Process for tinting, dyeing or doping of moulded components made of transparent (co)polyamides in aqueous dye bath
A technology for molding components, polyamides, used in dyeing methods, optical components, chemical instruments and methods, etc., can solve problems such as less dye
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Embodiment 1
[0163] Embodiment 1: produce polyamide PA1
[0164] 35.7 kg of the diamine MACM (3,3-diamino-4,4-dimethyldicyclohexylmethane) and 34.2 kg of dodecanedioic acid were added to a 130 L autoclave with a stirrer, while 30 kg of water were added. After heating to 280°C at a pressure of maximum 30 bar, preferably 20 bar, the batch is released to atmospheric pressure and degassed to the required torque. The polymer melt is discharged in strands, cooled in a water bath and pelletized. After drying, a relative viscosity of 1.73 in 0.5% m-cresol and a Tg of 153°C were obtained. Polyamides are amorphous and completely transparent.
[0165] Lenses in the form of discs of 70 x 2 mm were produced in polishing tools on an Arburg injection molding machine. The roll temperature was 260-340°C while the tool temperature was 45-140°C. These sheet lenses had a haze of 0.30 and a light transmission of 94% and were tinted in a functional bath.
Embodiment 2
[0166] Embodiment 2: produce polyamide PA2
[0167] 23.0kg diamine PACM (3,3-diamino-4,4-dimethyldicyclohexylmethane), 11.2kg diamine MACM (3,3-diamino-4,4-dimethyldicyclohexyl methane) and 35.7kg of dodecanedioic acid were added into a 130L autoclave with a stirrer, and 30.0kg of water was added simultaneously. After heating to 280°C at a pressure of maximum 30 bar, preferably 20 bar, the batch is released to atmospheric pressure and degassed to the required torque. The polymer melt is discharged in strands, cooled in a water bath and pelletized. After drying, a relative viscosity of 1.85 in 0.5% m-cresol, a Tg of 144°C and a melting point of 237°C were obtained. The polyamide is microcrystalline and completely transparent.
Embodiment 3
[0168] Embodiment 3: produce polyamide PA3
[0169] Add 30.0kg of diamine MACM (3,3-diamino-4,4-dimethyldicyclohexylmethane), 20.7kg of isophthalic acid and 26.0kg of glyceryl laurate lactam into a 130L autoclave with agitator In, add the water of 23.0kg simultaneously. After heating to 280°C and at a pressure of maximum 30 bar, preferably 20 bar, the batch is released to atmospheric pressure and degassed to the required torque. The polymer melt is discharged in strands, cooled in a water bath and pelletized. After drying, a relative viscosity of 1.55 in 0.5% m-cresol and a Tg of 160°C were obtained. The polyamide is amorphous and completely transparent.
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