The invention discloses a C200 strength-grade concrete for a formed steel concrete composite structure, which is composed of 473 parts of cement, 846 parts of fine aggregate, 1054 parts of coarse aggregate, 98.8 parts of water, 19.6 parts of concrete superplasticizer, 1.1 parts of defoaming agent, 84 parts of silicon powder, 123 parts of expanding agent, 7.2 parts of activator and 40 parts of expanding agent. The preparation method comprises the following steps: blending the concrete superplasticizer and activator into weighed water to obtain a mixture, sequentially adding the fine aggregate and 1/3 of the mixture into a stirrer according to parts by weight, and stirring; adding the coarse aggregate and 1/3 of the mixture, and stirring; adding the cement, expanding agent, silicon powder and fly ash, and stirring; and adding the defoaming agent and the rest of mixture, stirring and discharging. The concrete can obviously improve the bonding property between the formed steel and the concrete in a natural state, effectively displays the respective mechanical properties and the synergic working performance of the steel and concrete, greatly enhances the loading capacity, service performance and durability of the structural member, and has high volume stability and economical efficiency.