Moisture resistant photovoltaic devices with exposed conductive grid

a photovoltaic device and conductive grid technology, applied in the field of photovoltaic devices with exposed conductive grids, can solve the problems of reducing the service life of the device, so as to improve the service life, improve the adhesion, and improve the resistance to delamination, rupture, and/or moisture intrusion.

Inactive Publication Date: 2015-04-23
DOW GLOBAL TECH LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This approach significantly improves the moisture resistance and service life of chalcogenide-based photovoltaic devices by ensuring strong adhesion between the barrier layer and grid, preventing delamination and water intrusion, while allowing easy electrical connections.

Problems solved by technology

Silicon-based absorbers tend to be rigid, not flexible.
Heterojunction photovoltaic cells, especially those based on p-type and n-type chalcogenides, are water sensitive and can unduly degrade in the presence of too much water.
Also, the thinner, flexible layers are vulnerable to thermal and other delamination or cracking stresses.
Delamination and cracking not only can undermine device performance, but the resultant delamination and cracking also can exacerbate moisture intrusion.
However, such barrier films may tend to show poor adhesion to the top surface(s) of the device.
In particular, the adhesion between barrier materials and underlying transparent conducting oxide (TCO) materials and / or conductive collection grids may not be as strong as desired.
Additionally, the adhesion between the grids and other materials, such as the TCO compositions, also may be poor.
These issues can result in undue delamination or in a rupture of the continuous hermetic barrier film and / or open pathways allowing water intrusion to reach the chalcogenide compositions too easily.
This can lead to subsequent device performance degradation and ultimately failure.
Moreover, since the barrier film is typically a dielectric, providing a continuous electrically conductive path for electricity collection throughout the interconnecting cells with one another becomes a challenge.
However, silicon-based solar cells tend to be thicker and much more rigid than chalcogenide-based cells.

Method used

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  • Moisture resistant photovoltaic devices with exposed conductive grid
  • Moisture resistant photovoltaic devices with exposed conductive grid
  • Moisture resistant photovoltaic devices with exposed conductive grid

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0066]On 1″×1″ pieces of soda-lime glass, substrates comprising a sputter-deposited thin film of aluminum (about 30 nm), followed by an indium tin oxide (ITO) layer of 130 nm thickness were prepared. Indium tin oxide (ITO) films were prepared using a custom RF magnetron sputter chamber from a 100 mm diameter, 5 mm thick ITO ceramic target (90 wt % In2O3, 10 wt % SnO2) using gas flows of argon (14 sccm) and oxygen (2 sccm), controlled using mass flow controllers, to achieve a working gas pressure of 2.8 mTorr. The substrate temperature was held at 150° C. during deposition. A strip of Kapton tape (1 mm×5 mm) was applied to mask an area of the sample. A 178 nm thick layer of silicon nitride was sputter-deposited over the ITO and the tape. The silicon nitride was deposited via reactive sputtering using a boron-doped silicon target and a 50:50 Ar:N2 gas ratio. The pressure during deposition was controlled at 4.0 mTorr, the power is set at 140 W and the chamber platen was in rotational m...

example 2

[0069]Onto three (3) 1″×1″ pieces of soda-lime glass were sputter-deposited a thin film of aluminum (about 30 nm). A strip of Kapton tape (1 mm×5 mm) was applied to mask an area of each sample. A 150 nm thick layer of silicon nitride was sputter-deposited over the aluminum and the tape for each sample using identical conditions to those described in Example 1. The strips of tape were then carefully removed to expose the bare aluminum layer underneath silicon nitride. For each sample, a mask was applied to cover the whole substrate with the exception of a rectangular surface slightly larger than that of the exposed aluminum. Layers of Ni followed by Ag having a total thickness of about 1600 nm were evaporated over the mask using the conditions described in Example 1, thus depositing a conductive grid, which covered the exposed aluminum completely.

[0070]The samples were then placed in a pressure vessel at 115° C. / 100% relative humidity and 12 psig for accelerated exposure testing. Opt...

example 3

[0071]On a 1″×1″ (about 2.5 cm×2.5 cm) piece of soda-lime glass were sputter-deposited a thin film of aluminum (about 30 nm), followed by an indium tin oxide (ITO) layer of 130 nm thickness. Two strips of Kapton tape (1 mm×5 mm each) were applied to mask two distinct areas of the sample. A 150 nm thick layer of silicon nitride was sputter-deposited over the ITO and both strips of tape using the same chamber and conditions as described in Example 1. The strips were then carefully removed to expose the bare ITO layer underneath silicon nitride. A mask was applied to cover the whole sample with the exception of one rectangular surface slightly larger than that of one of the exposed ITO areas. Sequential layers of Ni followed by Ag having a total thickness of 1600 nm were evaporated under the conditions described in Example 1 over the mask, thus depositing a conductive grid, which covers one of the exposed areas of ITO completely.

[0072]Conductivity measurements demonstrate that conducti...

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Abstract

The present invention provides strategies for improving the adhesion among two or more of transparent conducting oxides, electrically conductive grid materials, and dielectric barrier layers. As a consequence, these strategies are particularly useful in the fabrication of heterojunction photovoltaic devices such as chalcogenide-based solar cells. When the barrier is formed and then the grid is applied to vias in the barrier, the structure has improved moisture barrier resistance as compared to where the barrier is formed over or around the grid. Adhesion is improved to such a degree that grid materials and dielectric barrier materials can cooperate to provide a hermetic seal over devices to protect against damage induced by environmental conditions, including damage due to water intrusion. This allows the collection grids to be at least partially exposed above the dielectric barrier, making it easy to make electronic connection to the devices.

Description

PRIORITY[0001]The present nonprovisional patent application claims priority under 35 U.S.C. §119(e) from U.S. Provisional patent application having Ser. No. 61 / 294,878, filed on Jan. 14, 2010, by Elowe et al. and titled MOISTURE RESISTANT PHOTOVOLTAIC DEVICES WITH EXPOSED CONDUCTIVE GRID, wherein the entirety of said provisional patent application is incorporated herein by reference.FIELD OF THE INVENTION[0002]The present invention relates to photovoltaic devices of the type incorporating a conductive collection grid that facilitates ease of making external electrical connections, and more particularly to heterojunction photovoltaic devices, especially chalcogen-based photovoltaic devices, with improved adhesion between such grids and other components of the devices, wherein the improved adhesion helps provide the devices with enhanced moisture resistance.BACKGROUND OF THE INVENTION[0003]Both n-type chalcogenide compositions and / or p-type chalcogenide compositions have been incorpor...

Claims

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Application Information

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Patent Type & AuthorityApplications(United States)
IPC IPC(8): H01L31/048H01L31/0224
CPCH01L31/022466H01L31/048H01L31/02167H01L31/022425H01L31/0322H01L31/0749Y02E10/541
InventorELOWE, PAUL R.DEGROOT, MARTY W.MILLS, MICHAEL E.STEMPKI, MATT A.
OwnerDOW GLOBAL TECH LLC