Phosphorus supple menting agent having controlled slow-release type phosphorus, its preparation and use method
A kind of phosphorus supplement, slow-release technology
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Embodiment 1
[0025] 1) Calcining commercially available hydrotalcite at a temperature of 450°C to obtain a bimetallic oxide, then grinding to 400 mesh, adding water and stirring evenly to prepare a suspension slurry with a concentration of 10%;
[0026] 2) Sodium phosphate with a phosphorus content of 6% by weight of the double metal oxide is pre-configured into a 0.1 mol / L sodium phosphate aqueous solution, slowly added to the suspension slurry in step 1) under stirring, and reacted at room temperature for 5 hours;
[0027] 3) centrifugal dehydration of the suspension slurry in step 2);
[0028] 4) The filter cake obtained in step 3) is dried and crushed to 300 mesh to obtain a controlled and slow-release phosphorus supplement. The content of phosphorus in the double metal oxide is 5%.
Embodiment 2
[0030] 1) Calcining commercially available hydrotalcite at a temperature of 550°C to obtain a bimetallic oxide, then grinding to 500 mesh, adding water and stirring evenly to prepare a suspension slurry with a concentration of 1%;
[0031] 2) Potassium phosphate with a phosphorus content of 35% by weight of the double metal oxide is pre-configured into a 1.0 mol / L potassium phosphate aqueous solution, slowly added to the suspension slurry in step 1) under stirring, and reacted at room temperature for 10 hours;
[0032] 3) the suspension slurry in step 2) is filtered and dehydrated;
[0033] 4) Drying and crushing the filter cake obtained in step 3) to a size larger than 300 meshes to obtain a controlled and slow-release phosphorus supplement. The content of phosphorus in the double metal oxide is 30%.
Embodiment 3
[0035] Preparation: hydrotalcite was prepared according to the method of "hydrothermal synthesis of magnesium-aluminum hydrotalcite" (Xie Hui, Jiao Qingze, Duan Xue. Applied Chemistry, 2001, 18: 70-72).
[0036] 1) calcining the hydrotalcite obtained in the preparatory step at a temperature of 500°C to obtain a bimetallic oxide, then grinding to 600 mesh, adding water and stirring evenly to prepare a suspension slurry with a concentration of 5%;
[0037] 2) Sodium hydrogen phosphate with a phosphorus content of 20% by weight of the double metal oxide is pre-configured into a 0.5 mol / L sodium hydrogen phosphate aqueous solution, slowly added to the suspension slurry in step 1) under stirring, and reacted at room temperature for 8 hours;
[0038] 3) centrifugal dehydration of the suspension slurry in step 2);
[0039]4) Drying and crushing the filter cake obtained in step 3) to a size larger than 300 meshes to obtain a controlled and slow-release phosphorus supplement. The cont...
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