UV anaerobic double curing coating
A dual-curing, ultraviolet light technology, applied in the coating and other directions, can solve the problems of non-curing, human and environmental hazards, and inability to ensure complete curing of coating components, and achieve the effect of improving adhesion and boiling water resistance.
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example 1
[0019] (1) Preparation of acrylate reactive oligomer epoxy acrylate
[0020] Add 100g of epoxy E-51 into a four-necked flask with a stirrer, condenser, thermometer and dropping funnel, add 37g of acrylic acid and 0.5g of N dropwise from the dropping funnel at a fixed speed within 30min under stirring at 100°C, A mixture of N-dimethylethanolamine and 0.2 g of p-methoxyphenol. The mixture is stirred and kept at ≤100°C for reaction, and when the acid value drops below 5 mgKOH / g, the temperature is lowered to 70°C and the material is discharged, which is the acrylate active oligomer epoxy acrylate (A).
[0021] (2) The paint formula is expressed by the amount of 100g paint prepared, see Table 1 for details
[0022] Table 1
[0023] components
raw material name
Dosage (g)
Acrylic Reactive Oligomers
Epoxy acrylate (A)
30.0
Active diluent
Compounds with 1 ethylenically unsaturated double bond
Hydroxyethyl Acrylate
2...
Embodiment 2
[0028] Except for changing the coating formula (see Table 2), all the others are the same as in Example 1, and the obtained UV-anaerobic dual-curing coating can be used for wood protection.
[0029] Table 2
[0030] components
Embodiment 3
[0032] (1) Preparation of acrylate reactive oligomer urethane acrylate
[0033] Add 100g of polyether 210 to a four-necked flask with a stirrer, condenser, thermometer and dropping funnel, and add 35g of 2,4-body TDI dropwise from the dropping funnel at a fixed speed within 30min under stirring at 40°C. After keeping the temperature for three hours, a mixture of 28 g of hydroxypropyl acrylate, 0.014 g of dibutyltin dilaurate and 0.16 g of p-methoxyphenol was added. Stir the mixture at about 90°C and keep it warm for 6 hours. When the NCO content is reduced to 0.5%, the temperature is lowered to 60°C, and 5g of isopropanol is added and stirred evenly to obtain urethane acrylate (B), a reactive oligomer of acrylate.
[0034] (2) The paint formula is represented by the amount of 100g paint prepared, see Table 3 for details.
[0035] table 3
[0036] components
raw material name
Dosage (g)
Acrylic Reactive Oligomers
40.0
...
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