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Anti-refractive film

a technology of anti-reflective film and film layer, which is applied in the direction of reflecting/signal paint, synthetic resin layered products, wave/particle radiation analysis, etc., can solve the problems of deterioration of screen sharpness, weak interlayer adhesion (interfacial adhesion), and deterioration of scratch resistance, so as to achieve low reflectance and high light transmittance , the effect of high scratch resistance and anti-pollution

Active Publication Date: 2018-04-19
LG CHEM LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides an anti-reflective film that has low reflectance and high light transmittance, while also being highly scratch resistant and anti-pollution. Additionally, the film improves the sharpness of the screen of a display device. The technical effect of this invention is to provide a better viewing experience for users of display devices. The invention also provides a manufacturing method for this anti-reflective film.

Problems solved by technology

However, since in the AG coating method, sharpness of a screen is deteriorated due to surface unevenness, recently, the AR coating method has been variously studied.
However, in the method of forming a plurality of layers as described above, since a process of forming each of the layers is separately performed, close interlayer adhesion (interfacial adhesion) may be weak, such that scratch resistance may be deteriorated.
However, in the case of using the particles with a nanometer size, it was difficult to increase scratch resistance while decreasing reflectance of the low-refractive layer, and an anti-pollution property of a surface of the low-refractive layer was significantly deteriorated due to the particles with the nanometer size.
Therefore, various studies for decreasing an absolute reflection amount of light incident from the outside and improving an anti-pollution property together with scratch resistance of a surface have been conducted, but physical properties of the anti-reflective film are not sufficiently improved in spite of these studies.

Method used

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Examples

Experimental program
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Effect test

preparation example

Preparation Example: Manufacturing of Hard Coating Film

[0177]A salt-type antistatic hard coating solution (KYOEISHA Chemical Co., Ltd., solid content: 50 wt %, product name: LJD-1000) was coated on a triacetyl cellulose film using a #10 Mayer bar, dried at 90□ for 1 minute, and irradiated with UV light (150 mJ / cm2), thereby manufacturing a hard coating film having a thickness of about 5 μm.

examples 1 to 5

f Anti-Reflective Film

examples 1 to 4

[0178](1) Preparation of Photocurable Coating Composition for Forming Low-Refractive Layer

[0179]Based on 100 parts by weight of pentaerythritol triacrylate (PETA), 281 parts by weight of hollow silica nanoparticles (diameter: about 50 to 60 nm, density: 1.96 g / cm3, JGC Catalyst and Chemicals), 63 parts by weight of solid silica nanoparticles (diameter: about 12 nm, density: 2.65 g / cm3), 131 parts by weight of a first fluorine-containing compound (X-71-1203M, Shin-Etsu), 19 parts by weight of a second fluorine-containing compound (RS-537, DIC), and 31 parts by weight of an initiator (Irgacure 127, Ciba) were diluted in a solvent in which methyl isobutyl ketone (MIBK), diacetone alcohol (DAA), and isopropyl alcohol were mixed at a weight ratio of 3:3:4 so that a solid content was 3 wt %.

[0180](2) Manufacturing of Low-Refractive Layer and Anti-Reflective Film

[0181]The photocurable coating composition obtained above was coated on the hard coating film in the preparation example using a ...

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Abstract

Disclosed herein is an anti-reflective film including: a hard coating layer; and a low-refractive layer containing a binder resin, and hollow inorganic nanoparticles and solid inorganic nanoparticles which are dispersed in the binder resin, wherein the low-refractive layer includes a first layer containing at least 70 vol % of the entire solid inorganic nanoparticles and a second layer containing at least 70 vol % of the entire hollow inorganic nanoparticles, and at the time of fitting polarization ellipticity measured by ellipsometry for the first layer or / and the second layer included in the low-refractive layer using a Cauchy model represented by the following General Equation 1, the second layer satisfies a predetermined condition.

Description

FIELD OF THE INVENTIONCROSS-REFERENCE TO RELATED APPLICATION[0001]This application claims the benefit of Korean Patent Application No. 10-2016-0028468 filed on Mar. 9, 2016, Korean Patent Application No. 10-2016-0029336 filed on Mar. 11, 2016, Korean Patent Application No. 10-2016-0030395 filed on Mar. 14, 2016, and Korean Patent Application No. 10-2017-0029953 filed on Mar. 9, 2017 with the Korean Intellectual Property Office, the disclosures of which are herein incorporated by reference in their entirety.[0002]The present invention relates to an anti-reflective film. More particularly, the present invention relates to an anti-reflective film capable of having low reflectance and high light transmittance, simultaneously implementing scratch-resistance and an anti-pollution property, and enhancing sharpness of a screen of a display device.BACKGROUND OF THE INVENTION[0003]In general, an anti-reflective film is mounted on a flat-panel display device such as a plasma display panel (PDP...

Claims

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Application Information

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IPC IPC(8): G02B1/115C09D5/00C09D7/40C09D135/02B05D3/02B05D3/06G02B1/14C08J7/043C08J7/044C08J7/046
CPCG02B1/115C09D5/006C09D7/67C09D135/02B05D3/0254B05D3/067G02B1/14B05D1/28C08K3/36C08K7/26C08K2201/011B32B27/08B32B27/18C08C19/40C08F265/06C08J7/042C08L33/10C08L83/04C09D4/00C09D4/06C09D5/00C09D5/004G01N23/207G02B1/11G02B1/113G02B5/18C09D7/61C08K3/01C08J2301/02C08J2435/02C08K7/18C08L27/12G02B1/12B32B2264/12C08L2203/16B32B2264/102B32B7/023B32B7/02
Inventor SONG, IN YOUNGBYUN, JIN SEOKKIM, BOO KYUNGJANG, SEOK HOONCHANG, YEONG RAEOH, SUNG JOON
Owner LG CHEM LTD
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