Polyamide imide polymer, its preparing method and use in paint-coated wire insulation layer
A polyamide-imide, manufacturing method technology, applied in the direction of insulated conductors, insulated cables, conductors, etc., can solve the problems of polymer hydrolysis, the decline of polymer heat resistance and other characteristics, and achieves improved heat resistance and improved reliability. Workability, low viscosity effect
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Embodiment 1
[0043] Embodiment 1: the manufacture of polyamide-imide polymer
[0044] Add nitrogen into a 200ml stainless steel reactor, dissolve pyromellitic anhydride and trimellitic anhydride in N-methyl-2-pyrrolidone according to the amount shown in Table 1, and add it to the stainless steel reactor, and then stir the reactor at a speed of about 100RPM After adding 4,4-methylene diphenyl diisocyanate and a certain amount of cresol at the same time, stir at 100RPM for 30 minutes, then slowly heat up to 70°C over 2 hours, then after 2 hours (10°C / 20min ) was heated up to 140°C again. Stir with 100 RPM speed for about 30 minutes while the temperature of above-mentioned solution keeps 140 ℃, the temperature of solution after reaction finishes slowly reduces to 40 ℃, add N-methyl-2-pyrrolidone afterward and dilute the solution to 40% (weight ratio), the solution was stirred for about 4 hours to make a polyamideimide polymer solution.
[0045] Table 1
[0046] Example 1
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