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Preparation method of lead electrobath for transitting to electrolysis in low termperature

A production method and technology for an aluminum electrolysis cell, which are applied in the field of aluminum electrolysis production, can solve problems such as affecting the working environment of workers in electrolysis workshops, large volatilization loss of materials in electrolysis cells, and harm to the health of electrolysis workers, etc., so as to improve the working environment and reduce The volatilization of materials and the effect of weakening the interaction force

Active Publication Date: 2006-12-06
GUIZHOU BRANCH CHINA ALUMINUM IND
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Problems solved by technology

The existing aluminum electrolysis with high electrolysis temperature has the following disadvantages: 1. The relatively high electrolysis temperature reduces the current efficiency of the electrolysis cell, and the unit consumption of DC power is high; 2. The material volatilization loss in the electrolysis cell is large, and the unit consumption of electrolysis production materials High; 3. The electrolysis temperature is high, and the material volatilization loss is relatively large, which affects the working environment of the workers in the electrolysis plant and brings harm to the health of the electrolysis workers
At present, the technology of aluminum electrolysis at low temperature is used to control the electrolysis temperature at 915°C to 930°C, which has not been recorded yet.

Method used

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Embodiment 1

[0009] The production method of aluminum electrolytic cell of the present invention transitions to low-temperature electrolysis comprises the following steps:

[0010] a) Adjust the electrolyte composition to reduce the primary crystal temperature step. The molecular ratio, CaF 2 , MgF 2 , LiF are respectively controlled in the range of 2.2~2.35, 3~6%, 1~4%, 1.6~2.0%, so that the primary crystal temperature of the electrolytic tank is in the range of lowering, and the primary crystal temperature is 905 ° C ~ 915 ° C; the molecular Ratio refers to the molar ratio of sodium fluoride and aluminum fluoride, and the adjustment of the electrolyte composition to reduce the primary crystal temperature refers to adding aluminum fluoride to the electrolytic cell through a dense phase conveying system, adding calcium fluoride and magnesium fluoride to control, The amount of aluminum fluoride added is 13kg / batch, and the amount of aluminum fluoride added is adjusted according to the mole...

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Abstract

This invention relates to a low-temperature electrolysis method electrolyzing aluminum in an aluminum electrolytic tank. The method comprises: (1) adjusting the electrolyte composition to lower the initial crystallization temperature; (2) controlling the voltage of the electrolytic tank; (3) controlling overheat of the electrolysis; (4) controlling the aluminum level; (5) controlling the intelligent fuzzy parameters; (6) finely operating. The method can improve the electrolytic conditions of the electrolytic tank, lower the initial crystallization temperature of 905-915 deg.C and the electrolysis temperature to 915-930 deg.C, raise the current efficiency, and reduce the electricity consumption.

Description

technical field [0001] The invention relates to an aluminum electrolysis production technology, in particular to a production method for the transition from an aluminum electrolysis cell to low-temperature electrolysis. Background technique [0002] The electrolysis temperature of electrolytic cells in my country is generally between 950°C and 970°C, the molecular ratio of electrolytes is between 2.5 and 2.7, the current efficiency of electrolytic cells is about 92%, and the unit consumption of primary aluminum direct current is relatively high. The existing aluminum electrolysis with high electrolysis temperature has the following disadvantages: 1. The relatively high electrolysis temperature reduces the current efficiency of the electrolysis cell, and the unit consumption of DC power is high; 2. The material volatilization loss of the electrolysis cell is large, and the unit consumption of electrolysis production materials High; 3. The electrolysis temp...

Claims

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Application Information

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IPC IPC(8): C25C3/06C25C3/20
Inventor 周新林张忠玉胡俊杰郭峰曹鹏钟向文王广稳何建涛常林波王群蔡有萍马云海曹继明马思聪寇东胜郭华伟李建军贺俊荣梁鲁清秦建春董江
Owner GUIZHOU BRANCH CHINA ALUMINUM IND
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