Image forming device and colour toner
A technology of toner and yellow toner, which is applied in the direction of electric recording process applying charge pattern, equipment of electric recording process applying charge pattern, developer, etc. The requirements of the color reproduction range, the difficulty of color reproduction performance, etc., to achieve the effect of expanding the color reproduction area
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[0202] The present invention will be further described below through examples, but the present invention is not limited thereto.
[0203] In addition, "part" mentioned below means a weight part, and "%" means a weight%.
[0204]
Synthetic example 1
[0205] [Synthesis Example 1 (Synthesis of Crystalline Polyester Resin No. 1)]
[0206] Add to a 5-liter four-neck flask equipped with a nitrogen introduction tube, a dehydration tube, a stirrer and a thermocouple
[0207] 1,4-butanediol: 23.75 moles
[0208] Ethylene glycol: 1.25 moles
[0209] Fumaric acid: 22.75 moles
[0210] 1,2,4-Pellisic anhydride: 1.65 moles
[0211] Hydroquinone: 4.8 grams
[0212] After reacting at 160° C. for 5 hours, the temperature was raised to 200° C. for 1 hour, and then at 8.3 kPa for 1 hour to obtain crystalline polyester resin No.1.
[0213]
[0214] [Synthesis of titanium-containing catalyst (a)]
[0215] Add the 80% aqueous solution of dihydroxybis(triethanolamide) titanium to the reactor that cooling pipe, stirrer and the nitrogen inlet pipe that can bubble in the liquid phase are housed, under the condition of blowing nitrogen bubbles in the liquid phase, Slowly raise the temperature to 90°C and react at 90°C for 4 hours (hydrolys...
Embodiment 1
[0226] formula:
[0227]
[0228]
[0229] After fully mixing the following toner compositions with a blender, they were melt-kneaded with a twin-screw extruder (mixing temperature: 140°C, extrusion speed: 10kg / hour, calendering nip: 2mm, and left to stand for 48 hours After that, it was pulverized and classified to obtain an original toner having a volume-average particle diameter of 7.6 μm. With respect to 100 parts of the original toner, 0.4 parts of hydrophobic silica (surface treated with hexamethyldisilylamine, particle diameter of primary particles: 0.02 μm) was mixed as an additional additive with a Henschel mixer , and a cyan toner (C-1) was obtained. The mixing condition is 1500 rpm, and the mixing cycle is eight times, and each cycle is stirring for 60 seconds and then stopping for 60 seconds.
[0230] * Crystalline polyester resin No.1 35 parts
[0231] * Amorphous polyester resin A 65 parts
[0232] * Carnauba wax (melting point: 81°C) 5 parts
[0233]...
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