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Purification assembly technique of nitrous oxides in air

A nitrogen oxide, combined process technology, applied in the field of air purification and atmospheric environmental protection, can solve the problems of low absorption efficiency, secondary pollution, high investment and operating costs, reduce raw material costs, create economic benefits, and low operating costs. Effect

Inactive Publication Date: 2009-02-25
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Regarding the purification method of nitrogen oxides in the air, the purification efficiency of the traditional selective catalytic reduction (SCR) method is generally 70%-90%, but there are high investment and operating costs, consumption of ammonia liquid, and nitrogen oxides cannot be recovered. shortcoming
The principle of non-catalytic selective reduction technology (SNCR) is the same as that of SCR, but it requires a high temperature of 900-1200 ° C, and will consume more ammonia liquid, causing secondary pollution of ammonia liquid leakage
The traditional wet method needs to use an oxidizing agent (such as NaClO, KMnO 4 ) to oxidize insoluble NO to easily absorbed NO 2 , and then absorbed by alkaline liquid absorbent, but it consumes a lot of oxidant and absorbent, and the absorbed product is easy to cause secondary pollution, and sewage treatment equipment must be added, so it is rarely used
Complexation absorption combined with biological conversion of nitrogen oxides technology not only requires the use of Fe(EDTA) solution for absorption, but the use of chelating agent itself puts forward high requirements for equipment. The cost has long been known, and the absorption efficiency is low, generally around 60%
The adsorption method is mostly physical adsorption, and the purpose of removing nitrogen oxides is achieved by changing the temperature or pressure, resulting in large energy consumption, and the concentration of the desorbed gas is low, difficult to recover, and high in cost.

Method used

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  • Purification assembly technique of nitrous oxides in air
  • Purification assembly technique of nitrous oxides in air
  • Purification assembly technique of nitrous oxides in air

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Cedar wood chips (such as figure 2 Shown) sieve to ensure that the size is controlled below 2mm, take 20g Chinese fir sawdust, wash in water, and soak in 5% KOH activation solution for 48h, control the oven temperature at 115°C to 120°C, and dry to obtain the Chinese fir sawdust filler.

[0035] Get 8g of Chinese fir sawdust filler and pack it in the filler column, connect the pipeline, check the airtightness of the device, and it will contain nitrogen oxides 135ppb (0.3mg / m 3 ) of the gas to be treated first passes through the pre-oxidation treatment device, and then passes through the fir sawdust packing bed from bottom to top. , The intermittent spray is controlled by the temperature and humidity or the time using the solenoid valve, and the spray water is recycled. The treated gas is discharged from the nitrogen oxide detector at the top of the packed bed. image 3 It is a dynamic effect diagram of the purification of nitrogen oxides by fir sawdust fillers. The p...

Embodiment 2

[0037] Sieve the larch sawdust to ensure that the particle size is controlled below 2mm, wash 15g of larch sawdust in water, and soak in 5% NaOH activation solution for 24 hours, control the oven temperature at 105°C to 110°C, and dry to obtain Larch sawdust filler.

[0038] Take 8g of larch sawdust filler and fill it in the filler column, connect the pipeline, check the airtightness of the device, and it will contain nitrogen oxides 135ppb (0.3mg / m 3 ) of the gas to be treated first passes through the pre-oxidation treatment device, and then passes through the larch sawdust packing bed from bottom to top. min, the intermittent spray is controlled by the temperature and humidity or time using the solenoid valve, and the spray collection liquid is recycled. The treated gas is discharged from the nitrogen oxide detector at the top of the packed bed. Figure 4 It is a dynamic effect diagram of purifying nitrogen oxides by larch sawdust fillers. The purification efficiency of la...

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Abstract

The present invention provides a technology for purifying and combining nitrogen oxide in air. Wood chips with the size less than 2mm are washed, then are dipped in alkali activated solution with 2 percent to 10 percent of KOH or 2 percent to 10 percent of NaOH for more than 24 hours and then are dried under the temperature of 150 DEG C to be made into a wooden chip filling which is filled in a filling column to form a filling bed. The air containing the nitrogen oxide to be disposed is processed by preoxidation treatment by an ozone generator which controls the ozone concentration to be 1 percent, the air enters from the bottom of the filling column, flows through the filling bed and is exhausted from the top of the filling column after being detected by a nitrogen oxide detector. The upper part of the filling bed is provided with an atomization spray device for atomizing and spraying the filling bed periodically, the atomizing quantity is 800-1000ml / h, and the effective distance is 1m. Interim spray is controlled by an electromagnetic valve according to temperature, humidity or time, and spray liquid can be recycled after being collected. The present invention has simple and convenient operation and good purification effect, is environment-friendly and reduces the cost greatly.

Description

technical field [0001] The present invention relates to the technical field of atmospheric environment protection, more specifically to the technical field of air purification, in particular to a combined process for purifying nitrogen oxides in the air. Background technique [0002] Regarding the purification method of nitrogen oxides in the air, the purification efficiency of the traditional selective catalytic reduction (SCR) method is generally 70%-90%, but there are high investment and operating costs, consumption of ammonia liquid, and nitrogen oxides cannot be recovered. shortcoming. The principle of non-catalytic selective reduction technology (SNCR) is the same as that of SCR, but it requires a high temperature of 900-1200 ° C, and will consume more ammonia liquid, causing secondary pollution of ammonia liquid leakage. The traditional wet method needs to use an oxidizing agent (such as NaClO, KMnO 4 ) to oxidize insoluble NO to easily absorbed NO 2 , and then abs...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/56
Inventor 修光利张大年刘兆辅罗静黄雪娟吴燕赵康魏华张萍
Owner EAST CHINA UNIV OF SCI & TECH
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