Method for coating metallic interconnect of solid oxide fuel cell

a technology of solid oxide fuel cell and metallic interconnection, which is applied in the direction of fuel cell details, fuel cells, electrochemical generators, etc., can solve the problems of difficult to achieve the durability of up to 40000 hours required for commercialization, concentration polarization, and serious environmental problems, etc., to achieve high electrical conductivity, enhance binding force, and inhibit chrome volatilization. inhibiting property

Inactive Publication Date: 2010-05-20
KOREA INST OF ENERGY RES
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Benefits of technology

[0021]Also, after the pulse plating, heat-treatment may be further carried out in a 800° C. reducing atmosphere (10% H2+90% N2) for 2˜20 hours to enhance a binding force between the metallic interconnect and a plated coating layer.
[0022]Through the method according to the present inve

Problems solved by technology

As power demands show a tendency to gradually increase according to a recent industrial development and economic growth, environmental problems, including air pollution and earth shock, have seriously arisen by the use of fossil fuels (such as petroleum, or coal) required for power production.
However, by these materials, it is very difficult to achieve the durability of up to 40000 hours required for commercialization, and thus there is need to develop a novel alloy and to research the application of protective coating on the surface of a conventional material.
However, at a higher current density than a predetermined limitation, plating ions around a to-be-coated substrate are depleted by mass

Method used

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  • Method for coating metallic interconnect of solid oxide fuel cell
  • Method for coating metallic interconnect of solid oxide fuel cell
  • Method for coating metallic interconnect of solid oxide fuel cell

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Embodiment Construction

[0035]Hereinafter, an exemplary embodiment of the present invention will be described with reference to the accompanying drawings. It is to be understood, however, that the following embodiment is illustrative only, and the scope of the present invention is not limited thereto. Also, those skilled in the art will appreciate that various modifications, additions and substitutions are possible.

[0036]In the operation of a solid oxide fuel cell (SOFC), a chrome oxide scale formed on the surface of a metallic interconnect at a high temperature causes some problems, such as reduction of a sealing property by peeling of the scale, pollution of a cathode by volatilization of chrome from the scale, or the like. These problems reduce output performance and long-term durability of the SOFC.

[0037]Accordingly, in the method according to the present invention, on the surface of a metallic interconnect, cobalt, one of transition metals for forming a spinel layer with a high electrical conductivity...

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Abstract

Disclosed is a method for coating a metallic interconnect for a solid oxide fuel cell (SOFC), the method including the steps of: carrying out pre-treatment for removing impurities adhered on a surface of the metallic interconnect; and carrying out pulse plating with cobalt as an anode, and the metallic interconnect as a cathode, in which an average current density (Ia) is set in a room-temperature cobalt plating solution, and a maximum current density (Ip), a current-on time (Ton) and a current-off time (Toff) are adjusted based on Ia=Ip×Ton/(Ton+Toff). Through the disclosed method, it is possible to obtain a metallic interconnect having a coating surface which has a high electrical conductivity and a high chrome volatilization inhibiting property and can minimize the occurrence of micro-cracks and micro-pores, thereby improving the performance of the SOFC.

Description

BACKGROUND OF THE INVENTION[0001]1. Field of the Invention[0002]The present invention relates to a solid oxide fuel cell, and more particularly to a coating method for forming a protective coating on the surface of a metallic interconnect that interconnects unit cells and collects current of a stack.[0003]2. Description of the Prior Art[0004]As power demands show a tendency to gradually increase according to a recent industrial development and economic growth, environmental problems, including air pollution and earth shock, have seriously arisen by the use of fossil fuels (such as petroleum, or coal) required for power production. Especially, since the exhaust of carbon dioxide by the use of fossil fuels is pointed out as a main factor of global warming and various kinds of environmental pollution, the development of solar light / heat energy, bio energy, wind energy, and hydrogen energy, as clean energy sources substituting for the fossil fuels, is being actively conducted.[0005]From...

Claims

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Application Information

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IPC IPC(8): C25D5/34
CPCC25D3/12C25D5/18C25D5/34H01M2008/1293H01M8/0206H01M8/0228C25D5/50C25D5/611C25D5/623Y02E60/50H01M8/02
Inventor SONG, RAK-HYUNSHIN, DONG-RYULLIM, TAK-HYUNGLEE, SEUNG-BOKHONG, JONG-EUNPYO, SEONG-SOO
Owner KOREA INST OF ENERGY RES
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