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Method for recovering powdery titania light catalyst

A technology of titanium dioxide and photocatalyst, applied in the direction of light water/sewage treatment, flocculation/sedimentation water/sewage treatment, etc., can solve the problems of small particle size, large and expensive solvent, difficult to apply, etc., to achieve simplified separation and high light utilization rate , the effect of convenient washing

Inactive Publication Date: 2005-02-23
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, due to the high activity of the catalyst requires the particle size of the catalyst to be small, common methods such as filtration and sedimentation are difficult to apply, and must be replaced by high-speed centrifugation, solvent extraction and other methods
However, these methods generally have the disadvantages of high energy consumption, time-consuming or the need for a large amount of expensive solvents.

Method used

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  • Method for recovering powdery titania light catalyst
  • Method for recovering powdery titania light catalyst
  • Method for recovering powdery titania light catalyst

Examples

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Effect test

Embodiment 1

[0037] Add 15 parts by weight of polyacrylamide into 85 parts of deionized water, and stir to completely dissolve it. Add 0.1 part by weight of the above-mentioned polyacrylamide aqueous solution to 99.9 parts by weight of dye wastewater containing commercial photocatalyst P25 treated by photocatalytic methods, and after stirring for several minutes, it can be observed that the catalyst is obviously agglomerated, forming large-sized Aggregates. After standing this solution, the photocatalyst is deposited at the bottom of the solution. The purpose of separating water and photocatalyst can be achieved by pouring off the clear liquid in the upper layer and retaining the solid in the lower layer.

Embodiment 2

[0039] Add 12 parts by weight of hydrolyzed polyacrylamide into 88 parts of deionized water and stir to dissolve it completely. Add 0.5 parts by weight of hydrolyzed polyacrylamide aqueous solution to 99.5 parts by weight of waste water containing commercial photocatalyst P25 treated by photocatalytic methods, and after stirring for several minutes, it can be observed that the catalyst is obviously agglomerated, forming large-sized Aggregates. Stand still, settle, filter, the filtrate of the lower layer is the treated water, and what remains in the filter screen of the upper layer is the recovered photocatalyst P25.

Embodiment 3

[0041] Add 1 part by weight of sodium polystyrene sulfonate to 99 parts of deionized water and stir to dissolve it completely. Add 50 parts by weight of sodium polystyrene sulfonate aqueous solution to 50 parts by weight of methyl orange aqueous solution containing self-made photocatalyst treated by photocatalytic method. After constant stirring for several minutes, the solution was allowed to settle by standing. The clear supernatant was decanted. The lower layer is the photocatalyst separated from water. Water was added to wash the recovered photocatalyst several times. Using the recovered photocatalyst, after treating the wastewater containing dye methyl orange by photocatalytic method, add polystyrene sodium sulfonate aqueous solution to the dye wastewater in the same proportion, after stirring for several minutes, let it stand, settle, the photocatalyst It can be separated again from the treated wastewater.

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Abstract

A process for recovering the powdered TiO2-type photocatalyst features that the aqueous solution of high-molecular flocculant is mixed with the sewage treated by photocatalyst to separate the photocatalyst from water, and the photocatalyst is washed several times for removing electrolyte.

Description

technical field [0001] The invention belongs to the field of recovery of photocatalysts, in particular to methods for separating and recovering powdery titanium dioxide photocatalysts and water. Background technique [0002] The separation and recovery of photocatalysts from treated sewage is one of the key limiting factors that restrict the application of photocatalyst technology in water treatment from laboratory technology to practical application. At present, the laboratory commonly used powdered TiO 2 Photocatalyst suspended in water or other solvents to study TiO 2 Photocatalytic degradation of organic matter and its influencing factors. Although the small size of powdered TiO 2 Photocatalysts have the advantages of large contact surface with pollutants, high light utilization efficiency, and high photocatalytic activity. However, in the face of practical applications, their disadvantages are also obvious, that is, it is difficult to separate the catalyst from water...

Claims

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Application Information

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IPC IPC(8): C02F1/30C02F1/54
Inventor 刘春艳刘云
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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