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Reduced-emissions combustion utilizing multiple-component metallic combustion catalyst and lightly catalyzed diesel oxidation catalyst

An oxidation catalyst, diesel engine technology, applied in the direction of combustion using catalytic materials, fuel additives, special configuration of fuel supply, etc., can solve problems such as PM reduction

Inactive Publication Date: 2008-04-09
CLEAN DIESEL TECHNOLOGIES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Catalyzed DOC is not considered effective, it can only provide 20-25% reduction in PM

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] This example reports the testing of a 1990 International DT 466 7.6L diesel engine operated on a repeated thermal transient test cycle on an engine dynamometer. Emissions results are the average of three runs and are measured in grams per horsepower-hour. Tests on untreated No. 2 diesel fuel with >300 ppm sulfur yielded baseline particulate emissions of 0.253 g / hp-hr and NO of 1.1 g / hp-hr 2 Or 18% of the total nitrogen oxides in the exhaust. Using a bimetallic FBC at a dose rate of 0.15ppm Pt and 7.5ppm Ce in No.2D fuel, PM was reduced by 15% to 0.215 g / hp-hr while NO 2 Reduced to 12% of total nitrogen oxide emissions.

[0029] Install with 3g / ft 3 The noble metal loaded lightly catalyzed ceramic DOC, run on untreated No. 2D fuel, produced PM emissions of 0.196 g / hp-hr or a 23% reduction over the baseline. NO was not measured due to unavailability of test equipment 2 . Using FBC-treated No.2D with lightly catalyzed DOC, reduced PM emissions to 0.178 g / hp-hr, a 30%...

Embodiment 2

[0037] This example presents a single cold and three hot FTP transient test cycles for the FBC / DOC combination on a 1990 Cummins 8.3 liter 6 CTA, 275 hp medium heavy duty engine certified to meet the 1991 emission standards for NOx and PM test results. The engine was first run on untreated No. 2D fuel (>300 ppm sulfur) with no exhaust aftertreatment DOC installed. Particulate emissions were determined from the average composite at 0.190 g / hp-hr.

[0038] The fuel was switched to FBC treated commercial ULSD (2 Also from 0.9 g / hp-hr to 0.4 g / hp-hr, a reduction of over 50%.

[0039] The DOC is a 9.5" diameter x 6"L 400cpsi ceramic substrate, manufactured by Corning, Inc., and uses 0.3g / ft 3 It is catalyzed by precious metals from Clean Air Systems, Inc. of New Mexico. Mount it in a stainless steel tank with regular inlet and outlet cones. The FBC was a platinum / cerium bimetallic used at a dose rate of 0.5ppm / 7.5ppm.

[0040] The same field aged DOC-2 that had been operated i...

Embodiment 3

[0046] This Example reports experiments further demonstrating the benefit of low levels of FBC in ULSD combined with lightly catalyzed DOC. In this example, a 7.6 liter engine was tested on a 1995 Navistar DT466 in a single cold test cycle and three hot test cycles. The average of the three composite emissions results was calculated and reported in grams per horsepower-hour. Baseline emissions results on untreated No.2D fuel (>300ppm S) showed an average PM emission of 0.106 g / hp-hr and NO 2 Emissions were 1.1 g / hp-hour, representing 23% of total NOx emissions.

[0047] Using ULSD (2 down to 0.8 g / hp-hr or 19% of total NOx emissions. Reductions in HC, CO and NOx were also observed for the FBC / ULSD combination.

[0048] In another test, the lightly catalyzed DOC-1 pretreated in Example 2 was installed in the exhaust and the engine was run on the FBC treated ULSD. Total PM emissions were reduced by 45% to 0.058 g / hp-hr while NO 2 This drops to 0.6 g / hp-hr, representing 14% ...

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PUM

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Abstract

An improved diesel operation system employs a lightly diesel oxidation catalyst (DOC), preferably with a platinum containing fuel borne catalyst (FBC) in the fuel. The DOC is at least partially lightly catalyzed with precious metal catalyst, e.g., platinum group metal, having a metal loading of from about 3 to 15 grams per cubic foot to minimize formation of NO2 in the exhaust gas. Preferred fuel borne catalyst levels will be low, e.g., from 0.05 to 0.5 ppm for platinum and 3 to 8 ppm for cerium and / or iron, thereby providing effective engine out emissions reductions without discharging excessive amounts of metal catalysts or NO2 to the atmosphere.

Description

Background technique [0001] The present invention relates to a method for reducing emissions of pollutants of the type produced by incomplete combustion such as particulates, unburned hydrocarbons and carbon monoxide while avoiding increases in NO 2 new method of generation. [0002] Diesel engines have a number of important advantages over Otto-type engines. Among them are fuel economy, easy maintenance and long life. However, from an emissions standpoint, they have more serious problems than their spark-ignition counterparts. Emissions concerns particulate matter (PM), nitrogen oxides (NO x ), unburned hydrocarbons (HC) and carbon monoxide (CO). term NO x Various chemical species used to describe oxides of nitrogen, including nitric oxide (NO) and nitrogen dioxide (NO 2 ). NO has attracted attention because it is believed to undergo a process known as photochemical smog formation through a series of reactions in the presence of sunlight and hydrocarbons, and it is a m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F01N3/00C10L1/10F02M27/02C10L1/30C10L10/14F23C6/04F23C13/00F23J7/00F23K5/08
CPCC10L1/301C10L10/06F01N2430/04F23J7/00F23K2301/103C10L1/189F01N2510/065C10L10/02C10L1/1886C10L1/305F02M25/00F02B3/06F01N3/10F01N3/035F02M27/02F01N3/023C10L1/1814C10L1/10F23K2900/05081C10L1/1241F23K5/08C10L1/1881F23K2300/103F01N3/00
Inventor 詹姆斯·M·瓦伦丁巴里·N·斯普拉格
Owner CLEAN DIESEL TECHNOLOGIES