Overall lead-free X-ray shielding plastic compound material

A composite material and X-ray technology, which is applied in the field of rare earth mixed with other metals and compounds, all lead-free X-ray shielding plastic composite materials, can solve problems such as easy voids, poor compatibility, and reduced comprehensive performance of composite materials

Inactive Publication Date: 2009-11-04
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Russian patents RU2054439 and RU2028331 disclose plastic X-ray-resistant composite materials modified with inorganic rare earth oxide fillers, but due to the poor compatibility of inorganic rare earth (rare earth oxides) with the plastic matrix, the polymer matrix Voids are prone to appear at the interface, and these gaps will be easily penetrated when irradiated by high-energy rays, and even the phenomenon of ray leakage occurs. In addition, we also found that adding a large amount of inorganic rare earth and metal bismuth (and its inorganic compounds) directly into the polymer matrix It will greatly reduce the comprehensive performance of composite materials.

Method used

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  • Overall lead-free X-ray shielding plastic compound material
  • Overall lead-free X-ray shielding plastic compound material
  • Overall lead-free X-ray shielding plastic compound material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The composition and parts by weight of each component are:

[0036] Low-density polyethylene (LDPE) 100

[0037] Samarium acrylate 20

[0038] Cerium methacrylate 40

[0039] Samarium methacrylate 40

[0040] Terbium acrylate 20

[0041] Samarium oxide 200

[0042] Cerium oxide 200

[0043] Metal tin 20

[0044] Tin oxide 100

[0045] Bismuth oxide 100

[0046] Bismuth undecylenate 230

[0047] Metal Tungsten 100

[0048] KH550 3

[0049] Low molecular weight polyethylene wax (molecular weight is 2000) 15

[0050] Antioxidant 1010 2

[0051] Dicumyl peroxide (in situ reaction initiator) 0.3

[0052] Preparation of shielding material: Heat the hot roll to 130°C, add 100 parts of LDPE and melt it to cover the roll, add 20 parts of samarium acrylate, 20 parts of terbium acrylate, 40 parts of samarium methacrylate, 40 parts of cerium methacrylate, After mixing 230 parts of bismuth undecylenate and 0.3 parts of in-situ reaction initiator dicumyl peroxide for 5 ...

Embodiment 2

[0055] The composition and parts by weight of each component are:

[0056] Low-density polyethylene (LDPE) 100

[0057] Cerium Acrylate 40

[0058] Gadolinium methacrylate 40

[0059] Samarium methacrylate 60

[0060] Holmium Acrylate 20

[0061] Gadolinium oxide 200

[0062] Cerium oxide 150

[0063] Metal tin 100

[0064] Tin oxide 120

[0065] Bismuth oxide 200

[0066] Bismuth methionate 150

[0067] Metal Tungsten 120

[0068] KH550 2

[0069] Low molecular weight polyethylene wax (molecular weight is 2000) 20

[0070] Antioxidant 1010 3

[0071] Dicumyl peroxide (in situ reaction initiator) 0.5

[0072] Preparation of shielding material: Heat the hot roll to 130°C, add 100 parts of LDPE and melt it to cover the roll, add 40 parts of cerium acrylate, 20 parts of holmium acrylate, 60 parts of samarium methacrylate, 40 parts of gadolinium methacrylate, After 150 parts of bismuth methacrylate and 0.5 parts of in-situ reaction initiator dicumyl peroxide were mix...

Embodiment 3

[0074] The composition and parts by weight of each component are:

[0075] Low-density polyethylene (LDPE) 100

[0076] Terbium acrylate 40

[0077] Cerium methacrylate 60

[0078] Samarium methacrylate 80

[0079] Gadolinium Acrylate 20

[0080] Neodymium oxide 150

[0081] Cerium oxide 150

[0082] Metal tin 150

[0083] Tin oxide 120

[0084] Bismuth oxide 100

[0085] Bismuth methionate 50

[0086] Metal Tungsten 150

[0087] KH550 2

[0088] Low molecular weight polyethylene wax (molecular weight is 2000) 20

[0089] Antioxidant 1010 2.5

[0090] Dicumyl peroxide (in situ reaction initiator) 0.8

[0091]Preparation of shielding material: Heat the hot roll to 130°C, add 100 parts of LDPE and make it melt to cover the roll, add 40 parts of terbium acrylate, 20 parts of gadolinium acrylate, 60 parts of cerium methacrylate, 80 parts of samarium methacrylate, After mixing 50 parts of bismuth methacrylate and 0.8 parts of in-situ reaction initiator dicumyl peroxid...

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Abstract

The invention relates to an overall lead-free X-ray shielding plastic compound material. The overall lead-free X-ray shielding plastic compound material uses rare earth mixture to replace lead, simultaneously adds metal tin and compounds thereof, metal tungsten and the compounds thereof and bismuth and the compounds thereof as shielding main materials and is further compounded with plastic to prepare the compound material which can realize the overall shielding and the complete lead-free property within the energy range of 40-170kVp. When in use of rare earth and bismuth materials, the way of combined use of the two metal element inorganic compounds and unsaturated organic complexes is adopted, and the in-situ reaction and the compounding with a polymer matrix are carried out, thereby leading the shielding element disperse phase to form nano-micro-level dispersed particles. The prepared material combines the X-ray shielding performance of shielding elements and the good conventional physical mechanical performance of matrix polymer material and can be widely used in medical diagnostic X-ray machines, X-ray diffraction instruments and occasions accompanied with X-ray generation for ray protection for working staff.

Description

Technical field: [0001] The invention relates to a lead-free X-ray shielding plastic composite material mixed with rare earth and other metals and compounds. Background technique: [0002] The invention is to prepare polymer composite materials for X-ray shielding with high shielding performance, lead-free, light and soft, and good physical and mechanical properties. Protection of workers in places accompanied by X-ray generation. [0003] The development, production and popularization of radiation protection materials is one of the key points of civil health protection work, and it is also an important part of radiation protection in the field of nuclear energy development and military use. For a long time, among the radiation workers in our country, there are a large number and the worst protection conditions are medical diagnosis and cardiovascular interventional X-ray workers (X-ray machines, CT machines). They need a lot of high-quality, light radiation-proof clothing....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G21F1/10
CPCC08K5/098C09D123/02G21F1/02C08K5/0091
Inventor 刘力张立群魏宗源臧立伟胡水温世鹏
Owner BEIJING UNIV OF CHEM TECH
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