Particulate additive for dispersing admixtures in hydraulic cements
A granular additive and hydraulic cement technology, which is applied in the field of dispersed admixtures, can solve problems such as not easy and difficult to use
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Embodiment 1
[0074] In this example, a certain range of admixtures and carriers are dry-milled in a vertical ball mill using the above-mentioned preferred operating parameters to reduce the median particle size of the carrier and adjust the particle distribution to be close to normal and relatively wide. The spike is diluted and combined with the vehicle. The formed additives were analyzed by X-ray Electron Photon Spectroscopy (XPS) combined with Scanning Electron Microscopy (SEM). This indicates that the surface of the carrier particles is enriched with admixtures compared to the bulk of the carrier particles and that the admixtures are not present in a loosely dispersed form. SEM analysis showed that the assumption of uniform coating of individual carrier particles is unrealistic and that there may well be more complex situations where admixture particles would be accommodated on the surface of the agglomerate and in some cases bound to individual carrier particles. Certain additives ar...
Embodiment 2
[0079] In this example, the fine F fly ash with a median particle size of 15 microns was dry-milled in a vertical ball mill using the above-mentioned preferred operating parameters to make the additive, so that the median particle size of the fly ash was reduced to 4 Micron, and adjust the particle distribution to be close to normal and relatively broad. No admixtures are used. When the additive is used in the binder of conventional slump concrete, and maintains a slump constant of 100 mm, it increases strength while reducing water requirements. The results of this experiment are shown in Table 2.
[0080] Mixture
Concrete water%
Early strength (Mpa)
late strength
(Mpa)
340℃hrs*
(Mature)
410℃hrs*
(Mature)
480℃hrs*
(Mature)
7 days **
13% *** pulverized coal
Ash
6.8
28.5
34.75
35.0
50.75
20% additives
6.4
32.25
36.25
42.5
63.25
...
Embodiment 3
[0087] In this embodiment, the above-mentioned preferred operating parameters are used in the vertical ball mill to dry-grind F-class fine fly ash with a median particle size of 15 microns and anhydrous sodium sulfate with 1% mass to prepare additives, so that the pulverized coal The median particle size of the ash is reduced to 4 microns and the particle distribution is adjusted to be near normal and relatively broad, the admixture is diluted in the carrier and bound to the carrier particles. The ratio of sodium sulfate and fly ash has been shown in previous experiments to be higher than the optimum value for the early strength growth of the mortar.
[0088] Mortar prepared from sand, cement (median particle size 12.5 microns), additives and water (water / binder ratio 0.48, total binder content 25% by mass of the total dry mix components) The 28-day compressive strength is shown in Table 3.
[0089] Mixture
Column compressive strength of 28-day water-cured concr...
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