Unlock instant, AI-driven research and patent intelligence for your innovation.

A catalyst for cleaning CO as well as its preparing method and application

A catalyst and fluoride technology, applied in the field of CO scavenging catalysts and its preparation, can solve the problems of poor selectivity of noble metal catalysts, scarce price of precious metal resources, narrow activity temperature range, etc., to achieve reduced energy consumption, high economic value, and simplified production The effect of craft

Inactive Publication Date: 2008-04-09
NAVY MEDICINE RES INST OF PLA
View PDF0 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Due to the poor selectivity of noble metal catalysts, the narrow range of active temperature, and the scarcity and high price of precious metal resources, it is urgent to develop a comparable hybrid catalyst

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Weigh 21.7 g Ce(NO 3 ) 2 , Dissolved in 50ml of aqueous solution. Weigh 1.8 grams of Al 2 o 3 Powder, evenly drop Ce(NO 3 ) 2 Aqueous solution 1.2ml, left for 24 hours overnight, dried at 70°C for 10 hours, shaken during drying. After drying, crush it, pass through a 40-mesh sieve, and put it into a muffle furnace for roasting at 300°C for 3 hours. Take out and pulverize, pass through a 40-mesh sieve, and set aside. Weigh 21.7 g of PdCl 2 , make a 50ml solution in dilute HCl, evenly drop 1.74ml into the prepared powder, leave it for 24 hours overnight, dry at 70°C for 10 hours, and shake during the drying process. After drying, crush it, pass through a 20-mesh sieve, and put it into a muffle furnace for roasting at 300°C for 3 hours. Take out and pulverize, and pass through a 20-mesh sieve. In the U-shaped glass tube, the two ends are blocked with glass wool, and the H 2 Reduction for 1 hour, and in H 2 gradually cooled to room temperature. Catalyst activit...

Embodiment 2

[0043] The catalyst preparation steps are basically the same as in Example 1. Weigh 1.4 g Al 2 o 3 Powder, evenly drop Ce(NO 3 ) 2Aqueous solution 3.5ml, left for 24 hours overnight, dried at 120°C for 10 hours, shaking during drying. After drying, crush it, pass through a 40-mesh sieve, and put it into a muffle furnace for roasting at 500°C for 3 hours. Take out and pulverize, pass through a 40-mesh sieve, and set aside. Evenly add 1.74ml PdCl dropwise 2 Add the hydrochloric acid solution to the prepared powder, place it overnight for 24 hours, and dry it at 120°C for 10 hours, shaking it during the drying process. After drying, crush it, pass through a 20-mesh sieve, and put it into a muffle furnace for roasting at 500°C for 3 hours. Take out and pulverize, and pass through a 20-mesh sieve. In the U-shaped glass tube, the two ends are blocked with glass wool, and the H 2 Reduction for 1 hour, and in H 2 gradually cooled to room temperature. Catalyst activities are...

Embodiment 3

[0045] The catalyst preparation steps are basically the same as in Example 1. Weigh 1.6 grams of Al 2 o 3 Powder, evenly drop Ce(NO 3 ) 2 Aqueous solution 2.3ml, left overnight for 24 hours, dried at 70°C for 10 hours, shaking during drying. After drying, crush it, pass through a 40-mesh sieve, and put it into a muffle furnace for roasting at 500°C for 3 hours. Take out and pulverize, pass through a 40-mesh sieve, and set aside. Evenly add 3.5ml PdCl 2 The hydrochloric acid solution was added to the prepared powder, placed overnight for 24 hours, dried at 70°C for 10 hours, and shaken during the drying process. After drying, crush it, pass through a 20-mesh sieve, and put it into a muffle furnace for roasting at 500°C for 3 hours. Take out and pulverize, and pass through a 20-mesh sieve. In the U-shaped glass tube, the two ends are blocked with glass wool, and the H 2 Reduction for 1 hour, and in H 2 gradually cooled to room temperature. Catalyst activities are list...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
pulverizationaaaaaaaaaa
Login to View More

Abstract

The invention relates to the catalyst technical field, in particular to catalyst used for clearing CO, and the preparation method and the application thereof. The invention discloses the catalyst for clearing CO under the low-temperature condition, and consists of the following components of the weight ratio by the molecular weight: 10 percent to 40 percent of CeO2 , 0.1 percent to 5 percent of Pd, and carrier surplus of porous inorganic oxide. The catalyst of the invention has remarkable elimination function to the CO with the certain concentration in the room temperature, and can instantly complete the degradation to the CO with the low concentration, and the effect can maintain 200 hours. Compared with the catalyst, the operation temperature of homogeneous catalyst is high, the making procedure is complex, and the price is expensive. The invention can simplify the making process of the catalyst, the energy consumption is reduced during making and operation, and the catalyst has higher economic value.

Description

Technical field: [0001] The invention relates to the technical field of catalysts, in particular to a catalyst for removing CO and its preparation method and application. Background technique: [0002] As we all know, CO is a typical flammable and toxic compound. It is a colorless, odorless, highly toxic gas. CO combines with hemoglobin in the human body, weakens the oxygen transport capacity of hemoglobin, and damages the human central nervous system. In the case of relatively low concentration, the reaction is headache and nausea. Continuous exposure to high concentrations of carbon monoxide can cause coma or even death. When the content in the air reaches 12.5%, it can explode in case of fire; when the CO content in the air is 2.0×10 -5 mol / L, people will appear dizzy and vomiting within two hours; when the content reaches 1.2%, it will cause death within 1-3min. Combustion of fossil fuels, the chemical industry, and the use of motor vehicles, resulting in large amou...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/83A61L9/01C01B31/20C01B32/50
Inventor 方晶晶许林军鲁毅钧肖存杰徐新宏
Owner NAVY MEDICINE RES INST OF PLA