Vegetable sterol ester-containing composition and additive that increases the feeling effects from hair cosmetic
a technology of vegetable sterol and additive, which is applied in the direction of hair cosmetics, biocide, plant/algae/fungi/lichens ingredients, etc., can solve the problems of lanolin's original odor, health problems, and general unfavored animal-derived substances, so as to increase the feeling effect, and increase the feeling effect
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preparation example 1
[0074] 2000 g of a deodorized distillate (the total tocopherol content of 10.3%, acid value of 81) obtained by deodorizing soybean oil as a by-product was methyl-esterificated in a mixed solvent of 100 ml of methanol and 1000 ml of toluene in the presence of 130 g of sulfuric acid under ref lux for 1 hour. An oily substance was separated, and washed four times with 500 ml of water. The acid value was 1 after the methyl-esterification. The resultant product was cooled to room temperature, and deposited crystal was filtered and separated. 8.9 g of the crystal was removed by the filtration.
[0075] A column was filled with 2000 ml of a strong basic anion exchange resin, “Amberlite IRA958”, to be an OH type, which was then replaced with toluene. Then, a solution of the prepared methyl-esterificated oil in toluene was passed therethrough. 4000 ml of toluene flowed through the column to wash the resin, and removed to provide 1670 g of non-adsorbed oil. The tocopherol adsorbed was eluted by...
preparation example 2
[0078] 2000 g of a deodorized distillate (the total tocopherol content of 9.8%, acid value of 78) obtained by deodorizing vegetable oil (a 1:1 mixture of soybean oil and rapeseed oil)as a by-product was methyl-esterificated in a mixed solvent of 1000 ml of methanol and 1000 ml of toluene in the presence of 130 g of sulfuric acid under reflux for 1 hour. An oily substance was separated, and washed four times with 500 ml of water. The acid value was 1 after the methyl-esterification. The resultant product was cooled to room temperature, and deposited crystal was filtered and separated. 9.2 g of the crystal was removed by the filtration.
[0079] A column was filled with 2000 ml of a strong basic anion exchange resin, “Duolite A113” to be an OH type, which was then replaced with toluene. Then, a solution of the prepared methyl-esterificated oil in toluene was passed therethrough. 4000 ml of toluene flowed through the column to wash the resin, and removed to provide 1650 g of non-adsorbed...
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