Modified triethanolamine, preparation method and application thereof
A technology of triethanolamine and modification, applied in the field of high-efficiency grinding aid and reinforcing agent for cement, can solve the problems of unsatisfactory application effect of grinding aid, inability to improve the early strength of cement, and high cost of grinding aid, and achieve low cost and good grinding aid. effect, the effect of reducing clinker consumption
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Embodiment 1
[0042] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is
[0043] Triethanolamine 50%
[0044] Mixed acid 48%
[0045] Sulfamic acid 1%
[0046] Silicone 1%.
[0047] The preparation process of this modified triethanolamine is: first drop into triethanolamine 50%, sulfamic acid 1% and silica gel 1% in the reaction kettle, after stirring evenly, be warming up to 80 ℃; Begin to drop 48% mixed acid (mixed acid is sulfuric acid: Phosphoric acid: oxalic acid=90:5:5), dripping is completed within 2 hours. The reaction temperature was controlled at 120°C, and then raised to 145°C after dripping, and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.
[0048] A kind of powdery grinding aid strengthening agent, its component is above-mentioned modified triethanolamine, inorganic fine powd...
Embodiment 2
[0060] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is
[0061] Triethanolamine 60%
[0062] Mixed acid 39%
[0063] Silicone 1%.
[0064] The preparation process of this modified triethanolamine is as follows: in the reaction kettle, firstly drop 60% of triethanolamine and 1% of silica gel, stir and then heat up to 90°C; start to add 39% of mixed acid (mixed acid is sulfuric acid: phosphoric acid: oxalic acid=90: 5:5), the dripping was completed within 0.5 hours. The reaction temperature was controlled at 100°C, and after dripping, the temperature was raised to 145°C and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.
[0065] A kind of powdery grinding aid strengthening agent, its component is above-mentioned modified triethanolamine, inorganic fine powder, aluminum sulfate...
Embodiment 3
[0077] A kind of modified triethanolamine, its component is triethanolamine, mixed acid, sulfamic acid and dehydrating agent, and the content of each component by mass percentage is
[0078] Triethanolamine 45%
[0079] Mixed acid 50%
[0080] Sulfamic acid 3%
[0081] Silicone 2%.
[0082] The preparation process of the modified triethanolamine is as follows: in the reaction kettle, press 45% of triethanolamine, 3% of sulfamic acid and 2% of silica gel, stir and then heat up to 85°C; start to drop 50% of mixed acid (mixed acid is sulfuric acid: Phosphoric acid: tartaric acid = 90: 5: 5), dripped within 2 hours. The reaction temperature was controlled at 120°C, and then raised to 145°C after dripping, and kept for 1 hour; after cooling, the dehydrating agent was filtered off; the obtained product was modified triethanolamine.
[0083] A water-based liquid grinding aid enhancer, its components are the above-mentioned modified triethanolamine, glycerin, molasses, ethylene gl...
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