Liquid crystal photoelectric component with compensating coating, and its prepn. process
A technology for optoelectronic components and coatings, applied in polarizing components, optics, nonlinear optics, etc., can solve problems such as increasing complexity, limiting the potential thickness of coatings, and achieving the effect of easy manufacturing
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[0048] Example 1: Polymer I (synthesis):
[0049] At 10°C, 4,4'-hexafluoroisopropylidene-bisphenol (33.62 g, 0.1 mole) and triethylamine (22.3 g, 0.22 mole) were mixed in dichloromethane (200 mL), and the Terephthaloyl chloride (10.15 g, 0.05 mole) and isophthaloyl dichloride (10.15 g, 0.05 mole) dissolved in dichloromethane (100 mL) was added with stirring. Then, the temperature was raised to room temperature, and the solution was stirred for 4 h under the protection of nitrogen. During this period, triethylamine hydrochloride precipitated in the form of gel, and the solution became viscous. Then, the solution was filtered and washed with dilute hydrochloric acid (100 mL, 2%), followed by three washes with water (200 mL). The resulting solution was poured into methanol with vigorous stirring, and a white fibrous polymer was precipitated. The glass transition temperature of this polymer was determined to be 199°C by differential scanning calorimetry. Poly(4,4′-hexafluorois...
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