Power-controlled bonding of resin or (co)polymer powder and flake materials

A technology of resin and power, which is applied in the field of manufacturing sticky powder, can solve the problems of inability to manufacture coating powder on an industrial scale, the appearance of the top coat is dark gray, and the coating cannot achieve gloss, so as to simplify the powder bonding method and reduce product failure High efficiency, reliable bonding effect

Inactive Publication Date: 2006-03-22
ROHM & HAAS CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the melt-blended composition is ground to make a paint powder, the flakes are easily broken, and the appearance of the topcoat obtained from such a paint powder is dull gray
Likewise, coating powders in which aluminum flakes were embedded in the powder by grinding, such as in a ball mill, contained significantly broken flakes, and the resulting coatings did not achieve a gloss comparable to solvent-based metallic paints
However, the brushing method cannot produce paint powders on any industrial scale

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 and 2

[0068] The following examples represent possible uses of the invention, but are not actually practiced.

Embodiment 1

[0070] 4 pounds of acid functional polyester coating powder containing 10 phr (per 100 parts resin) of beta-hydroxyalkylamide curing agent was placed in a 5 liter Plasmec Turbomixer for Plastics, Model TRM-5. The mixer blades rotate at 1600 rpm. The power generated by the mixer is displayed and output to a programmable logic controller (PLC). Power initially increased to 6.5 watts, + / - 0.2 watts. As the powder reached its Tg, the power dropped to about 6.0 watts at 30 seconds, and then the power began to rise steadily above 6.5 watts. If the mixer continues to run, the powder will agglomerate into large clumps and the power watts will increase beyond the capability of that mixer, forcing the mixer to stop. Instead, the PLC intervenes when power reaches 7.2 watts (10% higher than the steady-state power initially produced). When the power reached 7.2 watts, the mixing paddle was slowed to 1000 rpm and 0.16 pounds of aluminum flake pigment was added to the mixer. The mixer wa...

Embodiment 2

[0072] 4 lbs of epoxy coating powder containing 10 phr of bisphenol A epoxy phenyl imidazole curing agent were placed in a 5 liter Plasmec turbo mixer, model TRM-5 for plastics. The mixer blades rotate at 1600 rpm. Display the power generated by the mixer and output to PLC. Power initially increased to 8 watts, + / - 0.2 watts. As the powder approaches its Tg, the power drops to about 7.6 watts at 30 seconds and then rises steadily above 8 watts. If the mixer continues to run, the powder will agglomerate into large clumps and the power watts will increase beyond the capability of that mixer, forcing the mixer to stop. Instead, the PLC intervenes when power reaches 8.8 watts (10% higher than the steady-state power initially produced). When the power reached 8.8 watts, the mixing paddle was slowed to 1000 rpm and 0.16 pounds of aluminum flake pigment was added to the mixer. The mixer was continued for 2 minutes at 1000 rpm. At the end of this cycle, the powder and aluminum fl...

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PUM

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Abstract

The present invention provides methods of making sticky powder comprising mixing one or more resin or (co)polymer powders in one or more mixing devices without agglomerating the powders and while measuring the power, work or torque drawn by the mixing devices, the mixing continuing until the measure of the power or torque drawn indicates that the powders have become sticky. The mixing further comprises adding to the powders one or more dry materials and mixing to so that the dry materials adhere or ''bond'' to the sticky powders. Alternatively, the methods further comprise slowing or stopping the mixing, or cooling while mixing once the said sticky powders have been formed, adding one or more dry materials to form a sticky powder mixture, and further mixing to bond the sticky powders and the dry materials together.

Description

technical field [0001] The present invention relates to a method of manufacturing cohesive powders and a method of manufacturing powders containing additives or two or more powder materials, more particularly, to manufacturing paint powders containing metal or mica pigments. Background technique [0002] Because powder coatings provide durable coatings with excellent pigment control, powder coatings have been marketed with increased metallic or non-metallic flake content to provide highly reflective metallic-look coatings, or to provide shiny topcoats. In decorative coatings, glitter effects are achieved by metallic coatings. Highly reflective coatings provide visibility and easy identification of objects. Metallic coatings can be used to reduce container temperature, provide solar reflection, etc. Similarly, it is advisable to add non-metallic flakes such as mica to powder coatings to produce unique appearance effects. However, coating powders containing metal flakes are...

Claims

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Application Information

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IPC IPC(8): C09D5/03C08J3/12C08J3/20
Inventor J·C·奥尼尔A·萨拉弗纳斯S·M·斯尼德
Owner ROHM & HAAS CO
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