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Modified composite for bulk polymerization acrylonitrile-butadiene-styrene and preparation method thereof

A bulk polymerization and acrylonitrile technology, which is applied in the field of bulk polymerization of acrylonitrile-butadiene-styrene modified compounds and their preparation, can solve problems such as unpleasant smell, and achieve low odor volatility and excellent flame retardant performance. Effect

Active Publication Date: 2010-05-26
SHANGHAI KINGFA SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, because acrylonitrile-butadiene-styrene ABS will release some unpleasant odors to varying degrees, especially various automotive interior parts made of acrylonitrile-butadiene-styrene ABS materials, etc. Material products have gradually been questioned by many consumers; and ABS is a flammable material (oxygen index is 18.3-20.0), and it will release a lot of smoke that is easy to suffocate when burned. As people's awareness of environmental protection continues to increase, Acrylonitrile-butadiene-styrene ABS will be more challenged in these aspects, and higher and higher requirements are put forward for acrylonitrile-butadiene-styrene ABS materials. In order to further expand acrylonitrile-butadiene-styrene ABS For the application of diene-styrene ABS materials in related fields, and to improve the cost performance of acrylonitrile-butadiene-styrene ABS, it is necessary to find an effective way to prepare low-odor, even odorless, and excellent barrier properties. Flammable acrylonitrile-butadiene-styrene ABS material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0032] The raw material formula that present embodiment adopts:

[0033] The raw materials of ABS used in the ontology method are ABS3453 and 3904 of DOW Company;

[0034] The heat-resistant modifier is a copolymer of N-phenylmaleimide PMI and acrylonitrile-styrene copolymer AS of Nihonden Chemical Co., Ltd.; α-methylstyrene α produced by Wuxi Henghui Chemical Co., Ltd. -MS; N, N'--4,4'-diphenylmethane bismaleimide produced by Taian Fine Chemical Co., Ltd.;

[0035] The ultraviolet absorber is 2-(2'-hydroxy-5'-methylphenyl) triazole TINUVIN 326 produced by Guangzhou Chengcheng Chemical Co., Ltd.; 2-hydroxy-4-methanol produced by Nanjing Milan Chemical Co., Ltd. Oxybenzophenone UV-9;

[0036] The silicone masterbatch is Si-ABSMB50-313 with a silicone content of 50% produced by Dow Corning Corporation of the United States;

[0037] The odor inhibitor is made of domestic silica porous silica gel material;

[0038] The flame retardant is nano aluminum hydroxide, magnesium hydr...

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Abstract

The present invention relates to a bulk polymerized acrylonitrile-butadiene-styrene modified complex. The present invention is characterized in that the complex consists of the raw materials of the following weight percentages: 58.0 to 86.5 percent of acrylonitrile-butadiene-styrene (ABS), 10 to 24 percent of heat-resistant modifier, 0.3 to 1.0 percent of UV absorber, 0.5 to 3 percent of siliconemaster batch, 0.5 to 5 percent of odor inhibitor, 2 to 8 percent of flame retardant, 0.1 to 1 percent of lubricant, and 0.1 to 1 percent of coupling agent. The preparation method is: the raw materialsare weighed according to the weight percentages; the bulk acrylonitrile-butadiene-styrene (ABS) resin, the UV absorber, the odor inhibitor, the silicone master batch, the flame retardant and the processing acid are dried and mixed in the high-speed mixer for 3 to 5 minutes; the mixed raw materials are arranged in the twin-screw machine to melt, extrude and granulate; in the extrusion process, theheat-resistant modifier is added evenly through the measurement of the lateral precise feeding system; the pull strip is extruded, and the mixture is cooled, palletized and dried; then the final produce can be made. The advantage of the present invention is that the product has the smell volatility and the good flame-retardant properties; the produce is suitable for the industry and field of theinterior decorative component of the automobile, the refrigerator, the electronic appliance and so on.

Description

technical field [0001] The present invention relates to a kind of bulk polymerized acrylonitrile-butadiene-styrene modified compound and preparation method thereof, especially to a kind of acrylonitrile-butadiene-styrene ternary copolymerization resin (ABS) produced by bulk method ) modified composite material, specifically involving the preparation of a modified composite material suitable for various fields such as automotive interior parts, refrigerators, and electronic appliances by adding nano-scale flame retardants and odor inhibitors that can effectively suppress unpleasant odors. The utility model relates to a non-volatile body ABS material, which belongs to the technical field of chemical materials. Background technique [0002] Styrene acrylonitrile copolymer, that is, acrylonitrile-butadiene-styrene ABS (acrylnitrile-butadiene-strene copolymer), due to its excellent processing properties, good mechanical properties, and chemical resistance, it is widely used in au...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L55/02C08K5/3475C08L25/04C08L83/00C08K5/07
Inventor 宋晓东夏建盟吉继亮吴晓辉袁绍彦杨定吉甫吴晶晶
Owner SHANGHAI KINGFA SCI & TECH