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Alkyl- fragrant benzyl- polyethenoxy ether anionic surfactant and method of preparing the same and use thereof

A technology of alkyl arylbenzyl polyoxyethylene ether and alkyl arylbenzyl polyoxyethylene ether alcohol, which is applied in the field of alkyl arylbenzyl polyoxyethylene ether anionic surfactants and preparation thereof, and can solve the problem of unresolved problems. and alkyl arylbenzyl polyoxyethylene ether anionic surfactants

Inactive Publication Date: 2009-08-26
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] CN1296115A discloses the application of industrial product polyoxyethylene nonylphenol ether acetate in enhancing oil recovery, it does not mention alkyl aryl benzyl polyoxyethylene ether anionic surfactant equally

Method used

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  • Alkyl- fragrant benzyl- polyethenoxy ether anionic surfactant and method of preparing the same and use thereof
  • Alkyl- fragrant benzyl- polyethenoxy ether anionic surfactant and method of preparing the same and use thereof
  • Alkyl- fragrant benzyl- polyethenoxy ether anionic surfactant and method of preparing the same and use thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0065] Embodiment 1: the preparation of octyl benzyl trioxyethylene ether sodium acetate

[0066] (a) Preparation of Octylbenzyl Chloride

[0067] Put 0.5mol octylbenzene in the reaction kettle, then add 1mol paraformaldehyde and 0.35mol powdered anhydrous zinc chloride, add 110mL glacial acetic acid as solvent, stir vigorously and quickly pass in dry hydrogen chloride gas, at 70~ React at 80°C until hydrogen chloride is no longer absorbed, about 2 hours, cool to room temperature, separate the upper organic phase, and extract the lower acetic acid phase with petroleum ether for 2 to 3 times, combine the organic phases with 10wt% sodium carbonate and water in sequence Wash until neutral, dry with anhydrous sodium sulfate, add a little sodium bicarbonate to distill under reduced pressure, collect fractions at 165-167°C / 3.5mmHg, the yield is 75%, and it is a colorless liquid at room temperature. That 1 H NMR spectrum see figure 1 .

[0068] (b) Preparation of Octylbenzyl Trio...

Embodiment 2

[0076] Embodiment 2: Preparation of ammonium lauryl benzyl tetraoxyethylene ether sulfate

[0077] (a) Preparation of lauryl benzyl chloride

[0078] Put 0.5mol laurylbenzene in the reaction kettle, then add 0.9mol paraformaldehyde and 0.32mol powdered anhydrous zinc chloride, add 120mL glacial acetic acid as solvent, stir vigorously and quickly pass dry hydrogen chloride gas, at 85 React at ~90°C until hydrogen chloride is no longer absorbed, about 1.5 hours, cool to room temperature, separate the upper organic phase, and extract the lower acetic acid phase with petroleum ether for 2 to 3 times, combine the organic phases with 10wt% sodium carbonate and Wash with water until neutral, dry with anhydrous sodium sulfate, add a little sodium bicarbonate to distill under reduced pressure, collect fractions at 190-193°C / 3.5mmHg, the yield is 72%, and it is a white solid at room temperature.

[0079] (b) Preparation of lauryl benzyl tetraoxyethylene ether alcohol

[0080] Get the ...

Embodiment 3

[0084] Embodiment 3: the preparation of sodium octyl benzyl trioxyethylene ether propyl sulfonate

[0085] (a) Preparation of Octylbenzyl Chloride

[0086] Put 0.5mol octylbenzene in the reaction kettle, then add 1mol paraformaldehyde and 0.35mol powdered anhydrous zinc chloride, add 110mL glacial acetic acid as solvent, stir vigorously and quickly pass in dry hydrogen chloride gas, at 70~ React at 80°C until hydrogen chloride is no longer absorbed, about 2 hours, cool to room temperature, separate the upper organic phase, and extract the lower acetic acid phase with petroleum ether for 2 to 3 times, combine the organic phases with 10wt% sodium carbonate and water in sequence Wash until neutral, dry with anhydrous sodium sulfate, add a little sodium bicarbonate to distill under reduced pressure, collect fractions at 165-167°C / 3.5mmHg, the yield is 75%, and it is a colorless liquid at room temperature.

[0087] (b) Preparation of Octylbenzyl Trioxyethylene Ether Alcohol

[00...

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Abstract

The invention belongs to high efficient surface activating agent filed, in particular relating to alkylPolyoxy divinyl ether and the anion surface activating agent preparation method and use. After a series of reaction, the alkyl aromatic hydrocarbon forms a nonionic to anion surface activating agent substance with an aryl benzyl structure. The molecular structure of the surface activating agent substance decides that the invention has low acrimony and toxicity, good degradation performance, good water solubility and hardwater resistance, high efficiency forming capability and excellent anti-salt performance; the surface activating agent has high activity, the critical tension with various different crude oil can reach super low (10 to 3Mn / m), which has good application prospect in domestic chemical, sanitation, three-time oil extracting, spinning industry, leatherworking, pesticide emulsion and other fields. The chemical structure of the surface activating agent is as the drawing.

Description

technical field [0001] The invention belongs to the field of high-efficiency surfactants, and in particular relates to an alkylaryl benzyl polyoxyethylene ether anionic surfactant of a nonionic-anionic surfactant, a preparation method and an application thereof. Background technique [0002] Anionic nonionic surfactants, such as alkylphenol ether polyoxyethylene ether sulfate and acetate, have two types of hydrophilic groups, which overcome the adverse effects of low cloud points and greatly broaden the scope of nonionic surfactants. The application field of surfactant has been widely used in actual production. [0003] However, due to the presence of phenolic oxygen bonds in alkylphenol polyoxyethylene ethers, alkylphenols with strong biological toxicity will be produced during the degradation process, which limits their application in real life and industrial production. [0004] US4485873 discloses the application of polyoxyethylene alkylphenol ether acetate in enhanced ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01F17/42C09K23/42
Inventor 赵濉王显光俞稼镛徐志成罗澜严峰安静仪
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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