Photosensitive combination and photosensitive transprinting material using same, display device shading film and manufacturing method, black matrix, substrate having shading film and display device
A technology of photosensitive composition and display device, which is applied in optics, optomechanical equipment, nonlinear optics, etc., can solve the problems of poor sensitivity, high cost, condensation, etc., and achieve the effect of good sensitivity
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Embodiment 1
[0200] (Example 1): coating method
[0201]
[0202] In 1000ml of pure water, dissolve 23.1g of silver acetate (I), 65.1g of tin (II) acetate, 54g of gluconic acid, 45g of sodium pyrophosphate, 2g of polyethylene glycol (molecular weight 3,000) and PVP-K30 Japan Co., Ltd.; polyvinylpyrrolidone polymer) 5 g, and a solution 1 was obtained.
[0203] Separately, 46.1 g of hydroxyacetone was dissolved in 500 ml of pure water to obtain a solution 2.
[0204]On the one hand, the above-obtained solution 1 was kept at 25° C., on the other hand, the above-mentioned solution 2 was added thereto over 2 to 2 minutes while vigorously stirring, and the stirring was continued slowly for 6 hours. Then, the mixed solution turns black, and metal particles having silver-tin alloy parts (hereinafter, sometimes referred to as "silver-tin alloy part-containing particles") are obtained. Then, the mixed solution was centrifuged to precipitate the silver-containing tin alloy particles. The operati...
Embodiment 2~6 and comparative example 1、2
[0297] (Examples 2-6 and Comparative Examples 1 and 2): Coating method
[0298] In the above-mentioned Example 1, except that the photosensitive coating liquid A1 for BM was changed to A2-A8 described in Table 1, a black matrix, a color filter, and a liquid crystal were prepared in the same manner as in Example 1. display device.
Embodiment 7
[0299] (Example 7) transfer method
[0300] In the said Example 1, except having changed the manufacturing method of the black matrix into the following transfer method, the color filter and the liquid crystal display device were manufactured by the same method.
[0301]
[0302] -Production of photosensitive transfer material-
[0303] On a polyethylene terephthalate film temporary support (PET temporary support) with a thickness of 75 μm, apply a coating liquid for a thermoplastic resin layer consisting of the following formulation H1 using a slit nozzle and let it dry , forming a thermoplastic resin layer. Then, an intermediate layer coating liquid composed of the following formulation P1 was further applied on the thermoplastic resin layer, dried, and the intermediate layer was laminated. Next, the photosensitive coating liquid A1 for BM prepared in Example 1 was apply|coated and dried on the intermediate layer, and the black photosensitive composition layer was furthe...
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