Sodium hydrogencarbonate crystal particles having low caking property and process for producing them
a technology caking properties, which is applied in the field of sodium hydrogencarbonate crystal particles having a low caking property, can solve the problems of affecting the flowability of the particles, and affecting the commercial value of sodium hydrogencarbonate, so as to prevent caking over a long period of time, low caking property, and long treatment time
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example 1
[0058] Sodium hydrogencarbonate crystal particles (hereinafter referred to simply as products) having various surface compositions were produced under the following conditions. In Table 4, Nos. 1 to 3 and No. 6 correspond to Example of the present invention, and Nos. 4 and 5 correspond to Comparative Example.
[0059] 20 m3 of an aqueous sodium hydroxide solution having a concentration of 20 mass % was put in a tank (50 m3) provided with a stirrer, and the temperature was raised to 80° C. In such a state, a carbon dioxide gas at a concentration of 100 vol % was blown for 5 hours in a flow rate of 10 m3 per minute in a standard state for reaction crystallization. In the crystallization step, first, sodium hydroxide is reacted with carbon dioxide to form sodium carbonate. So far, no crystals are precipitated. is Then, carbon dioxide and sodium carbonate are reacted to form sodium hydrogencarbonate. Here, as the solubility of sodium hydrogencarbonate is low, crystal particles of sodium h...
example 2
[0082] The packaging bag made of an LLDPE film of 120 μm used in Example 1 had a water vapor transmission rate of 6.0 g / (m2·24 h) at 40° C. with a relative humidity difference of 90% as stipulated in JIS K 7129. Instead, a dampproof packaging bag having alumina vapor-deposited thereon was used and the caking property evaluation test was carried out. As the structure of the packaging bag, a PET film having a thickness of 12 μm, and having an alumina transparent vapor deposition applied by the PVD method was used for dampproof for the outermost layer so that the vapor deposition layer faced inside, a nylon film having a thickness of 15 μm was used for the interlayer, and for the innermost layer, a completely additive-free LLDP film having a thickness of 70 μm was laminated by dry lamination. The vapor transmission of the packaging bag was 0.2 g / (m2·24 h) at 40° C. with a relative humidity difference of 90° C. as stipulated in JIS K 7129. As the sample for caking property evaluation te...
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