184 results about "Nanocrystalline thin films" patented technology

A method and structure for forming magnetic alloy nanoparticles includes forming a metal salt solution with a reducing agent and stabilizing ligands, introducing an organometallic compound into the metal salt solution to form a mixture, heating the mixture to a temperature between 260° and 300° C., and adding a flocculent to cause the magnetic alloy nanoparticles to precipitate out of the mixture without permanent agglomeration. The deposition of the alkane dispersion of FePt alloy particles, followed by the annealing results in the formation of a shiny FePt nanocrystalline thin film with coercivity ranging from 500 Oe to 6500 Oe.

A process integration is disclosed for fabricating non-volatile memory (NVM) cells (105-109, 113-115) on a first flash cell substrate area (111) which are encapsulated in one or more planar dielectric layers (116) prior to forming an elevated substrate (117) on a second CMOS transistor area (112) on which high-k metal gate electrodes (119-120, 122-126, 132, 134) are formed using a gate-last HKMG CMOS process flow without interfering with the operation or reliability of the NVM cells.

The invention mainly relates to a novel light-emitting thin film, and particularly relates to a PEI (polyethyleneimine) based high-efficiency perovskite quantum dot light-emitting thin film and a preparation method thereof. PEI and ZnO are used as electron transporting layers; and the perovskite quantum dot light-emitting thin film is used as a fluorescent layer. The PEI based high-efficiency perovskite quantum dot light-emitting thin film structurally comprises a substrate (1) formed by an ITO (indium tin oxide) thin film, a ZnO layer (2) deposited on the substrate, a PEI layer (3) spin-coated on a ZnO nanocrystalline thin film, and perovskite quantum dots (4) spin-coated on the ZnO nanocrystalline thin film coated with PEI, wherein the ZnO layer and the PEI layer are combined into an electron migration layer together; and the inorganic cesium lead halide perovskite quantum dots are used as a light-emitting layer (4). Compared with fluorescence quantum yield of a perovskite quantum dot light-emitting thin film prepared by an existing process, fluorescence quantum yield of the perovskite quantum dot light-emitting thin film prepared by the preparation method disclosed by the invention can be improved by 2 to 3 times.

The invention discloses a method for preparing a modified titanium dioxide nanotube dye-sensitized photoanode thin film, and belongs to the field of dye-sensitized solar cells. The method comprises the following steps of: mixing titanium salt solution and a dopant to prepare doped titanium dioxide sol A; preparing titanium dioxide nanotubes by a hydrothermal synthesis method; dipping the titanium dioxide nanotubes in metal or non-metal dopant solution to obtain titanium dioxide nanotube powder B; mixing the powder B and the sol A and fully grinding to obtain titanium dioxide nanocrystalline slurry C; coating the sol A onto a conductive substrate and drying; coating the obtained nanocrystalline slurry C onto the conductive substrate on which the sol A is coated to obtain a titanium dioxide nanotube thin film electrode D; drying the D and performing thermal treatment to obtain a doped titanium dioxide nanotube nanocrystalline thin film electrode E; and soaking the E in ethanol solution of 4,4'-dicarboxylic bipyridyl ruthenium, washing with absolute ethanol and drying with nitrogen gas. The method has the advantages of simple preparation process, high repeatability and low cost.

The embodiment of the invention discloses a preparation method of a light anode of a flexible dye sensitized nano crystalline organic photovoltaic cell. The method comprises the following steps: dipping or spraying a uniform nano crystalline slurry on a flexible antioxidant metal wire mesh selected as a substrate, thus forming a nano crystalline thin film on the surface of the wire mesh; carryingout high-temperature heat treatment on the substrate attached with the nano crystalline thin film, thus preparing the metal wire mesh with the porous nano crystalline thin film; and then soaking the metal wire mesh with the porous nano crystalline thin film in a dye solution, thus realizing the dye sensitive effect on the nano crystalline thin film. The invention also discloses a light anode and a photovoltaic cell which are obtained according to the preparation method. According to the scheme provided by the invention, under the condition that the electric conductivity and transmission of light of the light anode can not be lowered, the DSSC (dye sensitized solar cell) has a flexible characteristic, and the nano crystalline thin film is subjected to high-temperature sintering treatment, thus the porous nano crystalline thin film is obtained, and the capability of dye absorption is improved, so that the assembled cell has the performance of higher photoelectric conversion efficiency.

