Non-adhesive biaxially-oriented polypropylene film for hot lamination and preparation method thereof

A technology of polypropylene film and biaxial stretching, applied in chemical instruments and methods, synthetic resin layered products, layered products, etc., can solve problems such as unfavorable environmental protection, affecting product appearance, and increasing production costs

Active Publication Date: 2010-01-27
QUANZHOU LICHANG PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, whether it is dry compounding or coating treatment, it means adding an additional production process, which greatly increases the production cost. At the same time, excessive use of adhesives and solvents containing glue is not conducive to environmental protection. And the adhesive is easy to change color and yellow during use, which affects the appearance of the product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0026] Example 1 Three-tier structure

[0027] The heat-sensitive functional layer accounting for 33% of the total film weight contains 20% ethylene-butene copolymer, 70% maleic anhydride grafted modified product of ethylene-butene copolymer, 10% hydrogenated petroleum Resin masterbatch (containing 50% hydrogenated petroleum resin and 50% low-density polyethylene), the materials are mixed and put into an auxiliary extruder, wherein the working temperature of the extruder is 150-270°C, melted and plasticized for extrusion;

[0028] The substrate layer contains 95% polypropylene, 1% antistatic composite masterbatch (containing 20% ​​antistatic agent and 80% polypropylene), 4% hydrogenated petroleum resin composite masterbatch (50% hydrogenated petroleum resin and 50% polypropylene), put the substrate layer material into a main extruder, wherein the working temperature of the extruder is 180-270°C, and melt and plasticize and extrude;

[0029] The anti-adhesion layer accounting ...

example 2

[0033] Example 2 Three-tier structure

[0034] The heat-sensitive functional layer accounting for 30% of the total film weight contains 30% ethylene-hexene copolymer, 65% maleic anhydride grafted modified product of ethylene-butene copolymer, 5% hydrogenated petroleum Resin masterbatch (containing 40% hydrogenated petroleum resin and 60% low-density polyethylene), the materials are mixed and put into an auxiliary extruder, wherein the working temperature of the extruder is 150-270°C, melted and plasticized for extrusion;

[0035] The substrate layer contains 85% polypropylene, 5% antistatic composite masterbatch (containing 30% composite amine antistatic agent and 70% polypropylene), 10% hydrogenated petroleum resin composite masterbatch (60% hydrogenated petroleum resin and 40% polypropylene), put the material of the substrate layer into a main extruder, wherein the working temperature of the extruder is 180-270°C, melt and plasticize and extrude;

[0036] The anti-adhesion ...

example 3

[0040] Example 3 Three-tier structure

[0041] The heat-sensitive functional layer accounting for 25% of the total film weight contains 30% ethylene-hexene copolymer, 65% maleic anhydride grafted modified product of ethylene-butene copolymer, 5% hydrogenated petroleum Resin masterbatch (containing 40% hydrogenated petroleum resin and 60% low-density polyethylene), the materials are mixed and put into an auxiliary extruder, wherein the working temperature of the extruder is 150-270°C, melted and plasticized for extrusion;

[0042]The substrate layer contains 85% polypropylene, 5% antistatic composite masterbatch (containing 30% composite amine antistatic agent and 70% polypropylene), 10% hydrogenated petroleum resin composite masterbatch (60% hydrogenated petroleum resin and 40% polypropylene), put the material of the substrate layer into a main extruder, wherein the working temperature of the extruder is 180-270°C, melt and plasticize and extrude;

[0043] The anti-adhesive l...

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PUM

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Abstract

The invention discloses a non-adhesive biaxially-oriented polypropylene film for hot lamination. The film comprises a heat-sensitive function layer, a substrate layer and an anti-sticking layer which are orderly arranged and are formed by co-extrusion lamination, wherein calculated as the weight ratio, the heat-sensitive function layer accounts for 4 to 33 percent of the total weight of the film, and the anti-sticking layer accounts for 4 to 17 percent of the total weight of the film; the substrate layer comprises 85 to 95 percent of polypropylene, 1 to 5 percent of antistatic composite masterbatch, and 4 to 10 percent of hydrogenated petroleum resin composite masterbatch; the antistatic composite masterbatch comprises 10 to 30 percent of antistatic agent and 70 to 90 percent of the polypropylene; the hydrogenated petroleum resin composite masterbatch comprises 40 to 60 percent of hydrogenated petroleum resin and 40 to 60 percent of the polypropylene; and the anti-sticking layer comprises 95 to 99 percent of the polypropylene and/or polyethylene, and 1 to 5 percent of anti-adhesion masterbatch, and the anti-adhesion masterbatch comprises 5 to 15 percent of antiblocking agent. The invention also provides a method for preparing the non-adhesive biaxially-oriented polypropylene film, which comprises the steps of: adding materials of the layers into extruding machines for melting plastification and extrusion respectively; merging for co-extrusion through a T type die head; performing biaxial tension; and performing corona treatment, and winding into the non-adhesive biaxially-oriented polypropylene film for hot lamination.

Description

Technical field: [0001] The invention relates to an adhesive-free biaxially stretched polypropylene film for thermal compounding of paper and plastics and a preparation method thereof. Background technique: [0002] The surface layer of ordinary three-layer or five-layer co-extruded biaxially oriented polypropylene film is a polypropylene resin layer, and the melting point of polypropylene is relatively high (homopolypropylene is usually about 165°C, and copolymerized polypropylene is usually about 130°C) ). Generally, the temperature of thermal lamination of paper and plastic film should not exceed 95°C, because when the processing temperature exceeds 95°C, the moisture in the paper will be lost, causing the paper to be deformed, coiled and brittle, which will affect the product quality. Due to the high melting point of polypropylene and poor thermal bonding performance, ordinary biaxially oriented polypropylene films cannot be directly thermally laminated with paper at a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/18B32B27/22B29C69/00B29C47/06B29C47/92B29C55/14B29C59/10B29C48/08B29C48/92
CPCB29C48/92B29C2948/92704B29C48/08B29C2948/92895B29C2948/92904B29C2948/92923
Inventor 吕水抽林陈震齐庆德林小松
Owner QUANZHOU LICHANG PLASTIC
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