Photosensitive resin compound
A technology of photosensitive resin and composition, which is applied in optics, optomechanical equipment, nonlinear optics, etc., can solve the problems of insufficient storage stability and heat resistance of radiation-sensitive resin compositions, and achieve excellent storage stability, The effect of excellent heat resistance
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Embodiment 1
[0145] The constituent units of the binder resin Aa used in Example 1, Comparative Example 1, and Comparative Example 2 are shown in formula (X).
[0146]
[0147] Description of constituent units
[0148] a: Corresponding to the constituent unit derived from (A1) in copolymer 1
[0149] b: Corresponds to the constituent unit derived from (A2) in copolymer 1
[0150] c: Corresponds to a constituent unit derived by reacting (A3) with a constituent unit derived from (A4) in copolymer 1
[0151] d: Corresponds to a constituent unit derived by reacting (A5) with a moiety derived from (A3) in copolymer 2
[0152] Table 1 shows the molar ratio of constituent units a to d in resin Aa, R 2 , the weight average molecular weight and molecular weight distribution of the obtained resin Aa based on polystyrene calibration standards.
[0153] Table 1
[0154]
Resin Aa
a
0.25
b
0.25
c
0.15
d
0.35
R 2
-CH 3
M w
1...
Embodiment 2
[0167] In the same manner as in Synthesis Example 1 of JP-A-11-133600, 7 parts by weight of 2,2'-azobis(2,4-dimethyl valeronitrile) and 200 parts by weight of diethylene glycol dimethyl ether. Subsequently, 30 parts by weight of styrene, 20 parts by weight of methacrylic acid, and 50 parts by weight of glycidyl methacrylate were added and purged with nitrogen, followed by stirring gently. The temperature of the solution was raised to 70° C. and maintained at this temperature for 5 hours to obtain a polymer solution containing resin Ab. The resulting resin Ab had a weight average molecular weight of 24,000 based on polystyrene calibration standards.
[0168] Example 1
[0169] [Preparation of Photosensitive Resin Composition 1]
[0170] 50 parts (converted to solids) of resin Aa obtained above, 50 parts of dipentaerythritol hexaacrylate (KAYARAD DPHA; produced by Nippon Kayaku Co., Ltd.), 3 parts by weight of 2-benzyl-2-dimethylamino -1-(4-morpholinophenyl)-butanone (Irgacu...
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Abstract
Description
Claims
Application Information
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