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Big magnetostriction alloy with high mechanical strength and manufacturing method thereof

A technology of magnetostriction and mechanical strength, applied in the direction of material selection for magnetostrictive devices, device material selection, etc., can solve problems such as restricting the application of magnetostrictive materials, large saturation magnetization field, and difficulty in single crystal preparation, etc. Achieve the effect of being beneficial to mass production, grain refinement and low cost

Inactive Publication Date: 2010-10-13
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although Tb-Dy-Fe alloy has a large magnetostriction, it requires a large saturation magnetization field, is very brittle, and has poor mechanical properties.
The saturation magnetization field of Fe-Ga alloy is only one tenth of that of Tb-Dy-Fe alloy, with high mechanical strength and good toughness, but low magnetostriction
At the same time, the preparation of single crystals of these two alloys is relatively difficult, consumes a lot of energy, and contains noble metal elements, Tb, Dy and Ga in the composition, which seriously restricts the application of magnetostrictive materials.

Method used

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  • Big magnetostriction alloy with high mechanical strength and manufacturing method thereof
  • Big magnetostriction alloy with high mechanical strength and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1) Mn and Fe with a purity greater than 99.5wt% are used as raw materials, weighed at an atomic percentage of 40:60 and placed in a quartz crucible, and the vacuum degree of the vacuum chamber is adjusted to 5×10 -2 ~2×10 -3 Pa, into high-purity argon as protective gas, intermediate frequency induction heating and melting, and cast in a water-cooled copper mold to form a rod-shaped Mn with a cross-section of 10mm thick × 12mm wide 40 Fe 60 alloy ingot.

[0023] 2) The smelted rod-shaped Mn 40 Fe 60 The alloy ingot was heated to 900°C in a vacuum tube furnace for 72 hours to homogenize its composition, and then slowly cooled to room temperature.

[0024] 3) For homogenized rod-shaped Mn 40 Fe 60 The alloy was cold-rolled 6 times, with a reduction of 0.5 mm each time. In order to eliminate cold work hardening, it was annealed at 300 ° C for 2 hours, and then rolled 4 times to obtain a rolling rate of 50%. 40 Fe 60 Alloy cold-rolled plate, thickness 5mm.

[0025] ...

Embodiment 2

[0031] 1) Mn and Fe with a purity greater than 99.5wt% are used as raw materials, weighed at an atomic percentage of 50:50 and placed in a quartz crucible, and the vacuum degree of the vacuum chamber is adjusted to 5×10 -2 ~2×10 -3 Pa, into high-purity argon as protective gas, intermediate frequency induction heating and melting, and cast in a water-cooled copper mold to form a rod-shaped Mn with a cross-section of 10mm thick × 12mm wide 50 Fe 50 alloy ingot.

[0032] 2) The smelted rod-shaped Mn 50 Fe 50 The alloy ingot was heated to 900°C in a vacuum tube furnace for 100 hours to homogenize its composition, and then slowly cooled to room temperature.

[0033] 3) For homogenized rod-shaped Mn 50 Fe 50 The alloy cast rod is cold-rolled 5 times, each reduction is 0.5mm, in order to eliminate cold work hardening, it is annealed at 300°C for 0.5h, rolled for 6 passes, annealed at 300°C for 3h, and finally Re-rolling for 5 passes to obtain Mn with a rolling ratio of 80% 50...

Embodiment 3

[0040] 1) Mn and Fe with a purity greater than 99.5wt% are used as raw materials, weighed according to the atomic percentage of 55:45 and put into a quartz crucible, and the vacuum degree of the vacuum chamber is adjusted to reach 5×10 -2 ~2×10 -3 Pa, into high-purity argon as protective gas, intermediate frequency induction heating and melting, and cast in a water-cooled copper mold to form a rod-shaped Mn with a cross-section of 10mm thick × 12mm wide 55 Fe 45 alloy ingot.

[0041] 2) The smelted rod-shaped Mn 55 Fe 45 The alloy ingot is heated to 1000°C in a vacuum tube furnace for 24 hours to homogenize its composition, and then slowly cooled to room temperature.

[0042] 3) For homogenized rod-like Mn 55 Fe 45 The alloy ingot was cold-rolled for 5 passes, with a reduction of 0.5mm each time. In order to eliminate cold work hardening, it was annealed at 300°C for 0.5h, rolled for 6 passes, annealed at 300°C for 5h, and finally Re-rolling for 5 passes to obtain Mn wi...

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Abstract

The invention discloses an alloy with high mechanical strength and large magnetostriction and a preparation method thereof. The material compositions and the atomic percentage are as follows: 40 to 60 percent of Mn and 40 to 60 percent of Fe. Under the normal temperature, the alloy is single face-centered cubic and has (011) (100) orientation texture. The preparation method comprises the following steps: 1) Mn and Fe with the purity of more than 99.5 percent by weight are adopted as raw materials and bar-shaped ferrormanganese ingot is obtained through high vacuum induction melting; 2) long-time high-temperature aging treatment is carried out on the bar-shaped ferrormanganese ingot so as to guarantee the uniformity of the alloy compositions; 3) multi-pass cold rolling and relief annealingare carried out on the homogenized bar-shaped ferrormanganese ingot so as to obtain a ferrormanganese cold rolling sheet; and 4) recrystallization annealing is carried out on the final ferrormanganese cold rolling sheet. The ferrormanganese cold rolling sheet prepared by the invention has a magnetostriction coefficient equal to that of the traditional rare earth magnetostriction alloy, and has little magnetic hysteresis, low price, and excellent mechanical performance.

Description

technical field [0001] The invention relates to a preparation method of an alloy, in particular to a magnetostrictive material and a preparation method thereof. Background technique [0002] Magnetostrictive material is a new type of functional material gradually developed in the 1970s. It has the conversion function of electromagnetic energy and mechanical energy, and is an important functional material for energy and information conversion, especially an important material for sonar converters. [0003] Magnetostriction is caused by the movement of the magnetic domain walls and the rotation of the magnetic moments when an external field is applied. Magnetostrictive materials widely used at present mainly include rare earth-based Tb-Dy-Fe alloys and Fe-Ga alloys. These two alloys can only obtain large magnetostriction in the state of oriented single crystal, and the saturation magnetostriction value of the former is 1700ppm, and that of the latter is 400ppm. Although the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/04C22C33/04C22C22/00C22C1/02C22C30/00H01L41/20H10N35/85
Inventor 严密张晶晶马天宇何爱娜
Owner ZHEJIANG UNIV