Method for treating acid heavy metal polluted waste water
A treatment method and technology for heavy metals, applied in water/sewage treatment, adsorbed water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problem of final disposal of precipitated sludge, unsatisfactory treatment effect of low-concentration heavy metal wastewater, etc. problem, to achieve the effect of easy operation, low cost and easy access
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Embodiment 1
[0016] Dry the chestnut skin in a constant temperature oven at 60°C for 30 hours, grind it, and sieve it, and take the chestnut skin with a particle size of 15 mesh for use.
[0017] Weigh 4.0g of the above-mentioned sieved chestnut skin into a 100ml centrifuge tube, add 50ml of complex heavy metal solution (SMS) with pH=1.0, shake at room temperature for 24h, centrifuge the mixture at 5000rmp for 20min, filter it with a 0.45um membrane, and measure the filtrate Medium heavy metals (cadmium, lead, copper, zinc) content.
[0018] The preparation of the complex heavy metal solution of the pH=1.0: 0.25mM PbNO 3 , CuNO 3 , CdNO 3 , ZnNO 3 Dissolve in 1L deionized water with 0.1M HNO 3 The solution was adjusted to pH = 1.0.
[0019] The 0.1M HNO 3 Solution preparation: Accurately take 5.5ml of concentrated nitric acid, and dilute to 1L with ionized water.
[0020] See Table 1 for the treatment effect. It can be seen that the concentration of heavy metal pollutants in the wa...
Embodiment 2
[0023] Dry the chestnut skins in a constant temperature oven at 65°C for 25 hours, grind, sieve, and take the chestnut skins with a particle size of 20 mesh for use.
[0024] Weigh 3.0 g of the above-mentioned sieved chestnut skin into a 100 ml centrifuge tube, add 50 ml of complex heavy metal solution (SMS) with pH=2.0, shake at room temperature for 24 hours, centrifuge the mixture at 5000 rpm for 20 minutes, filter it with a 0.45um membrane, and measure the filtrate Medium heavy metals (cadmium, lead, copper, zinc) content.
[0025] The preparation of the complex heavy metal solution of the pH=2.0: 0.25mM PbNO 3 , CuNO 3 , CdNO 3 , ZnNO 3 Dissolve in 1L deionized water with 0.1M HNO 3 The solution was adjusted to pH=2.0.
[0026] The 0.1M HNO 3 Solution preparation: Accurately take 5.5ml of concentrated nitric acid, and dilute to 1L with ionized water.
[0027] The treatment effect is shown in Table 2. It can be seen that the concentration of heavy metal pollutants in...
Embodiment 3
[0030] Dry the chestnut skins in a 70°C constant temperature box for 20 hours, grind them, and sieve them, and take the chestnut skins with a particle size of 40 mesh for use.
[0031] Weigh 2.0g of the chestnut skins sieved above into a 100ml centrifuge tube, add 50ml pH=3.0 composite heavy metal solution (SMS), shake at room temperature for 24h, centrifuge the mixture at 5000rmp for 20min, filter it with a 0.45um membrane, and measure Heavy metal (cadmium, lead, copper, zinc) content in the filtrate.
[0032] The preparation of the complex heavy metal solution of the pH=3.0: 0.25mM PbNO 3 , CuNO 3 , CdNO 3 , ZnNO 3 Dissolve in 1L deionized water with 0.1M HNO 3 The solution was adjusted to pH = 3.0.
[0033] The 0.1M HNO 3 Solution preparation: Accurately take 5.5ml of concentrated nitric acid, and dilute to 1L with ionized water.
[0034] The treatment effect is shown in Table 3. It can be seen that the concentration of heavy metal pollutants in the waste water is 0....
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