The present invention relates to a nano-crystal thin film and a low temperature preparation method. The thin film is provided with graded structure and uses nano-crystal titania particles of different sizes as raw materials to add specific chemical bonds or function masses to the surfaces of the nano-crystal particles through a method of surface modification. The materials are mixed in inorganic or organic solution to be prepared into carcass slurries before graded, which are made into films on a flexible conductive basement or any other basement through a simple film making method. Under a low reaction temperature, the particles in the thin films are well connected through chemical sintering, and the nano-crystal particles are connected through good chemical bonds. The whole thin film is provided with high mechanical strength. Flexible dye sensitization solar energy batteries, which are assembled from the thin films, are provided with the high photoelectric conversion efficiency. The thin film and the low temperature preparation method is predicated to be provided with a wide application prospect in photoelectric transformation and photo-catalyst fields.

The invention relates to a method for preparing a Cu2ZnSnS4 nanocrystalline thin-film solar cell, which comprises the following steps of: performing chemical bath deposition on a ZnS film to form a buffer layer by taking molybdenum-plated metal aluminum as a flexible substrate and a film prepared from hydrophilic Cu2ZnSnS4 nanocrystalline as an absorption layer; and assembling the solar cell by performing magnetron sputtering on intrinsic ZnO, ITO and Ni-Al electrodes. By the method, vacuum equipment is not required, production cost is reduced, and convenience is brought to mass production; raw materials for preparing the Cu2ZnSnS4 solar cell are environment-friendly materials and have low prices, so that the cost of the solar cell is reduced to the great extent; and the method has a good application prospect.

The invention relates to a blanket type light anode for a dye sensitized solar cell and a preparation method thereof, which belong to the technical field of solar cells. In the blanket type light anode for the dye sensitized solar cell, a layer of blanket type structure, namely a titanium dioxide nano linear array film is increased on the basis of the conventional multiporous titanium dioxide nanocrystalline film light anode. Due to the existence of a titanium dioxide nano linear array, more fuel sensitizing agents can be adsorbed; at the same time, because multiporous titanium dioxide nanocrystal interfaces are greatly reduced, crystal boundary potential barriers which need to be overcome during electronic transmission are reduced to accelerate the effective separation of photoelectron-cavity pairs in dye molecules; the multiporous titanium dioxide nanocrystalline film at the bottom can effectively reduce leakage current and dark current; and the blanket type light anode for the dye sensitized solar cell provided by the invention has higher photoelectric conversion efficiency. The preparation method has the advantages of simpleness, mild reaction condition and safe and reliable process.

A method to monitor a nanocrystalline film surface structure and the thickness thereof uses the surface structure characteristics of the vapor deposition nanocrystalline thin films having the low volume fraction to make a nanocrystalline thin film become a nonhomogeneous double-layer structure comprising a dense bottom layer having high index of refraction and a surface layer having the low volume fraction. The optical module of this double-layer structure can be used to simulate the characteristics of the nanocrystalline structure. That is to say, in the thin film deposition manufacturing process, if the thin film structure satisfies the optical module of the double-layer structure, this means it has the nanocrystalline characteristic. Hence, in the manufacturing process, use the optical instruments to measure the thin film and the substrate and to calculate the optical parameters; thus a nanocrystalline film surface structure and the thickness thereof can be precisely monitored immediately.

