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Method for purifying superfine montmorillonite

A purification method and montmorillonite technology, applied in chemical instruments and methods, inorganic chemistry, non-metallic elements, etc., can solve the problems of limited improvement of bentonite dispersibility, cumbersome sodium treatment, water and energy consumption, etc. Suspension performance, wide application range, high yield effect

Active Publication Date: 2007-10-10
湖北三鼎科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The sodium treatment of this method is cumbersome, and the extrusion sodium treatment method needs aging to improve the dispersion performance of bentonite, while the solution sodium treatment method consumes water and energy, and the dispersibility of bentonite after treatment is limited.

Method used

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  • Method for purifying superfine montmorillonite
  • Method for purifying superfine montmorillonite
  • Method for purifying superfine montmorillonite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Zhejiang bentonite is mainly made up of minerals such as montmorillonite, quartz, feldspar, kaolin, wherein montmorillonite content is 74%, and its XRD diffraction pattern is shown in accompanying drawing 1, according to soil-water ratio (the weight ratio of bentonite ore and water ) 1:4 soaked in a high-speed mixer to make slurry, and passed through a 200-mesh sieve to remove large particles of impurities, and then input the slurry into the MBP80 type peeler for ultra-fine peeling. After slurry particle size distribution D 50 1.26μm, D 75 The particle size distribution of the ultra-fine slurry is 1.98 μm, and the ultra-fine slurry is swirled in a hydrocyclone to remove fine sand, and the particle size distribution of the high-purity slurry obtained after classification is D 90 1.9 μm, finally dehydrated, dried and pulverized to obtain high-purity ultrafine montmorillonite, its XRD diffraction pattern is shown in Figure 2.

[0035] It can be seen from accompanying dra...

Embodiment 2

[0037] The Sichuan bentonite ore 1 is mainly composed of two minerals, montmorillonite and quartz, wherein the content of montmorillonite is 81%, and its XRD diffraction pattern is shown in Figure 3, after pulping in a pulper according to the soil-water ratio of 1:6 Pass through a 100-mesh sieve to remove large particles of impurities, and then input the slurry into a sand mill for ultra-fine peeling. The specific gravity of the grinding medium selected in the sand mill is 3.2, and the particle size distribution of the ultra-fine slurry is D 50 1.02μm, D 75 The ultra-fine slurry is centrifugally classified in a centrifuge to remove fine sand, and the particle size distribution of the high-purity slurry obtained after classification is D 90 1.98 μm, finally dehydrated, dried and pulverized to obtain high-purity ultrafine montmorillonite, its XRD diffraction pattern is shown in Figure 4.

[0038]It can be seen from accompanying drawing 4 that the high-purity ultrafine montmoril...

Embodiment 3

[0040] The Sichuan bentonite raw ore 2 is mainly composed of montmorillonite and quartz two minerals, wherein the content of montmorillonite is 92%, and its XRD diffraction pattern is shown in accompanying drawing 5, after pulping in a pulping machine according to the soil-water ratio of 1:8 Pass through a 180-mesh sieve to remove large particles of impurities, and then enter the slurry into the MBP80 type peeler for ultra-fine peeling. The specific gravity of the grinding medium selected in the peeler is 4.2, and the particle size distribution of the ultra-fine slurry is D 50 1.44μm, D 75 The ultra-fine slurry is centrifugally classified in a centrifuge to remove fine sand, and the particle size distribution of the high-purity slurry obtained after classification is D 90 1.51 μm, finally dehydrated, dried and pulverized to obtain high-purity ultrafine montmorillonite, its XRD diffraction pattern is shown in Figure 6.

[0041] It can be seen from accompanying drawing 6 that t...

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Abstract

This invention discloses a method for finely purifying montmorillonite. The method comprises: mixing bentonite ore and water at a ratio of 1:(2-9) to obtain slurry, soaking and stirring in a stirrer, sieving with 100-325 mesh sieve to remove large particles, sending the slurry to an ultrafine exfoliation apparatus for ultrafine exfoliation, classifying by a classifier to remove fine sand and obtain ultrapure and ultrafine slurry, dehydrating, drying, and pulverizing to obtain ultrapure and ultrafine montmorillonite. Ultrafine exfoliation effectively breaks the aggregation of montmorillonite and impurity ore, thus can improve the dispersion and suspension performance of montmorillonite, and is advantageous for following classification and purification. Classification by using specific gravity can obtain ultrapure and ultrafine montmorillonite. The method has such advantages as no need for dispersant, simple process, and high yield, and is suitable for mass production.

Description

technical field [0001] The invention relates to an ultrafine purification method of montmorillonite, which belongs to the technical field of deep processing of montmorillonite. Background technique [0002] Montmorillonite (montmorillonite), also known as microcrystalline kaolinite, is a layered structure, flaky crystal silicate clay ore, named after it was first discovered in Montmorillon, France, in the geological age by Made from natural volcanic ash. The montmorillonite particles are fine, about 0.2-1 micron, with colloidal dispersion characteristics, and are usually produced in the form of massive or soil-like aggregates. Observed under an electron microscope, the crystals are monoclinic and generally in the form of irregular flakes. The color is white with light gray, sometimes with light blue or light red, dull luster; Mohs hardness 2-2.5, specific gravity 2-2.7. It has strong adsorption capacity and ion exchange capacity, and also has high ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/40C01B33/38
Inventor 吕大丰谌刚杨建秀许佳亮寿瑾枫
Owner 湖北三鼎科技有限公司