Bleaching process for broussonetia papyrifera white bast bio-pulp

A technology of biological pulp and white bark, which is applied in the bleaching field of white bark bark, can solve the problems of complex bleaching process, water pollution, large investment in equipment, etc., achieve broad application prospects, reduce dust, and low production cost Effect

Inactive Publication Date: 2008-04-16
大连中植环境生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the use of chlorine-containing bleaching agents in the above bleaching methods, such as chlorine gas, hypochlorite, etc., it is inevitable to produce a large amount of toxic substances AOX (adsorbable organic halides), which can easily cause serious water pollution.
Chlorine dioxide is used for bleaching, although the environmental pollution load is reduced, but chlorine dioxide bleaching agent is difficult to preserve, and must be used as soon as possible after preparation, and the preparation process of chlorine dioxide is more complicated, and the investment in equipment is relatively large.
The core of the modern new TCF (totally chlorine-free) bleaching method is oxygen-alkali treatment. Although oxygen-alkali treatment does not produce AOX, it requires the use of pressure vessels and oxygen generators. The bleaching process is complicated and the energy consumption is high.
None of the above methods can well meet the requirements of the modern environment-friendly bleaching process. Therefore, it is necessary to develop a new pulp bleaching method that can improve the bleaching efficiency without causing environmental load.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Embodiment 1, the bleaching of guangyechu white bark biological pulp

[0015] The method provided by the invention is carried out to the method for bleaching the biological pulp of eucalyptus glabra, comprising the steps of:

[0016] 1) After the glabra glabra biological slurry is mixed with water to a mass percentage concentration of 0.8%, the glabra glabra biological slurry is screened with a 40-mesh slotted sieve, and dust spots are formed in the biological slurry. And the green skin with no fixed shape will be filtered through the sieve, and what remains on the sieve is the biological pulp of guangyechu white skin.

[0017] 2) Adjust the screened bio-pulp with water to a concentration of 0.5% by mass, and use a conical desander to further remove the residual black skin in the slurry.

[0018] It can be seen from the measurement that the whiteness of the Guangyechu Baipi biological pulp after the above screening and purification treatment increased from 43.2% ISO to...

Embodiment 2

[0021] Embodiment 2, the bleaching of wild mulberry bark biological pulp

[0022] 1) After adjusting the wild mulberry bark bio-pulp with water to a mass percentage concentration of 1.0%, use a 60-mesh sieve to screen the wild mulberry bark bio-pulp, and form fine black bark with dust spots in the bio-pulp And the green bark with no fixed shape will filter through the sieve, and what remains on the sieve is the wild mulberry white bark biological pulp.

[0023] 2) Adjust the screened bio-pulp with water to a concentration of 0.5% by mass, and use a conical desander to further remove the residual black skin in the slurry.

[0024] It can be seen from the measurement that the whiteness of the wild mulberry bark biological pulp after the above-mentioned screening and purification treatment has increased from 43.2% ISO to 66.7%, and the KMnO 4 The value dropped from 14.56 to 6.72.

[0025] 3) Use alkaline hydrogen peroxide to carry out supplementary bleaching of the above-mentio...

Embodiment 3

[0027] Embodiment 3, the bleaching of hybrid mulberry bark biological pulp

[0028] 1) After mixing the hybrid white bark biological pulp with water to a mass percentage concentration of 0.6%, use a 30-mesh sieve to screen the hybrid white bark biological pulp, and form fine black skin with dust spots in the biological pulp The green skin with no fixed shape will be filtered through the sieve, and what remains on the sieve is the hybrid white bark biological pulp.

[0029] 2) Adjust the screened bio-pulp with water to a mass percent concentration of 0.6%, and use a conical desander to further remove the residual black skin in the slurry.

[0030] It can be seen from the measurement that the whiteness of the hybrid white bark biological pulp after the above screening and purification treatment has increased from 43.2% ISO to 68.9%, and the KMnO 4 The value dropped from 14.56 to 6.07.

[0031] 3) Supplementary bleaching of the above-mentioned hybrid white bark biological pulp ...

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Abstract

The invention discloses a bleaching method of broussonetia papyrifera white bast bio-pulp, which is passed through a slot screen of 20-60 mesh, and then processed with centrifugal separation, finally processed with supplementary bleaching with alkaline peroxide. The method can remove most colored material in bio-pulp by physical methods of slot screen and centrifugal separation, thereby effectively reducing dirt count in the bio-pulp, the whiteness of the bio-pulp is increased to 80-85 percent ISO from 38-44 percent ISO, the value of KMnO4 is decreased below 5.81 from 14-16, the yield is 90-95 percent, fiber average length is decreased to 6.92 mm from 6.34 mm, requirements of producing white paper or high grade paper classes can be completely fulfilled. Moreover, the method does not use chlorine-containing bleaching agent, has simple technology, low production cost and no environmental pollution. The invention has a wide application prospect in the pulp and paper field.

Description

technical field [0001] The invention relates to a bleaching method of bast fiber in the field of pulp and papermaking, in particular to a bleaching method of mulberry bark biological pulp. Background technique [0002] Existing low hardness pulp, according to different pulping methods, its brightness is all between 20%~40%ISO. In order to meet the needs of producing white paper or high-grade paper, the above-mentioned pulp must be bleached. Traditional bleaching methods use chlorination, alkali treatment, and hypochlorite for three-stage bleaching; modern bleaching methods use chlorine dioxide and other means for multi-stage bleaching. Because all use chlorine-containing bleaching agents in the above-mentioned bleaching methods, such as chlorine gas, hypochlorite, etc., it will inevitably produce a large amount of toxic substances AOX (adsorbable organic halides), which can easily cause serious water pollution. Chlorine dioxide is used for bleaching, although the environme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H11/00D21D5/02D21D5/18D21C9/16D21H17/14D21H17/66
Inventor 刘秉钺何连芳熊伟
Owner 大连中植环境生物科技有限公司
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