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High performance creep resistant magnesium alloys

a magnesium alloy, high-performance technology, applied in the field of creep-resistant magnesium-based alloys, can solve the problems of low strength, inability to serve at temperatures higher than 150-170° c, and =120 mpa, and achieve the effects of high strength, superior casting properties, and prolonged operations

Inactive Publication Date: 2016-10-20
DEAD SEA MAGNESIUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a lightweight alloy for high-pressure die casting (HPDC) process with superior castability, low susceptibility to hot tearing, and excellent ductility. The alloy is composed of at least 94.8 wt % magnesium, 2.5 to 4.6 wt % neodymium, 0.05 to 0.40 wt % yttrium, 0.03 to 0.65 wt % zirconium, and incidental impurities. The alloy contains no heavy rare earth (HRE) elements, cerium, lanthanum, or praseodymium. It can be used for HPDC and other applications such as sand casting, investment casting, and permanent mold casting. The alloy exhibits high strength, high creep resistance, high corrosion resistance, and excellent ductility. It has a high creep rupture stress, creep strength, and low minimum creep rate as well as low corrosion rate. The alloys are also cost-effective.

Problems solved by technology

However, these alloys cannot serve at temperatures higher than 150-170° C. under high stresses of 60-100 MPa.
High-pressure die casting of the alloys results in low strength (TYS=120 MPa, UTS=165 MPa) and elongation (E=2%).
However, the HPDC is not addressed.
The complexity of the technology significantly increases the cost of the final alloy product.
The alloys are mainly designated for sand casting and, in addition, they are expensive due to the use of heavy rare earth elements, such as Gd in amounts of 1.0-1.6%.
The high Ca content results in increased porosity, embrittlement and hot cracking in HPDC processes.
The alloy is unsuitable for HPDC process.
Furthermore, the high content of heavy rare earth elements leads to high cost of these alloys.
The alloys are not suitable for HPDC process and are expensive.

Method used

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[0049]The alloys of the present invention were prepared in 150 l crucible made of low carbon steel. The mixture of CO2+0.5% HFC134a was used as a protective atmosphere. The raw materials used were as follows:

[0050]Magnesium (Mg)—pure magnesium, grade 9980A, containing at least 99.8% Mg.

[0051]Neodymium (Nd)—commercially pure Nd (less than 0.5% impurities).

[0052]Zirconium (Zr)—Zr95 Tablets, containing at least 95% Zr.

[0053]Yttrium (Y)—commercially pure Y (less than 1% impurities).

[0054]Calcium (Ca)—pure Ca (less than 0.1% impurities).

[0055]Contrary to the alloying procedure described in CN1752251, where intermediate Mg—Nd, Mg—Ca and Mg— Zr master alloys were used, the alloys of the present invention have been prepared using pure Nd and pure Ca that significantly simplifies the process, reduces its duration and markedly lowers the alloy cost. Neodymium and zirconium were added typically at 770-780° C. with intensive stirring of the melt. After addition of zirconium, the melt was held f...

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Abstract

The invention provides a magnesium based alloy consisting of at least 94.8% magnesium, 2.5-4.6% neodymium, 0.05-0.40% yttrium, and 0.03-0.65% zirconium, exhibiting good castability, high strength, high corrosion resistance and high creep resistance even at high temperatures. The alloy is suitable for high pressure die casting, sand casting, investment casting, permanent mold casting, twin roll casting, or direct chill casting.

Description

FIELD OF THE INVENTION[0001]The present invention relates to creep-resistant magnesium-based alloys for applications at high temperatures which exhibit good castability, particularly suitable for high-pressure die casting, but advantageously used also in a processes comprising sand casting, investment casting, permanent mold casting, as well as direct chill casting or twin-roll casting.BACKGROUND OF THE INVENTION[0002]The magnesium industry is experiencing dramatic growth, in part due to the demands of the transportation industry to improve fuel economy and emissions. In addition, a great progress in weight reduction has been made in consumer applications of magnesium alloys such as power hand tools, lawn and garden equipment, electronic and optical equipment, etc. In order to significantly expand the above applications, new advanced alloys are required.[0003]High pressure die casting (HPDC) is the dominant form of casting due to its productivity and suitability for mass production....

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C22C23/06B22D21/00C22F1/06
CPCC22C23/06B22D21/007C22F1/06
Inventor BRONFIN, BORISNAGAR, NIRKOTLOVSKY, VLADIMIRMOSCOVITCH, NIR
Owner DEAD SEA MAGNESIUM
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