The invention discloses a method of preparing a metal nano-crystal film, which includes: A. a layer of metal film is deposited on an insulating substrate; B. conductin fast annealing with high temperature in the inert gas, so as to form the separated metal nano-crystal film. The metal nano-crystal film prepared by the invention has very good charge retention and storage characteristics as well as processing compatibility with traditional silicon planes, and is very applicable in preparing high-performance semiconductor memory components. The method of preparing a metal nano-crystal film provided by the invention greatly simplifies the preparing technology, reduces the preparing cost, improves the technological stability and preparing efficiency, and is very good for wide promotion and application of the invention.

The invention is a crystalline silicon solar battery adopting emission region on film silicon back, belonging to a new structured photovolt battery, and its key point is depositing a layer of silicon film on the back to form heterogeneous PN junction on an N-type monocrystalline silicon substrate so as to replace the homogenous PN junction on the right side of a battery, prepared by routine diffusion, where the deposited silicon film can noncrystalline, microstalline, or nanocrystalline film; the heterogenerous PN junction forming method can directly deposit a P-type silicon film on the N-type monocrystalline silicon, and can firstly deposit a layer of intrinsic silicon film on the N-type monocrystalline silicon and then deposit the P-type silicon film. Thus, the battery efficiency can reach above 20%.

The invention discloses a production method of a dye-sensitized TiO2 film based gas sensor. The method comprises steps of: choosing a substrate suitable for subsequent film plating; preparing electrodes on the substrate through a film plating method; preparing a nanocrystalline TiO2 film on the substrate with electrodes by a magnetron sputtering method; selecting a suitable dye sensitizing material according to gas to be tested and dissolving the dye sensitizing material in a compatible solvent to prepare a dye solution; immersing the nanocrystalline TiO2 film into the dye solution for 12-8 h; taking out the nanocrystalline TiO2 film; removing impurities with ethanol; and drying and baking in an oven at 30-80 DEG C for 1-5 h. According to the invention, the nanocrystalline TiO2 film is employed as the substrate material, and the dye sensitizing material is employed as a sharpening material; dye molecules encapsulate the TiO2 molecules while filling gaps between the TiO2 crystals; and the gas sensor can be used for qualitative and quantitative analysis on gas at room temperature through changes of the sensor resistance, and has high sensitivity and wide detection range.

A highly porous flexible carbon counter electrode used for solar battery of the dye sensitize amino-quinoline thin film is provided, which comprises an composite film composed by a carboform membrane layer with a microstructure of three dimensional porous diffusion and polyafluortetraethylene thin membrane layer; a titanium dioxide semiconductor expanded film equipped on the said composite film as the working electrode of the semiconductor. The preparation method of the electrode is: greying the arboform membrane and platinum black to the nanometer-carried; sensitizing the counter electrode used of the solar battery with the dye of the composite film, which forms dye sensitize solar battery with the working electrode of the semiconductor oxide based on the rigid stratum; greying the arboform membrane and platinum black to the nanometer-carried, which is composed with the polyafluortetraethylene thin membrane to form a composite film, which forms dye sensitize solar battery with the working electrode of the semiconductor oxide based on the rigid stratum.

The invention discloses a preparation method for a ZnO nanocrystalline thin-film transistor type UV detector. The UV detector successively comprises a low-resistance Si layer, a SiO2 insulating layer, a ZnO nanocrystalline layer and an Au electrode from bottom to top. The preparation method comprises the steps of firstly, preparing a ZnO nanocrystalline colloid dispersed phase; secondly, conducting the spin coating process of the colloid dispersed phase on the SiO2 surface of Si/SiO2, and then annealing; finally, plating the Au electrode to complete the preparation of the UV detector. Compared with a traditional UV detector, the above UV detector prepared through the above method is low in dark current, high in response sensitivity, quick in response time, simple in structure and low in manufacturing cost. Therefore, the method has an important application value in the fields of military, civilian and special aspects.

