Inorganic compound-coated pigments and cosmetics using the same

a technology of compound coating and pigment, applied in the direction of material nanotechnology, chemistry apparatus and processes, make-up, etc., can solve the problems of cosmetics not being able to cover human skin with adequate stability for a long time, the ability of masking to be lower, and the cosmetics not being able to achieve adequate stability in us

Inactive Publication Date: 2002-03-28
TANAKA HIROKAZU +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0009] Further it is another object of the present invention to provide cosmetics which can preserve the excellent effect for a long period of time and does not change the color tone by oxidizing or decomposing organic compounds blended therein nor lower its appearance and performances.

Problems solved by technology

However, as time goes by after the cosmetic is applied to human skin and a surface of pigments blended therein is wet with skin fats or sweat, a reflectance or scattering capability of the pigments becomes smaller with a color tone of the cosmetic film changing and also with the masking capability becoming lower, so that the capability of the cosmetics to cover human skin degrades.
With this kind of cosmetics, the cosmetic effect can be preserved for a longer period of time to some extent by making it harder to be wet with skin fat or sweat, but the adequate stability in use for a long time has not be realized.
Further there is a method of preventing or delaying a pigment from getting wet by simultaneously mixing porous silica or the like in cosmetics so that skin fats or sweat secreted in association with passage of time is absorbed in the silica or the like, but the effect is not adequate at present.
Further in some of the cosmetics with the white or colored pigments blended therein, sometimes oil and fat, moistener, a surfactant, an organic thickener, an organic solvent or the like blended in cosmetics may be oxidized or decomposed, which in turn degrades the appearance or performance.
When the rate is less than 1 weight %, the blending effect is not obtained at all, and if the rate surpasses 80 weight %, the hiding performances become too strong, which hinders the natural effect provided by the cosmetics.

Method used

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  • Inorganic compound-coated pigments and cosmetics using the same
  • Inorganic compound-coated pigments and cosmetics using the same
  • Inorganic compound-coated pigments and cosmetics using the same

Examples

Experimental program
Comparison scheme
Effect test

embodiment 1

[0041] Embodiment 1

[0042] 90 g white pigments (W) made of titanium oxide and having an average particle diameter of 250 nm was mixed in one litter of ethanol to prepare a dispersion. This dispersion was heated to 45.degree. C. and 28% aqueous annomia was added to adjust pH to 9.5 or more, and then tetraethoxysilane with the weight equivalent to 10 g of SiO.sub.2 and 110 g of 28% aqueous ammonia was added to the dispersion while preserving the conditions described above. After addition of the compounds described above, the dispersion was further agitated for additional two hours, and then filtered, washed, and dried under the temperature of 110.degree. C., and further sintered under the temperature of 600.degree. C., and silica-coated titanium oxide white pigments (Ws) were obtained. The white pigments were observed with an electronic microscope, and it was found that the particles were not aggregated and the particle shapes and diameters before and after coating with silica were sub...

embodiment 2

[0050] Embodiment 2

[0051] Indian red pigments coated with silica (Rs) was obtained by the same method as that described above excluding only the point that Indian redpigments (R) made from needle-shaped particles each having an average length of 500 nm and an average diameter of 100 nm was used in place of the titanium oxide used in Embodiment 1. Observation of the red pigments with an electronic microscope showed that the particles had not be aggregated and particles shapes and diameters before and after coating with silica were substantially identical.

[0052] Changes of a color tone for the resultant red pigments coated with silica (Rs) and red pigments non-coated with silica (R) were measured like in Embodiment 1. A result of the measurement is shown in FIG. 4 to FIG. 6 and in Table 2.

2 TABLE 2 Color difference (.DELTA.E) CTG 16 wt % Water 16 wt % Non-coated red pigments (R): 11 11 Silica-coated red pigments (Rs): 4.9 3.3 Decrease rate (%) of .DELTA.E: 55 70

[0053] Like in a case o...

embodiment 3

[0054] Embodiment 3

[0055] Yellow iron oxide pigments coated with silica (Ys) was obtained by the same method as that described above excluding only the point that yellow iron oxide pigments (Y) made from needle-shaped particles each having an average length of 500 nm and an average diameter of 100 nm was used in place of the titanium oxide used in Embodiment 1. Observation of the yellow pigments with an electronic microscope showed that the particles had not be aggregated and particles shapes and diameters before and after coating with silica were substantially identical.

[0056] Changes in a color tone of the resultant yellow pigments coated with silica (Ys) and yellow pigments non-coated with silica (Y) were measured like in Embodiment 1. A result of the measurement is shown in FIG. 7 to FIG. 9 and in Table 3.

3 TABLE 3 Color difference (.DELTA.E) CTG 16 wt % Water 16 wt % Non-coated yellow pigments (Y): 17 15 Silica-coated yellow pigments (Ys): 4.1 4.4 Decrease rate (%) of .DELTA.E:...

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Abstract

White or colored pigments which do not suffer from color tone or hiding performances thereof even when the surface is moistened with water or oil, without spoiling coloring performance or hiding performance of the pigments themselves. These pigments are surface-coated with an inorganic compound having the refractive index of 1.8 or below. The inorganic compound is preferably silicon oxide, and the pigments are preferably inorganic pigments comprising titanium oxide, zinc oxide, or iron oxide. The cosmetics of the invention are blended the pigments therein.

Description

[0001] This is a continuation application of patent application Serial No. 09 / 319,176 filed on Jun. 3, 1999.[0002] The present invention relates to pigments having the surface coated with a particular inorganic compound, and more specifically to white or colored pigments with improved capability for preventing change of the color caused when wet with water or oil and degradation in hiding performances thereof. Furthermore the present invention relates to cosmetics with the white or colored pigment blended therein.BACKGROUND TECHNOLOGY[0003] White pigments such as titanium oxide or zinc oxide and inorganic colored pigments such as Indian red, yellow iron oxide, black iron oxide, and ultramarine blue pigment, or organic pigments such as tar coloring matter generally change the colors to darker ones when wet with water or oil with the hiding performances degraded. This phenomenon occurs because a light reflectance or a scattering effect of the surface of pigments becomes lower.[0004] B...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C09C1/04C09C1/24C09C1/36C09C3/06
CPCA61K8/11A61K2800/412A61K2800/43A61Q1/02B82Y30/00C01P2002/84C01P2004/03C01P2004/10C01P2004/20C01P2004/32C01P2004/50C01P2004/62C01P2004/64C01P2004/84C01P2006/60C09C1/043C09C1/24C09C1/3661C09C3/063
Inventor TANAKA, HIROKAZUMIYAZAKI, TAKUMI
Owner TANAKA HIROKAZU
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