Light diffusion film
A technology of light diffusing film and catalyst, applied in optics, light guides, optical components, etc., can solve problems such as damage to production efficiency, pollution of light diffusing film, low performance, etc., and achieve the effect of good scratch resistance
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[0089] The invention is illustrated by the following examples.
Synthetic example 1
[0091] Into a dry reaction vessel equipped with a stirrer, a thermometer, a cooler, and a nitrogen conduit, 42 parts by mass of polycaprolactone triol (Praccel 308, manufactured by Daicel Chemical Co., Ltd.) and 50 parts by mass of hexamethylene diisocyanate were mixed. (hereinafter, abbreviated as HDI), 0.1 parts by mass of dibutyltin dilaurate, and reacted for 10 hours while stirring under the condition of 120° C. in a nitrogen atmosphere. Then, after removing unreacted HDI under reduced pressure, toluene was added to obtain a prepolymer (1) having a nonvolatile content of 90% by mass.
[0092] In a separable flask with a stirrer, 670 parts by mass of 2% methyl cellulose water was mixed, and while stirring, 102 parts by mass of prepolymer (1), 100 parts by mass of methyl methacrylate, A solution consisting of 10 parts by mass of toluene and 2 parts by mass of tert-butyl peroxytrimethylacetate (Perbull PV, manufactured by NOF Corporation) was prepared as a suspension. Under ...
Synthetic example 2
[0094] Using the same method as in Synthesis Example 1, 48 parts by mass of polycaprolactone diol (Praccel 210, manufactured by Daicel Chemical Co., Ltd.), 42 parts by mass of HDI, and 0.1 part by mass of octyltin dilaurate were reacted, and toluene was added. , to obtain a prepolymer (2) having a nonvolatile content of 70% by mass.
[0095] In a separable flask with a stirrer, 700 parts by mass of 3% methylcellulose water was mixed, and while stirring, 128 parts by mass of prepolymer (2), 75 parts by mass of methyl methacrylate, A solution consisting of 25 parts by mass of n-butyl methacrylate and 3 parts by mass of t-butylperoxy-2-ethylhexanoate (Cayaestel O, manufactured by Kayaku Akuzo Co., Ltd.) was prepared as a suspension. Under the condition of stirring, raise the temperature of the suspension to 60°C and react for 5 hours, then raise the temperature to 100°C for more than 1 hour, and separate toluene by azeotropic method. After cooling, carry out solid-liquid separati...
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