The invention relates to a preparation method of a high-density silicon nano-crystalline thin film, and the preparation method comprises: a silicon dioxide layer is formed on a silicon substrate; silicon monoxide is taken as a target material to be deposited on the silicon dioxide layer by the electron beam evaporation method, thereby forming a mixture thin film layer; silicon ions are implanted in the mixture thin film layer; and the mixture thin film layer is annealed to form the high-density silicon nano-crystalline thin film layer. The preparation method prepares the high-density silicon nano-crystalline thin film by the electron beam evaporation of the silicon monoxide and the ion implantation method for matching, thereby having the advantages of simple process steps, multiple purposes and ability of being compatible with the traditional Si-based CMOS technology. The surface density of the silicon nano-crystalline which is prepared by using the method can be up to 10<12>cm<minus 1> level, and the diameter of particles is in the range of 5-8nm. The preparation method is mainly applied in the preparation of key components of the third generation of silicon-based solar cell chips, silicon single electron devices, single electron memories, silicon nano-crystalline floating gate memories and other aspects, thereby being applicable to the requirements on large-scale production.

The invention discloses a stannum dioxide nano crystal state film preparing method, including the following steps; (1) washing the surface of a substrate; (2) placing the substrate in the mixed solution of oil of vitriol and oxydol to hydroxylate the surface; (3) dipping the substrate X(CH2)nSi(OH3)3, X(CH2)nSiCl3 or HS(CH2 m solution for soaking, so as to form an organic molecular self-composing single-layer film on the surface; (4) soaking the substrate with mercaptoand alkyl groups as head groups by the mixed solution of oxydol and acetic acid; or soaking the substrate with ethylene as head group by saturated potassium monopersulfate solution, so as to functionalize organic molecular self-composing layer on the surface; (5) dipping the substrate in SnCl4 HCl solution or SnF2 boric acid solution to make a stannum dioxide nano crystal state film. It provides a functionalized surface liquid-phase deposition technique and the prepared products have rutile crystal shaped structure.

The invention relates to the technical field of solar cells, and discloses a method for preparing a copper-zinc-tin-sulfur thin-film solar cell through interfacial modification. The copper-zinc-tin-sulfur thin-film solar cell is of a multi-layer film structure, and comprises a substrate, an Mo back contact layer, a copper-zinc-tin-sulfur light absorption thin-film layer, a CdS buffer layer, a ZnO window layer, an MgF2 anti-reflecting film and an Ni-Al metal gate electrode. According to the method, through interfacial modification, a Cu2S1-xSex pre-fabricating layer is prepared on the Mo back contact layer, wherein x is greater than or equal to 0 and smaller than or equal to 1; copper-zinc-tin-sulfur nano-ink is used for film forming on the pre-fabricating layer, so that diffusion confusion and chemical reaction of the Cu2S1-xSex pre-fabricating layer and a copper-zinc-tin-sulfur nanocrystalline thin-film are realized through high-temperature annealing technology; on the basis that other impurity elements are not introduced, the disadvantage that copper-zinc-tin-sulfur nanocrystalline is low in film-forming adhesive force is effectively overcome, and a copper-zinc-tin-sulfur light absorption thin-film layer with good crystallinity, uniform appearance, single phase and high adhesive force is obtained, thus the copper-zinc-tin-sulfur thin-film solar cell with high efficiency is prepared.

The invention belongs to solar battery technique field and to one nanometer film sensitive transistor solar battery and its process method, which in the solar energy battery, it covers one layer of liquid or quartz solid or solid electrolyte on wide nanometer semi-conductor film surface with other side coated with foil layer conductive glass to form clamper shape.

