Organometallic polymer material and process for preparing the same
A technology of polymer materials and organic metals, applied in the field of optics, to achieve the effect of reducing losses
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Embodiment 1~15 and comparative example 1~2
[0088] In each of the following Examples and Comparative Examples, the materials were synthesized using the following Step P or Step Q.
[0089]
[0090] (1)
[0091] The organometallic compound A shown in Table 1: 5.5 ml (5.4 g in the case of Example 1), the organometallic compound B shown in Table 1: 5.8 ml (6.2 g in the case of Example 1), containing An aqueous solution of hydrochloric acid (hydrochloric acid with a concentration of 2N: 1.65 ml) and 20.5 ml of ethanol were mixed as a catalyst and allowed to stand for 24 hours to hydrolyze the organometallic compound A and the organometallic compound B for polycondensation.
[0092] (2)
[0093] Take 4 ml of the obtained polycondensate solution in a petri dish, dissolve 10 mg of 1-hydroxycyclohexyl phenyl ketone as a polymerization initiator, and evaporate the ethanol by heating at 100°C to obtain about 1 g of a viscous liquid a.
[0094] In 1 g of viscous liquid A, metal alkoxide X shown in Table 1: 3 ml (2.3 g in the ...
Embodiment 1
[0108] 3-methacryloxypropyltriethoxysilane was used as organometallic compound A, phenyltrimethoxysilane was used as organometallic compound B, trimethylethoxysilane was used as metal alkoxide, organic acid Y used trifluoroacetic anhydride.
Embodiment 2
[0110] Except having used trifluoroacetic acid as organic acid Y, it carried out similarly to Example 1.
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