Biodiesel based fuel oil and preparation thereof
A technology of biodiesel and fuel oil, applied in fuel, liquid carbon-containing fuel, petroleum industry, etc., can solve the problems of poor stability and low calorific value, and achieve the effects of good stability, high calorific value and saving consumption
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[0018] Preparation of Crude Biodiesel:
[0019] Mix rapeseed oil, palm oil, cottonseed oil and other natural oils with methanol in a molar ratio of 6:1, add 2%wt KOH, stir evenly at 80°C, and let it stand for 1 hour to separate and the upper layer is The crude biodiesel raw material we use is mainly composed of biodiesel, unreacted excess alcohol and catalyst residues, free glycerin, a small amount of metal ions, and residual soaps. .
[0020] A biodiesel-based fuel oil consisting of the following substances, in weight percent:
[0021] Crude Biodiesel 50-80%
[0022] Complex emulsifier 4-35%
[0023] Methanol or water or a mixture of both Balance.
[0024] For the biodiesel-based fuel oil, the compound emulsifier is a mixture of the following two types of substances, the first type is: oleic acid, palmitoleic acid, naphthenic acid, fatty amine polyamides with 40-100 C atoms Oxyethylene ether, sorbitan fatty acid ester with 40-100 C atoms, polyoxyethylene sorbitan fatty a...
Embodiment 1
[0028] At room temperature, a mixture of 52% of crude biodiesel, 26% of compound emulsifier, 12% of methanol and 10% of water was prepared by weight percentage, put into a container, and stirred evenly for 60 minutes, and the whole mixture was transparent liquid. The composite emulsifier is composed of 50%wt oleic acid, 42%wt sorbitan fatty acid ester SPAN80, 5%wt triethanolamine and 3%wt 1-octanol. The obtained calorific value is 37.9KJ / g, and the product does not appear turbid after being placed for 6 months.
Embodiment 2
[0030] At room temperature, prepared by weight percentage, put the mixture of 58% of crude biodiesel, 22% of compound emulsifier, and 20% of methanol into a container, and stir evenly for 60 minutes, and the whole mixed liquid is a transparent liquid. The composite emulsifier is compounded by 45%wt of palmitoleic acid, 50%wt of diethanolamine and 5%wt of tert-butanol. The obtained calorific value is 37.8KJ / g, and the product does not appear turbid after being placed for 6 months.
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