A method for preparing rare earth doped strontium cerate nanometer crystal thin film by organic polymer presoma method is disclosed. It is prepared by: preparing initial solution with cerous nitrate, strontium nitrate or strontium acetate, rare earth oxide as raw materials, determining the proportion by prepared thin film composition, the composition of thin film is SrCe1-xRExO3, the range of x volume is 0.02-0.20, concentration of initial solution is 0.1-0.4mol/L, taking ethylene as complexant, the adding account of ethylene is 2-6 times of metal ionic total account, mixing and supersonic oscillating, heating in water bath under 50-100deg.C, adjusting PH value, the system being heated reacting to produce organic polymer, film coating with 1500-3000rpm circulating speed on required chip by glue equalizer when viscosity reaching 100-300cP, infrared drying or vacuum drying, second film coating, drying until reaching the required thickness, and producing nanometer crystal thin film under 900deg.C reacting.

The invention belongs to the technical field of application of all-inorganic metal halide nanocrystals, and discloses application of a non-self-absorption nanocrystal as a scintillator and a preparation method of the non-self-absorption nanocrystal. The chemical general formula of the nanocrystal is Cs3Cu2X5, and X is selected from Cl, Br and I. The preparation method of the scintillator comprisesthe following steps: coating a glass sheet with an organic solution of Cs3Cu2X5 nanocrystalline, and naturally volatilizing an organic solvent in air to form a Cs3Cu2X5 nanocrystalline film which canbe used as the scintillator. The Cs3Cu2X5 nanocrystalline thin film is prepared to serve as a scintillator to be applied to X-ray imaging, the efficient scintillation performance is shown, and meanwhile the Cs3Cu2I5 nanocrystalline scintillator is applied to X-ray imaging, and the very high resolution is shown as high as 0.32 mm. The preparation method is simple in preparation process, easy to implement and low in cost, and has important application value and important prospect in medical diagnosis, national defense industry and manufacturing industry. And meanwhile, the defects of the traditional lead-containing halogen perovskite nanocrystalline can be overcome.

The invention discloses a low-temperature preparation method of a Cu2ZnSnS4 or Cu2CdSnS4 nanocrystalline film with low cost and high quality, comprising the following steps of: firstly adding a certain amount of copper sulphate, zinc chloride or cadmium chloride, stannous chloride and thioacetamide into a beaker with deionized water, letting glass which undergoes ultrasonic cleaning by the use ofalcohol, acetone and deionized water vertically suspend inside the beaker; adding dropwisely a diluted hydrochloric acid solution into the beaker to adjust the pH value and make the solution to stay in the acid condition; heating up and reacting for a certain time at a certain stirring rate, carrying out annealing treatment on the glass, on which the Cu2ZnSnS4 or Cu2CdSnS4 nanocrystalline film grows, in Ar and H2S(5%) atmospheres to finally obtain the high-quality Cu2ZnSnS4 or Cu2CdSnS4 nanocrystalline film. The invention has the following advantages: the nanocrystalline preparation method issimple; the synthesis temperature is low; the cost of precursor materials is low; and the nanocrystalline film prepared is uniform and compact. The Cu2ZnSnS4 or Cu2CdSnS4 nanocrystalline film prepared in the invention can be used as an absorbed layer for photovoltaic devices or a good thermoelectric material.

The invention discloses a SnS nanocrystalline thin film preparation method, which adopts an ink method. The preparation method comprises two steps: (1) preparation of SnS nanocrystalline ink including preparing a Sn-source precursor solution and a S-source precursor solution, respectively adding the S-source precursor solution and high-temperature injecting the Sn-source precursor solution into a three-neck flask, refluxing in the N2 atmosphere to prepare a SnS nanocrystalline solution, centrifugally cleaning the nanocrystalline solution with absolute ethanol, and ultrasonically dispersing in absolute ethanol to obtain the ink; (2) thin film preparation including soaking a glass substrate in the nanocrystalline ink, and preparing the thin film by dip-coating method. The preparation method is simple, and can control the formation and growth speed of crystal nucleus. Additionally, the preparation method is easy in controlling stoichiometric ratio, and is suitable for preparation of multicomponent thin film.