteristics. Such batteries consist of nanoporous electrodes (sintered TiO 2 Semiconductor nanoparticle film), dye molecules for absorbing photons (commonly used as ruthenium complexes), electrolyte and counter electrode for reducing media. When the electrolyte is selected as containing I - / I 3 - When using acetonitrile or ethanol / propanol solution, its photoelectric conversion efficiency can reach ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/04
CPCY02E10/50
Inventor 谭庶欣翟锦万梅香江雷
Owner INST OF CHEM CHINESE ACAD OF SCI
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