Aqueous dispersion, method for producing same, and method for bonding shaped article made of ethylene-alpha-olefin copolymer
A water-based dispersant and bonding method technology, which is applied in the direction of monocarboxylate copolymer adhesives, adhesive types, surface pretreatment bonding methods, etc., can solve problems such as difficult to achieve adhesion, Achieve the effect of improving mechanical stability and storage stability, good stability and high adhesion
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[0214] 100 parts by weight of the ethylene / 1-butene copolymer obtained in Preparation Example (2) above, 0.5 parts by weight of dicumyl peroxide (DCP), and 0.35 parts by weight (TAIC conversion value) of tripropenyl isocyanide Ornithyl ester (TAIC) (trade name: M-60 (TAIC content: 60% by weight) (manufactured by Nippon Chemicals Co., Ltd.)), 7 parts by weight of dicarboxylamine nitride and 10 parts by weight of talc powder The mixture was kneaded on a roll having a roll surface temperature of 100° C. for 10 minutes to form a thin plate.
[0215] Then the thin plate obtained is placed on the stamping die, at 150kg / cm 2 , 160° C., and pressure heating for 12 minutes to obtain a foamed molded product (thickness 24.5 mm, length 1500 mm, width 200 mm).
[0216] Example 1
[0217] Preparation of aqueous dispersant (aqueous emulsion composition)
[0218] With 5 parts by weight of ethylene / α-olefin copolymer (density: 862kg / m 3 , MFR: 1.2g / 10 minutes, trade name: TAFMER-DF610 (man...
Embodiment 2
[0235] In addition to replacing 5 parts by weight of ethylene / α-olefin copolymer (density: 862kg / m 3 , MFR: 1.2g / 10 minutes, trade name: TAFMER-DF610 (manufactured by Mitsui Chemicals)), using 5 parts by weight of ethylene / α-olefin copolymer (density: 885kg / m 3 , MFR: 1.2 g / 10 minutes, brand name: TAFMER-DF810 (manufactured by Mitsui Chemicals, Inc.)), the same operation as in Example 1 was performed to obtain an aqueous emulsion composition.
[0236]Using this aqueous emulsion composition, the cleaned foam molded article and the rubber sheet were adhered in the same manner as in Example 1, and the adhesive strength was measured. The results are shown in Table 1.
Embodiment 3
[0238] In addition to replacing 5 parts by weight of ethylene / α-olefin copolymer (density: 862kg / m 3 , MFR: 1.2g / 10 minutes, trade name: TAFMER-DF610 (manufactured by Mitsui Chemicals)), using 5 parts by weight of ethylene / α-olefin copolymer (density: 870kg / m 3 , MFR: 35g / 10 minutes, trade name: TAFMER-DF7350 (manufactured by Mitsui Chemicals Co., Ltd.), replace 40 parts by weight of turpentine (trade name: gumterebinthN (manufactured by YATUHARA Chemical Co., Ltd.)) and 20 parts by weight of turpentine An aqueous emulsion composition was obtained in the same manner as in Example 1 except for limonene (trade name: D limonene (manufactured by Yatuhara Chemical Co., Ltd.).
[0239] Using this aqueous emulsion composition, the cleaned foam molded article and the rubber sheet were adhered in the same manner as in Example 1, and the adhesive strength was measured. The results are shown in Table 1.
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